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1. 发明授权

US09732179B2 Dilithium initiators 有权
公开(公告)号：US09732179B2
公开(公告)日：2017-08-15
申请号：US15189233
申请日：2016-06-22
申请人： Fina Technology, Inc.
发明人： Alexander Pleska
IPC分类号： C08F4/46 , C08F4/56 , C08F2/00 , C08F36/00 , C08F297/04 , C08F136/06 , C09J147/00 , C09J153/02
CPC分类号： C08F297/042 , C08F136/06 , C08L47/00 , C09J147/00 , C09J153/02
摘要： Disclosed herein are highly active dilithio initiators prepared from high molecular weight dienes (C≧6) and methods for the preparation of such compounds. These dilithio initiators result in greater control over polymer microstructure and provide useful polymers and oligomers with low vinyl incorporation.

2. 发明申请

US20070066776A1 Catalyst composition II 失效
公开(公告)号：US20070066776A1
公开(公告)日：2007-03-22
申请号：US11602897
申请日：2006-11-21
申请人： Gregory Solan , Christopher Davies
发明人： Gregory Solan , Christopher Davies
IPC分类号： C08F4/56
CPC分类号： C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
摘要： This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.

3. 发明申请

US20050272852A1 Natural rubber-rich composition and tire with tread thereof 审中-公开
标题翻译：天然橡胶丰富的组合物和具有胎面的轮胎
公开(公告)号：US20050272852A1
公开(公告)日：2005-12-08
申请号：US10859524
申请日：2004-06-02
申请人： Paul Sandstrom , Adel Halasa , Wen-Liang Hsu , John Verthe , Chad Jasiunas
发明人： Paul Sandstrom , Adel Halasa , Wen-Liang Hsu , John Verthe , Chad Jasiunas
IPC分类号： B60C1/00 , C08F4/56 , C08K3/04 , C08K3/36 , C08L7/00 , C08L9/06 , C08L21/00
CPC分类号： C08L7/00 , B60C1/0016 , C08K3/04 , C08K3/36 , C08L9/06 , C08L21/00 , C08L2666/02 , C08L2666/08
摘要： This invention relates to a natural rubber-rich rubber composition and tire with tread thereof. A partial replacement of the natural rubber in the natural rubber-rich tire tread is accomplished by an inclusion of a specialized trans 1,4-styrene/butadiene copolymer rubber characterized by having a combination of bound styrene content and microstructure limitations. The tire tread rubber composition is comprised of a blend of the specialized trans 1,4-styrene/butadiene rubber and cis 1,4-polyisoprene natural rubber optionally together with at least one additional diene-based elastomer in which the natural rubber remains a major portion of the elastomers in the tread rubber composition. A significant aspect of the invention is a partial replacement of natural cis 1,4-polyisoprene rubber in the tread rubber composition. The specialized trans 1,4-styrene/butadiene rubber has a bound styrene content in a range of from about 15 to about 35 percent and a microstructure of its polybutadiene portion composed of from about 50 to about 80 percent trans 1,4-isomeric units, from about 10 to about 20 percent cis 1,4-isomeric units and from about 2 to about 10 percent vinyl 1,2-isomeric units; preferably a Mooney (ML1+4) at 100° C. viscosity value in a range of from about 50 to about 100, alternately from about 50 to about 85, and preferably a glass transition temperature (Tg) in a range of from about −60° C. to about −90° C.
摘要翻译：本发明涉及一种富含天然橡胶的橡胶组合物和具有胎面的轮胎。天然橡胶丰富的轮胎胎面中天然橡胶的部分替代是通过包含特征在于具有结合苯乙烯含量和微结构限制的组合的专用反式1,4-苯乙烯/丁二烯共聚物橡胶来实现的。轮胎胎面橡胶组合物由专门的反式1,4-苯乙烯/丁二烯橡胶和顺式1,4-聚异戊二烯天然橡胶的混合物组成，任选与至少一种另外的二烯基弹性体共混，其中天然橡胶保持主要橡胶组合物中的部分弹性体。本发明的一个重要方面是在胎面橡胶组合物中部分替代天然顺式1,4-聚异戊二烯橡胶。专用的反式1,4-苯乙烯/丁二烯橡胶具有约15至约35％范围内的结合苯乙烯含量，其聚丁二烯部分的显微组织由约50至约80％的反式1,4-异构体单元，约10至约20％的顺式1,4-异构体单元和约2至约10％的乙烯基1,2-异构体单元; 优选为100℃时的门尼（ML1 + 4），粘度值为约50至约100，交替为约50至约85，优选玻璃化转变温度（Tg）为约 - 60℃至约-90℃

4. 发明授权

US6103842A Process and catalyst system for synthesizing random trans SBR with low vinyl microstructure 失效
标题翻译：用于合成具有低乙烯基显微组织的随机反式SBR的工艺和催化剂体系
公开(公告)号：US6103842A
公开(公告)日：2000-08-15
申请号：US72492
申请日：1998-05-04
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Laurie Elizabeth Austin
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Laurie Elizabeth Austin
IPC分类号： B60C1/00 , C08F4/54 , C08F4/56 , C08F236/10 , C08F4/50 , C08F36/06
CPC分类号： C08F236/10 , C08F4/565
摘要： The process and catalyst system of this invention can be utilized to synthesize a highly random styrene-butadiene rubber having a high trans content by solution polymerization. The styrene-butadiene rubber made by the process of this invention can be utilized in tire tread rubbers that exhibit improved wear characteristics. This invention more specifically reveals a catalyst system for use in exothermal polymerizations which consists essentially of (a) an organolithium compound, (b) a barium alkoxide and (c) a lithium alkoxide. The subject invention further discloses a process for synthesizing a random styrene-butadiene rubber having a low vinyl content by a process which comprises copolymerizing styrene and 1,3-butadiene under isothermal conditions in an organic solvent in the presence of a catalyst system which consists essentially of (a) an organolithium compound, (b) a barium alkoxide and (c) a lithium alkoxide.
摘要翻译：本发明的方法和催化剂体系可用于通过溶液聚合合成具有高反式含量的高度无规的苯乙烯 - 丁二烯橡胶。通过本发明方法制备的苯乙烯 - 丁二烯橡胶可用于表现出改善的磨损特性的轮胎胎面橡胶。本发明更具体地揭示了一种用于放热聚合的催化剂体系，其基本上由（a）有机锂化合物，（b）烷氧基钡和（c）醇盐锂组成。本发明还公开了一种合成具有低乙烯基含量的无规苯乙烯 - 丁二烯橡胶的方法，该方法包括在等温条件下在有机溶剂中在催化剂体系存在下共聚苯乙烯和1,3-丁二烯的方法，所述催化剂体系基本上组成（a）有机锂化合物，（b）钡醇盐和（c）醇锂。

5. 发明授权

US4139690A Process for preparing conjugated diene polymers 失效
标题翻译：制备共轭二烯聚合物的方法
公开(公告)号：US4139690A
公开(公告)日：1979-02-13
申请号：US769038
申请日：1977-02-16
申请人： Yoshikazu Torigoe , Noboru Ohshima , Masaaki Watanabe , Eitaro Okuya
发明人： Yoshikazu Torigoe , Noboru Ohshima , Masaaki Watanabe , Eitaro Okuya
IPC分类号： C08F4/00 , C08F2/08 , C08F4/42 , C08F36/00 , C08F36/04 , C08F4/56
CPC分类号： C08F36/04
摘要： A process for preparing conjugated diene polymers by either polymerization of one or more monomers selected from a group of conjugated diene compounds or copolymerization of a conjugated diene compound with an alkenyl aromatic compound, using an organolithium initiator in a hydrocarbon solvent, characterized in that the polymerization is carried out in the presence of(1) one or more anionic surface active agent having a group --SO.sub.3 M or --OSO.sub.3 M (where M is an alkali metal) and(2) one or more Lewis bases.
摘要翻译：通过使用一种或多种选自一组共轭二烯化合物的单体或共轭二烯化合物与烯基芳族化合物的共聚合来制备共轭二烯聚合物的方法，使用有机锂引发剂在烃溶剂中，其特征在于聚合在（1）具有基团-SO 3 M或-OSO 3 M（其中M是碱金属）的一种或多种阴离子表面活性剂的存在下进行和（2）一种或多种路易斯碱。

6. 发明授权

US3944528A Solution diene elastomers by alkyl lithium catalysis 失效
标题翻译：溶液二烯弹性体通过烷基锂催化
公开(公告)号：US3944528A
公开(公告)日：1976-03-16
申请号：US549416
申请日：1975-02-12
申请人： Frederick C. Loveless
发明人： Frederick C. Loveless
IPC分类号： C08F236/10 , C08F4/56
CPC分类号： C08F236/10
摘要： This invention relates to a solution process for preparing copolymers of a conjugated diene hydrocarbon and a vinyl-substituted aromatic hydrocarbon using a potassium-modified organolithium catalyst. The Li/K molar ratio is varied depending upon whether a random or pseudorandom copolymer is desired and depending on whether an aliphatic hydrocarbon or aromatic hydrocarbon solvent or a mixture of such solvents is used. The invention includes the pseudorandom copolymers formed by the process of the invention, such copolymers being characterized, in part, by having blocks with two to four units of the vinyl-substituted aromatic hydrocarbon interspersed throughout the copolymer chain.
摘要翻译：本发明涉及使用改性有机锂催化剂制备共轭二烯烃和乙烯基取代芳烃的共聚物的溶液方法。 Li / K摩尔比取决于是否需要随机或伪随机共聚物并且取决于是使用脂族烃还是芳族烃溶剂或这些溶剂的混合物而变化。本发明包括通过本发明的方法形成的伪随机共聚物，这种共聚物的特征在于部分地具有散布在整个共聚物链中的具有2-4个单元的乙烯基取代的芳烃的嵌段。

7. 发明授权

US09260537B2 Modified conjugated diene rubber, method and composition thereof 有权
标题翻译：改性共轭二烯橡胶，其方法和组成
公开(公告)号：US09260537B2
公开(公告)日：2016-02-16
申请号：US13654839
申请日：2012-10-18
申请人： TSRC CORPORATION
发明人： Chi-Chen Hsieh , Fu Lin , Chi-Ta Tsai , Hui-Kai Lin , Bo-Han Lin
IPC分类号： C08C19/22 , C08C19/44 , C08F8/30 , C08F36/08 , C08F4/56 , C08F36/04 , C08F36/06 , C08C19/25 , C08K3/36
CPC分类号： C08C19/44 , C08C19/22 , C08C19/25 , C08F4/56 , C08F8/30 , C08F36/04 , C08F36/06 , C08F36/08 , C08K3/36 , C08L15/00
摘要： A method of forming modified conjugated diene rubber includes (a) reacting an alkali metal ion-containing conjugated diene rubber with a first modifier having a structural formula (I), wherein R1, R2, R3 are each independently selected from the group consisting of C1-C12 of alkyl and C2-C12 of alkenyl groups and C6-C12 of aromatic group, and R4 is selected from the group consisting of C1-C12 of alkyl, C2-C12 of alkenyl, C1-C12 of alkoxy groups and C6-C12 of aromatic group; and (b) adding a second modifier having a structural formula (II) after (a), HO—R5—Y (II) wherein R5 is selected from the group consisting of C1-C12 of alkylene, C2-C12 of alkenylene, C3-C12 of alicyclic groups and C6-C12 of aromatic group, and Y is selected from the group consisting of oxygen-containing C1-C12 group and nitrogen-containing, C1-C12 group, wherein Y has the oxygen atom or the nitrogen atom directly connected to a carbon atom of R5.
摘要翻译：形成改性共轭二烯橡胶的方法包括（a）使含碱金属离子的共轭二烯橡胶与具有结构式（I）的第一改性剂反应，其中R1，R2，R3各自独立地选自C1 -C 12的烷基和C 2 -C 12的芳基，R 4选自烷基的C 1 -C 12，烯基的C 2 -C 12，烷氧基的C 1 -C 12和C 6 -C 12 的芳族基团; 和（b）在（a）之后加入具有结构式（II）的第二改性剂，其中R 5选自亚烷基的C 1 -C 12，亚烯基的C 2 -C 12，亚烯基的C 3 -C -C12和芳基的C6-C12，Y选自含氧的C1-C12基团和含氮的C1-C12基团，其中Y具有氧原子或氮原子直接连接到R5的碳原子。

8. 发明授权

US07151147B2 Method for producing polymers using conjugated dienes and vinyl aromatic compounds, polymers produced according to said method and use thereof 有权
公开(公告)号：US07151147B2
公开(公告)日：2006-12-19
申请号：US10523180
申请日：2003-07-24
申请人： Herbert Koch , Wolfgang Adametz
发明人： Herbert Koch , Wolfgang Adametz
IPC分类号： C08F4/56 , C08F236/10
CPC分类号： C08F36/04 , C08C19/44 , C08F4/565 , C08F4/48
摘要： This invention relates to a process for producing polymerisates by anionic polymerization in an inert reaction medium using conjugated dienes and vinylaromatic compounds in the presence of a catalyst, co-catalyst, and randomizer. Further, the invention relates to the polymerisates produced thereby and their uses.

9. 发明授权

US6140444A Catalyst system, process, and silicone compositions 有权
标题翻译：催化剂体系，工艺和硅酮组合物
公开(公告)号：US6140444A
公开(公告)日：2000-10-31
申请号：US232728
申请日：1999-01-19
申请人： Michael P. Levandoski , Hsien-Kun Chu
发明人： Michael P. Levandoski , Hsien-Kun Chu
IPC分类号： B01J31/12 , C08F4/56 , C08F299/08 , C08G77/08 , C08G77/20 , C08G77/38 , C08G77/42 , C08G77/445 , C08G77/458 , C08G77/46 , C08K3/36 , C08K5/541 , C08K5/5419 , C08K5/5425 , C08K5/544 , C08L83/06 , C08L83/07
CPC分类号： C08G77/20 , C08G77/08 , C08G77/42
摘要： The invention relates to a catalyst system for reacting a silanol group with an alkoxysilane containing a polymerizable ethylenically unsaturated group. The catalyst system includes an organo-lithium reagent and a hydroxylamine. The catalyst system, permits reaction of the silanol group with alkoxysilanes containing rapidly polymerizable ethylenically unsaturated groups, such as an acryloxyalkyl group, for instance an acryloxypropyl group.
摘要翻译：本发明涉及一种使硅烷醇基与含有可聚合烯属不饱和基团的烷氧基硅烷反应的催化剂体系。催化剂体系包括有机锂试剂和羟胺。催化剂体系允许硅烷醇基团与含有快速聚合的烯属不饱和基团的烷氧基硅烷如丙烯酰氧基烷基例如丙烯酰氧基丙基反应。

10. 发明授权

US5973086A Process for the living anionic polymerization of alkyl (methacrylic) monomers using a novel initiator system 失效
标题翻译：使用新型引发剂体系进行烷基（甲基丙烯酸）单体活性阴离子聚合的方法
公开(公告)号：US5973086A
公开(公告)日：1999-10-26
申请号：US774035
申请日：1996-12-27
申请人： Durairaj Baskaran , Swaminathan Sivaram
发明人： Durairaj Baskaran , Swaminathan Sivaram
IPC分类号： C08F4/10 , C08F4/56 , C08F120/12 , C08F120/14 , C08F20/14
CPC分类号： C08F120/12 , C08F120/14 , C08F4/565
摘要： A process for the living anionic polymerization of alkyl(meth)acrylic monomers, involving polymerizing the monomers in the presence of an initiator comprising a carbanion and a metal or nonmetal salt of perchloric acid. The initiator has the formula (I): ##STR1## wherein R.sub.1 =a linear or branched alkyl group having one to six carbon atoms, R.sub.2 =a phenyl or alkyl group having one to six carbon atoms, R.sub.3 =a phenyl or an ester group and M.sup.+ is an alkali, alkaline earth metal or quarternary ammonium cation containing 1-8 carbon atoms in an alkyl group thereof.
摘要翻译：涉及（甲基）丙烯酸烷基酯单体的活性阴离子聚合的方法，包括在包含碳负离子和高氯酸的金属或非金属盐的引发剂存在下聚合单体。引发剂具有式（I）：其中R1 =具有1-6个碳原子的直链或支链烷基，R2 =苯基或具有1-6个碳原子的烷基，R3 =苯基或酯基，M +是在其烷基中含有1-8个碳原子的碱金属，碱土金属或季铵阳离子。

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