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    • 2. 发明授权
    • Process for dyeing and printing polyalkylene terephthalate fibers with dispersed anthraquinone dyestuff
    • 用于染色和印刷具有分散的蒽醌衍生物的聚亚甲基三十一碳烯纤维的方法
    • US3473882A
    • 1969-10-21
    • US3473882D
    • 1965-05-03
    • CIBA LTD
    • WEBER KURTRICKENBACHER HANSRUEDIMEISTER ULRICH
    • C09B1/36C09B1/42C09B1/54C09B1/60C09B5/16C09B43/16C09B62/085D06P1/20D06P3/82
    • D06P3/8252C09B1/36C09B1/42C09B1/545C09B1/60C09B5/16C09B43/16C09B62/085D06P1/20D06P3/8214D06P3/8247Y10S8/933
    • Monoaroylamino-anthraquinones that are free of acidic groups imparting solubility in water, that have an anthraquinone residue consisting of 3 fused rings and that are free from hydroxyl groups are employed to dye materials of aromatic polyesters. The said dyes may contain an a - or b -naphthoylamino or especially benzoylamino group, the a -position being preferred. The anthraquinone residue may be further substituted, especially in the a -position by -NH2, alkylamino, phenylamino, aliphatic or cycloaliphatic acylamino, alkoxy, alkylmercapto or nitro groups or halogen atoms. The dyestuffs of the following formula are of special interest: in which R is a benzene residue that may be substituted, at least one X represents a hydrogen or halogen atom, an -NH2, aliphatic or cycloaliphatic acylamino, carboalkoxy, alkoxy or nitro group, the other X's being hydrogen atoms. The residue R may be substituted with halogen atoms, alkyl or alkoxy groups. A large number of dyestuffs are specified which may be prepared by monobenzoylation of the appropriate amino compound. Mixtures of dyestuffs may also be used which mixtures sometimes show better affinity than single dyestuffs (see Example 2). U.S.A. Specification 2,876,061 is referred to.ALSO:Fibrous materials of aromatic polyesters are dyed or printed by heating them with an aqueous dispersion of a monoaroylamino-anthraquinone which is free from water-solubilising acidic groups and from hydroxyl groups and whose anthraquinone residue consists of 3 fused rings. The said dyes may contain an a - or b -naphthoylamino or especially benzoylamino group, the a -position being preferred. The authraquinone residue may be further substituted, especially in the a -position by -NH2, alkylamino, phenylamino, aliphatic or cycloaliphatic acylamino, alkoxy, alkylmercapto or nitro groups or halogen atoms. The dyestuffs of the following formula are of special interest: in which R is a benzene residue that may be substituted, at least one X represents a hydrogen or halogen atom, an -NH2, aliphatic or cycloaliphatic acylamino, carboalkoxy, alkoxy or nitro group the other X's being hydrogen atoms. The residue R may be substituted with halogen atoms, alkyl or alkoxy groups. A large number of dyestuffs are specified. Mixtures of dyestuffs may also be used which mixtures sometimes show better affinity than single dyestuffs (see Example 2). Dyeing may be effected in the presence of dispersing agents, e.g. soap, sulphite cellulose paste liquor, the sodium salts of N-benzyl-m -heptadecylbenzimidazole disulphonic acid, di-isobutylnaphthalene sulphonic acid, and dinaphthyl methane disulphonic acid. Polyethylene terephthalate fibres may be dyed under super-atmospheric pressure at 120 DEG C. from a slightly acid bath or in a presence of a number of specified swelling agents. The dyes may also be applied by printing or padding from a thickened solution advantageously containing urea and then thermofixed at 180-220 DEG C. Mixed fabrics of polyester and cotton may be dyed and the dyebaths or print pastes may also contain a reactive or a vat dyestuff. Cross-dyeing wool/polyester blends may be achieved due to the good reservation on wool. Examples of dyeing polyethylene terephthalate are given in which a number of known auxiliaries are employed. U.S.A. Specification 2,876,061 is referred to.
    • 3. 发明授权
    • Hair dye comprising substituted anthraquinones in shampoo base
    • 包含洗发水基质中的取代的蒽醌的染发剂
    • US3192117A
    • 1965-06-29
    • US17437762
    • 1962-02-20
    • THERACHEMIE CHEM THERAPEUT
    • JAKOB KAISER WILHELMALFONS STURM
    • A61K31/00C09B1/20C09B1/28C09B1/54C09B1/60
    • A61K8/355A61K31/00A61Q5/065C09B1/14C09B1/20C09B1/22C09B1/28C09B1/285C09B1/545C09B1/60
    • Anthraquinone dyes for hair are made by reacting halogenated, nitrated or sulphonated anthraquinones which may also contain one or two primary amino groups with mono- or polyglycols or their monoalkyl ehters or with thioglycols, for example by reacting dichlorinated 1 : 4 - diamino - anthraquinone or 1 : 4-diamino-5 - nitro - anthraquinone with ethyl diethylene glycol or monochlorinated 1 : 4-diamino - anthraquinone with sodium diethylene glycol, by reacting 1 : 4-diamino-anthraquinone with p-toluenesulphonic esters of monoethyldiethylene glycol or by reacting 1 : 4-diamino-2-bromoanthraquinone or 1 : 4 - diamino - 5 - nitroanthraquinone with NH(C2H4OC2H4OC2H5)2. Dyes if the following formulae are specified: ALSO:Hair such as human hair or fur is dyed by applying a dyeing agent containing an anthraquinone dye which is free from acid groups and has attached to the anthraquinone nucleus no hydroxyl groups but at least one aliphatic residue attached via a hetero-atom, the said aliphatic residue being (a) a hydroxy-alkyl or alkyl ether residue, the alkylene chain of which is interrupted at least once by a hetero-atom or in which ether residue the alkylene chain is attached to a cyclic ether group of (b) an alkyl residue on which the alkylene chain is interrupted by an acid amide group. Representative of dyes specified are those of the formulae:- The dyeing agent may also contain wetting or washing agents such as alkylbenzene-sulphonates, fatty alcohol sulphates, alkyl sulphonates, fatty acid ethanolamides and addition products of ethylene oxide with fatty acids and fatty alcohols; permanent waving agents such as thioglycollic acid, thiolactic acid, mercaptopropane- and mercaptobutanesulphonic acids; thickeners such as methyl cellulose, starch, fatty alcohols, petroleum jelly, paraffin oil and fatty acids; and other dyes. The dyeing agent may be in the form of a cream shampoo. In examples the dyes are incorporated into creams containing cetyl-stearyl alcohol, coconut alcohol, fatty alcohol sulphate and ammonia, which may also contain sodium 2 : 4-dinitronaphthol sulphonate (3), the sodium salt of the mono-(4-amino-3-nitro-anilide) of maleic acid (5), 4-amino-3-nitro-phenyl urea (8) or ammonium thioglycollate (13) or in which the fatty alcohol sulphate is replaced by an ethylene oxide/fatty alcohol addition product (10). In a further example the cream contains paraffin oil, fatty alcohol sulphate and ammonia. German Specification 1,087,565 is referred to.
    • 8. 发明授权
    • Anthraquinone dyestuffs, their preparation and use and dichroic material
containing these anthraquinone dyestuffs
    • 蒽醌染料,其制备和使用以及含有这些蒽醌染料的二色性物质
    • US4689171A
    • 1987-08-25
    • US774112
    • 1985-09-09
    • Martin BlunckUwe ClaussenFriedrich W. KrockRutger Neeff
    • Martin BlunckUwe ClaussenFriedrich W. KrockRutger Neeff
    • C09B1/00C09B1/02C09B1/10C09B1/14C09B1/20C09B1/22C09B1/28C09B1/32C09B1/50C09B1/503C09B1/514C09B1/515C09B1/54C09B1/58C09B1/60C09B1/62C09K19/60G02F1/13G02F1/137C09K19/10C07C97/24C09B1/16
    • C09B1/58C09B1/02C09B1/20C09B1/50C09B1/542C09K19/603
    • Dyestuffs of the formula ##STR1## in which Y.sub.1, Y.sub.2, Y.sub.3, Y.sub.4 designate hydrogen, halogen, nitro, amino, alkylamino, arylamino, cycloalkylamino, aralkylamino, alkylthio, arylthio, cycloalkylthio, aralkylthio or hydroxyl, it being possible for the hydrocarbon radicals to be sustituted, with the proviso that(a) at least one of the substituents Y.sub.1, Y.sub.2, Y.sub.3 or Y.sub.4 does not denote hydrogen,(b) a maximum of two of the substituents Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 designate halogen and either(c.sub.1) X.sub.1, X.sub.3 represent halogen, --R.sub.1, --OR.sub.1 or --SR.sub.1, R.sub.1 denoting optionally substituted alkyl, it being possible for the alkyl chain to be substituted by an oxygen atom or several non-adjacent oxygen atoms, optionally substituted aryl, optionally substituted cycloalkyl, optionally substituted aralkyl or an optionally substituted heterocyclic radical and X.sub.2 designating hydrogen, or(c.sub.2) X.sub.1, X.sub.2 denote halogen, ##STR2## m' designating 0, 1, 2, or 3, m designating 0, 2 or 3,R.sub.2 designating halogen, --CF.sub.3, --CN, --OR.sub.1, --SR.sub.1, --R.sub.1, ##STR3## R.sub.3 designating hydrogen or R.sub.2 and R.sub.4 designating hydrogen, alkyl, halogen, alkoxy or --CO.sub.2 R.sub.1 andX.sub.3 representing hydrogen, or(c.sub.3) X.sub.1 designates halogen,X.sub.2 designates --OR.sub.1 or --SR.sub.1 andX.sub.3 designates hydrogen,their preparation and use and dichroic material containing these anthraquinone dyestuffs.
    • 其中Y 1,Y 2,Y 3,Y 4表示氢,卤素,硝基,氨基,烷基氨基,芳基氨基,环烷基氨基,芳烷基氨基,烷硫基,芳硫基,环烷基硫基,芳烷硫基或羟基的式Ⅰ的染料, (a)至少一个取代基Y1,Y2,Y3或Y4不表示氢,(b)最多两个取代基Y1,Y2,Y3和Y4表示卤素, (c1)X1,X3表示卤素,-R1,-OR1或-SR1,R1表示任选取代的烷基,烷基链可能被氧原子或若干不相邻的氧原子取代,任选取代的芳基 ,任选取代的环烷基,任选取代的芳烷基或任选取代的杂环基,和指定氢的X2,或(c2)X1,X2表示卤素,指定0,1,2或3的卤素,或“IMAGE” ,指定0,2或3,R2表示卤素,-CF 3,-CN, - 指定氢或R 2和R 4的R 3表示氢,烷基,卤素,烷氧基或表示氢的-CO 2 R 1和X 3,或(c 3)X 1表示卤素,X 2表示 -OR1或-SR1和X3表示氢,它们的制备和用途以及含有这些蒽醌染料的二色性材料。