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    • 2. 发明授权
    • Process for producing MEK-modified resorcin/formalin resin parallelly carrying out recovery and reuse of specified raw material
    • 生产MEK改性的间苯二酚/福尔马林树脂并行进行特定原料回收和再利用的方法
    • US08519083B2
    • 2013-08-27
    • US12443489
    • 2007-09-27
    • Nobuo KaifuHiroshi NakaokaKaoru Abe
    • Nobuo KaifuHiroshi NakaokaKaoru Abe
    • C08G6/02
    • C08G8/22
    • The present invention relates to a process for producing an MEK-modified resorcinol-formalin resin, in which recovery and reuse of the specific raw materials (water, calcium chloride, and methyl ethyl ketone (MEK)), and methanol contained in formalin, are carried out in parallel. Using this closed-system recycle production method, a resorcinol-formalin resin aqueous solution can be obtained, wherein the resin aqueous solution has a reaction product concentration of from 30 to 80%, moderate flowability with a pH of 6 to 10, a calcium chloride concentration of 100 ppm or less, a peak area corresponding to a resorcinol monomer of from 3 to 9% to the entire peak area obtained by gel permeation chromatography analysis, and a peak area corresponding to resorcinol pentanuclear or higher nuclear bodies of from 30 to 55% to the entire peak.
    • 本发明涉及一种生产MEK改性间苯二酚 - 福尔马林树脂的方法,其中甲醛中所含的特定原料(水,氯化钙,甲基乙基酮(MEK))和甲醇的回收和再利用是 并行执行 使用这种封闭系统循环生产方法,可以得到间苯二酚 - 福尔马林树脂水溶液,其中树脂水溶液的反应产物浓度为30〜80%,pH为6〜10的适度的流动性,氯化钙 浓度为100ppm以下,与通过凝胶渗透色谱分析得到的全部峰面积相当于间苯二酚单体的峰面积为3〜9%,对应于间苯二酚五核或更高核体的峰面积为30〜55 %到整个高峰。