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1. 发明申请

WO2006005762A1 PROCESS FOR PREPARING LINEAR ALPHA OLEFINS 审中-公开
标题翻译：制备线性ALPHA油脂的方法
公开(公告)号：WO2006005762A1
公开(公告)日：2006-01-19
申请号：PCT/EP2005/053352
申请日：2005-07-13
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , OOSTERVELD, Inge , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , OOSTERVELD, Inge , VAN ZON, Arie
IPC分类号： C07C2/22
CPC分类号： C07C2/08 , C07C1/327 , C07C5/2575 , C07C2523/755 , C07C2527/128 , C07C2531/14 , C07C11/02
摘要： A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of: (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i)reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin, and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.
摘要翻译：制备具有n个碳原子的直链α-烯烃具有2n个碳原子的直链α-烯烃的方法，包括以下步骤：（a）在二聚催化剂存在下将具有n个碳原子的直链α-烯烃二聚化以产生线性内部具有2n个碳原子的烯烃; （b）（i）使催化量的异构化/置换催化剂存在下使步骤（a）中产生的具有2n个碳原子的直链内烯烃与三烷基铝化合物反应，以使线性内烯烃异构化，从所述三烷基铝化合物取代烷基以形成烷基铝化合物，其中至少一个与铝结合的烷基是源自所述线性内烯烃的异构化的直链烷基，和（b）（ii ）使所述烷基铝化合物与α-烯烃反应，任选地在置换催化剂存在下使所述烷基铝化合物的所述直链烷基取代形成具有2n个碳原子的直链α-烯烃。

2. 发明申请

WO2008077908A1 LIGANDS AND CATALYST SYSTEMS THEREOF FOR THE CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体催化低级化合物的配体和催化剂体系
公开(公告)号：WO2008077908A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064391
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/6571 , C07F11/00 , B01J31/18
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand having the general Formula (I); P(R 4 J-P(R 1 ) (R 2 )=N(R 3 ) (I) wherein: the R 1 group is selected from a hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl group; the R 2 group is selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups; the R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 4 group is an optionally substituted alkylenedioxy, alkylenedimercapto or alkylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the alkylenedioxy, alkylenedimercapto or alkylenediamino structure or an optionally substituted arylenedioxy, arylenedimercapto or arylenediamino structure which is bound to the phosphorus atom through the two oxygen, sulphur or nitrogen atoms of the arylenedioxy, arylenedimercapto or arylenediamino structure.
摘要翻译：本发明涉及具有通式（I）的配体; （R 4）（R 4）（R 2）= N（R 3）（I）其中：R 1基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R 2基团选自烃基，取代的烃基，杂烃基和取代的杂烃基; R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 4，亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构，其通过亚烷基二氧基，亚烷基二巯基或亚烷基二氨基结构的两个氧，硫或氮原子或任选取代的亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构与磷原子结合，通过两个氧，硫或硝基键合到磷原子上亚芳基二氧基，亚芳基二巯基或亚芳基二氨基结构的原子。

3. 发明申请

WO2008077911A1 LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：用于烯烃单体低级化的配体和催化剂体系
公开(公告)号：WO2008077911A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064398
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/535 , C07F11/00 , B01J31/18
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to a ligand having the general formula (I) : (R 1 ) 2 P-P(R 1 )m(R 2 ) n =N(R3) (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions, with the proviso that m is 0 or 1, n is 1 or 2 and the total of m + n is 2. The present invention also relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands.
摘要翻译：本发明涉及具有通式（I）的配体：（R 1）2 PP（R 1）2（R 1）其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 0-2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基，条件是m为0或1，n为1或2，m + n的总和为2.本发明还涉及使用所述配体的烯烃单体的同时三聚和四聚的催化剂体系和方法。

4. 发明申请

WO2007057455A1 CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体的催化低聚
公开(公告)号：WO2007057455A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068652
申请日：2006-11-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： B01J31/24 , B01J31/18 , B01J31/34 , C07C2/32 , C07C2/36
CPC分类号： C07C2/36 , B01J31/188 , B01J31/34 , B01J2231/20 , B01J2531/62 , C07C2531/14 , C07C2531/24 , C07F9/46
摘要： A catalyst precursor composition comprising: a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I) ; (R 1 ) (R 2 ) P-X-P(R 3 ) (R 4 ) wherein: X is a bridging group of the formula -N(R 5 )-, wherein R 5 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; at least three of R 1 to R 4 are independently selected from optionally substituted aromatic groups, each bearing a polar substituent on at least one of the ortho-positions; and optionally one of R 1 to R 4 is independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; c) a second ligand having the general formula (II) ; (R 1 ' ) (R 2 ' ) P-X'-P(R 3 ' ) (R 4 ' ) wherein: X' is a bridging group as defined for X of the first ligand, component (b) , of general formula (I) ; at least R 1 ' and R 2 ' of R 1 ' to R 4 ' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; and optionally none, one or both of R 3 ' and R 4 ' are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and additional component; d) a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.
摘要翻译：一种催化剂前体组合物，其包含：a）铬，钼或钨的来源; b）具有通式（I）的第一配体; （R 1）（R 2）PXP（R 3）（R 4）其中：X是式-N（R 5） - 的桥连基团，其中R 5选自氢，烃基，取代的烃基，杂烃基，取代的异烃基，甲硅烷基或其衍生物; R 1至R 4中的至少三个独立地选自任选取代的芳族基团，其各自在至少一个邻位上带有极性取代基; 并且任选的R 1至R 4中的一个独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当该基团为芳族时，其不含任何邻位的极性取代基; c）具有通式（II）的第二配体; （R'1）（R 2）P-X'-P（R 3）（R 4）其中：X'是如通式（I）的第一配体组分（b）的X所定义的桥连基团; R 1至R 4的至少R 1'和R 2'独立地选自烃基取代的烃基，杂烃基和取代的杂烃基，条件是当该基团是芳族的时，它在任何邻位不含极性取代基; 并且任选地，R“3”和“R”4中的任一个或两个独立地选自在至少一个邻位取代基上带有极性取代基的任选取代的芳族基团，位置。本发明还涉及包含本发明的催化剂前体组合物和另外的组分的催化剂体系; d）助催化剂。本发明还涉及烯烃单体的三聚和四聚的方法，特别是乙烯对1-己烯和1-辛烯的三聚和四聚，其中该方法包括使至少一种烯属单体与本发明的催化剂体系接触发明。

5. 发明申请

WO2007057458A1 CATALYTIC PROCESS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体低级化的催化方法
公开(公告)号：WO2007057458A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068659
申请日：2006-11-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07C2/36 , C07C11/107 , B01J31/24
CPC分类号： B01J31/188 , B01J31/143 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07C2/36 , C07C2531/24 , C07F9/46
摘要： A process for the simultaneous trimerization and tetramerization of olefinic monomers , wherein the process comprises contacting at least one olefinic monomer with catalyst system comprising : a) a source of chromium, molybdenum or tungsten; b) a ligand having the general formula (I) ; (R 1 ) 2 P-X-P (R 1 ) m (R 2 )n wherein : X is a bridging group of the formula -N(R 3 )-, wherein R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups and c) a cocatalyst, at a pressure in the range of from below atmospheric to about 40 barg and at a temperature in the range of from about 0 °C to about 120 °C. The present invention further relates to a process for the simultaneous trimerization and tetramerization of ethylene to 1-hexene and 1-octene.
摘要翻译：一种用于烯烃单体的同时三聚和四聚的方法，其中所述方法包括使至少一种烯属单体与催化剂体系接触，所述催化剂体系包括：a）铬，钼或钨的来源; b）具有通式（I）的配体; （R 1）2 PXP（R 1）2（R 2）2（R 2） n其中：X是式-N（R 3 O 3） - 的桥连基团，其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; R 2和R 2独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，和c）助催化剂，其压力范围为低于大气压至约40巴，温度为在约0℃至约120℃的范围内。本发明还涉及一种将乙烯同时三聚和四聚到1-己烯和1-辛烯的方法。

6. 发明申请

WO2006108803A1 CATALYTIC TRIMERIZATION AND TETRAMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体的催化三聚和四聚体
公开(公告)号：WO2006108803A1
公开(公告)日：2006-10-19
申请号：PCT/EP2006/061425
申请日：2006-04-07
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： B01J31/24 , B01J31/18
CPC分类号： B01J31/188 , B01J31/143 , B01J31/2409 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2540/10 , C07C2/36 , C07C2531/24 , C07C11/02 , C07C11/107
摘要： A catalyst precursor composition comprising: a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I) ; (R 1 ) (R 2 ) P-X-P(R 3 ) (R 4 ) (I), wherein: X is a bivalent organic bridging group; R 1 and R 3 are independently selected from, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, with the proviso that when R 1 and R 3 are aromatic groups they do not contain a polar substituent at any of the ortho-positions; R 2 and R 4 are independently selected from optionally substituted aromatic groups, each R 2 and R 4 bearing a polar substituent on at least one of the ortho-positions; and c) a second ligand having the general formula (II) ; (R 1' ) (R 2' )P-X'-P(R 3' ) (R 4' ) (II), wherein: X' is a bridging group of the formula -N(R 5' )-, wherein R 5' is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; and R 1' , R 2' , R 3' and R 4' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups of which at least one of R 1' , R 2' , R 3' and R 4' is substituted with a polar substituent, or R 1' , R 2' , R 3' and R 4' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, wherein any substituents on one or more of R 1' , R 2' , R 3' and R 4' are non-polar. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and additional component; d) a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.
摘要翻译：一种催化剂前体组合物，其包含：a）铬，钼或钨的来源; b）具有通式（I）的第一配体; （R 1）（R 2）（R 4）（R 4）（R 4）（R 4）（R 4） X是二价有机桥连基团; R 1和R 3独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当R 1和 R 3是在任何邻位不包含极性取代基的芳族基团; R 2和R 4独立地选自任选取代的芳族基团，每个R 2和R 4都带有一个在至少一个邻位上的极性取代基; 和c）具有通式（II）的第二配体; （R'1'）（R 2'）P-X'-P（R 3'）（R 4' （II），其中：X'是式-N（R 5'）的桥连基团，其中R 5'选自氢烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; 和R 1'，R 2'，R 3'和R 4'独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，其中R 1，R 2，R 3，R'和R“中的至少一个 > 4'被极性取代基取代，或R 1，R 2，R 3，R 3， SO 4“独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，其中R 1，R 2，R 2， SUP>，R 3'和R 4'是非极性的。本发明还涉及包含本发明的催化剂前体组合物和另外的组分的催化剂体系; d）助催化剂。本发明还涉及烯烃单体的三聚和四聚的方法，特别是乙烯对1-己烯和1-辛烯的三聚和四聚，其中该方法包括使至少一种烯属单体与本发明的催化剂体系接触发明。

7. 发明申请

WO2010130696A1 PROCESS FOR THE PRODUCTION OF ETHYLENE GLYCOL AND RELATED COMPOUNDS 审中-公开
标题翻译：乙二醇和相关化合物的生产方法
公开(公告)号：WO2010130696A1
公开(公告)日：2010-11-18
申请号：PCT/EP2010/056387
申请日：2010-05-10
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , MEURS, Jan Hermen Hendrik , WIJNANS, Sanne
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , MEURS, Jan Hermen Hendrik , WIJNANS, Sanne
IPC分类号： C07C231/08 , C07C231/10 , C07C29/149 , C07C235/06 , C07C211/14
CPC分类号： C07C209/78 , C07C29/149 , C07C213/00 , C07C31/202 , C07C211/10 , C07C215/08
摘要： The present invention provide a process for the production of compounds of general formula (I), Y-CH 2 CH 2 -Z (I) wherein Y and Z are functional groups independently selected from the group consisting of a hydroxyl group and R 1 R 2 N and wherein R 1 and R 2 may be the same or different and are functional groups selected from the group consisting of hydrogen and substituted or non- substituited alkyl groups comprising 1 to 8 carbon atoms, or R 1 R 2 N is a cyclic compound selected from the group of aromatic and non-aromatic cyclic compounds optionally comprising one or more heteroatoms in addition to the nitrogen atom, said process comprising the steps of: (i) reacting carbon monoxide and an amine in the presence of oxygen to provide a compound of general formula (II) wherein R 1 and R 2 or R 1 R 2 N are as defined above and X is selected from the group consisting of R 1 R 2 N and R 3 O, wherein R 3 is selected from alkyl groups comprising 1 to 8 carbon atoms; and (ii) converting the compound of general formula (II) into a compound of general formula (I) by a process that comprises a hydrogenation reaction.
摘要翻译：本发明提供一种制备通式（I）的化合物，Y-CH 2 CH 2 -Z（I）的化合物，其中Y和Z是独立地选自羟基和R 1 R 2 N的官能团，其中R 1和R 2 可以相同或不同，并且是选自氢和取代或未取代的包含1至8个碳原子的烷基的官能团，或R 1 R 2 N是选自芳族和非芳族环状化合物的环状化合物所述方法包括以下步骤：（i）在氧气存在下使一氧化碳和胺反应，得到通式（II）的化合物，其中R1和R2或R1R2N 其定义如上，X选自由R 1 R 2 N和R 3 O组成的组，其中R 3选自包含1至8个碳原子的烷基; 和（ii）通过包括氢化反应的方法将通式（II）的化合物转化为通式（I）的化合物。

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