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1. 发明授权

US5973086A Process for the living anionic polymerization of alkyl (methacrylic) monomers using a novel initiator system 失效
标题翻译：使用新型引发剂体系进行烷基（甲基丙烯酸）单体活性阴离子聚合的方法
公开(公告)号：US5973086A
公开(公告)日：1999-10-26
申请号：US774035
申请日：1996-12-27
申请人： Durairaj Baskaran , Swaminathan Sivaram
发明人： Durairaj Baskaran , Swaminathan Sivaram
IPC分类号： C08F4/10 , C08F4/56 , C08F120/12 , C08F120/14 , C08F20/14
CPC分类号： C08F120/12 , C08F120/14 , C08F4/565
摘要： A process for the living anionic polymerization of alkyl(meth)acrylic monomers, involving polymerizing the monomers in the presence of an initiator comprising a carbanion and a metal or nonmetal salt of perchloric acid. The initiator has the formula (I): ##STR1## wherein R.sub.1 =a linear or branched alkyl group having one to six carbon atoms, R.sub.2 =a phenyl or alkyl group having one to six carbon atoms, R.sub.3 =a phenyl or an ester group and M.sup.+ is an alkali, alkaline earth metal or quarternary ammonium cation containing 1-8 carbon atoms in an alkyl group thereof.
摘要翻译：涉及（甲基）丙烯酸烷基酯单体的活性阴离子聚合的方法，包括在包含碳负离子和高氯酸的金属或非金属盐的引发剂存在下聚合单体。引发剂具有式（I）：其中R1 =具有1-6个碳原子的直链或支链烷基，R2 =苯基或具有1-6个碳原子的烷基，R3 =苯基或酯基，M +是在其烷基中含有1-8个碳原子的碱金属，碱土金属或季铵阳离子。

2. 发明公开

US20230322981A1 CURABLE RESIN COMPOSITION, CURED PRODUCT, DIFFRACTIVE OPTICAL ELEMENT, MULTILAYER DIFFRACTIVE OPTICAL ELEMENT, AND OXIDE NANOPARTICLES 审中-公开
公开(公告)号：US20230322981A1
公开(公告)日：2023-10-12
申请号：US18148031
申请日：2022-12-29
申请人： FUJIFILM Corporation
发明人： Masahiro TAKATA , Masashi ONO , Naozumi SHIRAIWA
IPC分类号： C08F120/12 , C08K3/22
CPC分类号： C08F120/12 , C08K3/22 , C08K2003/2213 , C08K2003/2231
摘要： An object of the present invention is to provide a cured product which is suitable as a material for a layer of low refractive index in a multilayer diffractive optical element, can exhibit a desired chromatic aberration reducing effect over a near-infrared wavelength region to a shortwave infrared wavelength region in a case of being used in the multilayer diffractive optical element, and can exhibit high transmittance in this wavelength range; a curable resin composition suitable for obtaining this cured product; and a diffractive optical element and a multilayer diffractive optical element including this cured product. Provided are a curable resin composition which includes oxide nanoparticles including indium and cerium, a monofunctional or higher functional (meth)acrylate compound, and a dispersant; a cured product formed of the curable resin composition; a diffractive optical element and a multilayer diffractive optical element; and oxide nanoparticles used in this composition.

3. 发明公开

US20230159678A1 METHODS OF POLYMERIZATION WITH AROMATIC THIOL INITIATORS 审中-公开
公开(公告)号：US20230159678A1
公开(公告)日：2023-05-25
申请号：US18011106
申请日：2021-06-16
申请人： The Regents of the University of Colorado, a body corporate
发明人： Christopher N. Bowman , Dillon Love
IPC分类号： C08F120/38 , C08F120/12
CPC分类号： C08F120/38 , C08F120/12
摘要： Provided herein are methods of using aryl thiols as photoinitiators. The thiol compounds are useful as oxygen insen-sitive photoinitiators for applications such as bulk polymerizations and for specialty polymer synthesis by preparing aromatic thiol functionalized macroinitiators.

4. 发明授权

US09688601B2 Process for preparing (meth)acrylates 有权
公开(公告)号：US09688601B2
公开(公告)日：2017-06-27
申请号：US14924018
申请日：2015-10-27
申请人： Evonik Roehm GmbH
发明人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
IPC分类号： C07C67/03 , C08F20/18 , C08F120/12
CPC分类号： C07C67/03 , C08F20/18 , C08F120/12 , C07C69/54
摘要： Process for preparing (meth)acrylates of the formula (I) CH2═C(R1)—CO—O—R2 (I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2═C(R1)—CO—OR3 (II) with an alcohol of the formula (III) HO—R2 (III) in the presence of an amount of a suitable catalyst which catalyzes the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.0 l/kg, measured in liters of oxygen per kilogram of (meth)acrylate of the formula (I), where the volume of oxygen introduced is calculated at a temperature of 25° C. and a pressure of 101 325 pascal. The resulting (meth)acrylates can surprisingly be processed to particularly high molecular weight emulsion polymers which are, for example, outstandingly suitable for use as flow resistance reducers in mineral oil extraction.

5. 发明申请

US20150232591A1 (METH)ACRYLATE COMPOSITION 有权
标题翻译：（METH）丙烯酸酯组合物
公开(公告)号：US20150232591A1
公开(公告)日：2015-08-20
申请号：US14429598
申请日：2013-08-09
申请人： AUTONETWORKS TECHNOLOGIES, LTD. , SUMITOMO WIRING SYSTEMS, LTD. , SUMITOMO ELECTRIC INDUSTRIES, LTD. , KYUSHU UNIVERSITY
发明人： Tatsuya Hase , Kazuo Nakashima , Makoto Mizoguchi
IPC分类号： C08F122/10 , C07D307/16 , C08F120/20 , C08F120/12 , C08F120/14 , C08F120/28 , C07C69/54 , C07C69/602
CPC分类号： C08F122/105 , C07C69/54 , C07C69/602 , C07D307/16 , C08F2/48 , C08F8/30 , C08F20/10 , C08F120/12 , C08F120/14 , C08F120/20 , C08F120/28 , C08F2220/343 , C08G18/4825 , C08G18/672 , C08G18/73 , C08G65/3322 , C08L33/00 , C08L71/02 , C09D4/06 , C09D133/08 , C09D133/10 , C09D133/14 , C09D175/16 , C09J4/06 , C09J133/08 , C09J133/10 , C09J133/14 , C09J175/16 , C08L75/08 , C08G18/48
摘要： Presented is a (meth)acrylate composition that can be cured even in an unirradiated portion that is not reached by light. The (meth)acrylate composition contains a compound having one or more vinyl groups in a molecular structure thereof. The compound has a ratio of a molecular weight thereof to a number of the vinyl groups of 300 or lower. The composition generates a heat of reaction during photopolymerization thereof, and the heat of reaction causes thermal polymerization of the composition.
摘要翻译：呈现即使在未被光照射的未照射部分也能固化的（甲基）丙烯酸酯组合物。（甲基）丙烯酸酯组合物含有其分子结构中具有一个或多个乙烯基的化合物。该化合物的分子量与乙烯基数的比例为300以下。该组合物在其光聚合期间产生反应热，反应热引起组合物的热聚合。

6. 发明授权

US09908904B2 Triorganoborane-amino functionalized nanoparticles, compositions, and methods 有权
公开(公告)号：US09908904B2
公开(公告)日：2018-03-06
申请号：US14652462
申请日：2013-12-11
申请人： 3M INNOVATIVE PROPERTIES COMPANY
发明人： James E. Garbe , Jimmie R. Baran, Jr.
IPC分类号： C01B35/14 , B32B5/16 , C07F7/18 , C08F120/14 , C08F120/68 , C08F120/12 , C09C1/36 , C09C3/08 , C09C3/12 , C09C1/30 , B82Y30/00
CPC分类号： C07F7/1804 , B82Y30/00 , C01B35/146 , C01P2004/64 , C08F120/12 , C08F120/14 , C08F120/68 , C09C1/3081 , C09C1/3684 , C09C3/08 , C09C3/12 , Y10T428/2982
摘要： Surface-modified nanoparticles wherein each nanoparticle includes an inorganic core and surface modifying groups, wherein the surface modifying groups include at least one triorganoborane-amine complex having the structure —Z—NHR1—B(R2)3 wherein: Z is a divalent organic group; R1 is H or an organic group; and each R2 is independently an organic group bound to the boron atom through a carbon atom. The inorganic core is typically an inorganic oxide core, e.g., silica, zirconia, or alumina.

7. 发明申请

US20170335043A1 TRIACRYLATE COMPOUNDS AND METHODS FOR PRODUCING THE SAME, AND COMPOSITIONS 审中-公开
公开(公告)号：US20170335043A1
公开(公告)日：2017-11-23
申请号：US15521142
申请日：2015-10-21
申请人： MITSUBISHI GAS CHEMICAL COMPANY, INC.
发明人： Umi YOKOBORI , Taketo IKENO , Hideyuki SATO , Ryuji HASEMI
IPC分类号： C08F265/06 , C08F10/00 , C08F120/12 , G01R33/46
CPC分类号： C08F265/06 , C07C67/03 , C07C67/08 , C07C69/54 , C08F10/00 , C08F20/20 , C08F120/12 , C08F290/067 , C08F2810/20 , C09D4/00 , C09D11/101 , C09J4/00 , G01R33/46 , C08F2222/1026
摘要： The invention provides a triacrylate compound represented by the following formula (1). In the formula, each R is independently a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a halogen atom, R1 and R2 are each independently a linear or branched alkyl group having 1 to 6 carbon atoms, and R3 is a linear or branched alkyl group having 1 to 6 carbon atoms or a hydroxymethyl group.

8. 发明申请

US20150274860A1 FLAME-RESISTANT FIBER BUNDLE, CARBON FIBER BUNDLE, AND PROCESSES FOR PRODUCING THESE 审中-公开
标题翻译：耐火纤维布，碳纤维布及其制造方法
公开(公告)号：US20150274860A1
公开(公告)日：2015-10-01
申请号：US14433036
申请日：2012-12-26
申请人： MITSUBISHI RAYON CO., LTD.
发明人： Yoshihiro Sako , Hiroyuki Nakao , Tomoyuki Kotani , Yasuhito Tokoro , Hiroshi Tategaki , Akiyoshi Kogame , Kazunori Sumiya , Kenji Hirano
IPC分类号： C08F120/12 , D01F9/21 , D01F6/16
CPC分类号： C08F120/12 , C08L33/18 , D01D5/16 , D01D5/253 , D01D10/02 , D01F6/16 , D01F9/21 , D01F9/225 , D02J13/001 , Y10T428/2918
摘要： A process for producing a flame-resistant fiber bundle, the process comprising a step in which a flame-resistant fiber bundle (1) having a single-fiber density ρF1 of 1.26 g/cm3 to 1.36 g/cm3 is brought into contact sequentially with a heater group having a surface temperature TH of 240° C. to 400° C. under the following conditions (A), (B), and (C) to obtain a flame-resistant fiber bundle (2) having a single-fiber density ρF2 of 1.33 g/cm3 to 1.43 g/cm3: (A) the heater Hn+1 with which the fiber bundle is brought into contact “n+1”-thly has a highter temperature than the heater Hn with which the fiber bundle is brought into contact “n”-thly; (B) the total contact time between the fiber bundle and the heater group is 10 seconds to 360 seconds; and (C) the contact time between the fiber bundle and each heater is 2 seconds to 20 seconds.
摘要翻译：一种制造阻燃纤维束的方法，该方法包括使具有1.26g / cm 3至1.36g / cm 3的单纤维密度F1的阻燃纤维束（1）接触的步骤在具有以下条件（A），（B）和（C）的情况下，依次具有表面温度TH为240℃至400℃的加热器组，以获得具有单个的阻燃纤维束（2） - 纤维密度为1.33g / cm 3至1.43g / cm 3的F2：（A）纤维束与“n + 1”接触的加热器Hn + 1的温度比加热器Hn高，使纤维束“n”接触; （B）纤维束和加热器组之间的总接触时间为10秒至360秒; （C）纤维束与各加热器的接触时间为2秒〜20秒。

9. 发明申请

US20100280205A1 PROCESS FOR PREPARING (METH)ACRYLATES 有权
标题翻译：制备（甲基）丙烯酸酯的方法
公开(公告)号：US20100280205A1
公开(公告)日：2010-11-04
申请号：US12745703
申请日：2008-09-29
申请人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
发明人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
IPC分类号： C08F120/12 , C07C69/54
CPC分类号： C07C67/03 , C08F20/18 , C08F120/12 , C07C69/54
摘要： Process for preparing (meth)acrylates of the formula (I) CH2═C(R1)—CO—O—R2 (I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2═C(R1)—CO—OR3 (II) with an alcohol of the formula (III) HO—R2 (III) in the presence of an amount of a suitable catalyst which catalyses the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.0 l/kg, measured in litres of oxygen per kilogram of (meth)acrylate of the formula (I), where the volume of oxygen introduced is calculated at a temperature of 25° C. and a pressure of 101 325 pascal. The resulting (meth)acrylates can surprisingly be processed to particularly high molecular weight emulsion polymers which are, for example, outstandingly suitable for use as flow resistance reducers in mineral oil extraction.
摘要翻译：制备式（I）的（甲基）丙烯酸酯的方法，其中R 1是氢或甲基，R 2是饱和或不饱和的，直链或支链的脂族或环状的具有6至22个碳原子的烷基或（C 6 -C 14） - 芳基 - （C 1 -C 8） - 烷基; 通过使式II CH 2 = C（R 1）-CO-OR 3（II）的（甲基）丙烯酸酯与式（III）的醇HO-R 2（III）在一定量的合适的催化剂存在下反应，催化反应和一定量的酚聚合抑制剂或两种或多种酚聚合抑制剂的组合，其足以抑制不期望的聚合; 反应是通过输入或引入反应混合物中进行的，所述反应混合物是由一定量的氧气或足够抑制不期望的聚合的氧气混合物的反应而产生的，并且该方法的特征在于特定的总氧气输入量小于或等于至1.0l / kg，以公斤式（I）的（甲基）丙烯酸酯计，氧气的导入量在25℃，压力为101 325帕斯卡时计算。所得到的（甲基）丙烯酸酯可以令人惊奇地加工成特别高分子量的乳液聚合物，例如非常适合用作矿物油提取中的阻流剂。

10. 发明授权

US06388026B1 Process for the preparation of macromers 失效
标题翻译：制备大分子单体的方法
公开(公告)号：US06388026B1
公开(公告)日：2002-05-14
申请号：US08906141
申请日：1997-08-05
申请人： J. David Campbell , Michihiro Kaai , David D. Schatz , Fouad Teymour
发明人： J. David Campbell , Michihiro Kaai , David D. Schatz , Fouad Teymour
IPC分类号： C08F2018
CPC分类号： C08F2/02 , C08F120/12
摘要： A process for preparing low molecular weight homomacromers and comacromers which includes (a) charging a reactor with (i) ethylenically unsaturated monomers selected from the group consisting of acrylic monomers or monoalkenyl aromatic monomers and (ii) if said ethylenically unsaturated monomer is not a thermally initiating monomer, a free radical polymerizable initiator, to form a polymerizable reaction charge. The reaction charge is heated during continuous mixing in the reactor to reaction temperature in the range from about 180° C. to about 500° C. for a residence time greater than 5 minutes to form the low molecular weight homomacromers or comacromers. If the residence time is 60 minutes or less, the reaction temperature is greater than 270° C. and if the reaction charge is a mixture of acrylic monomer and monoalkenyl monomer and the residence time is 60 minutes or less then the reaction temperature is greater than 310° C.
摘要翻译：一种制备低分子量同质异构体和共聚物的方法，其包括（a）向（i）选自丙烯酸单体或单链烯基芳族单体的烯键式不饱和单体和（ii）所述烯属不饱和单体不是热的引发单体，自由基可聚合引发剂，形成可聚合反应的电荷。将反应装料在反应器中连续混合期间加热至约180℃至约500℃范围内的反应温度，停留时间大于5分钟以形成低分子量同型异构体或可变光体。如果停留时间为60分钟以下，则反应温度大于270℃，如果反应物为丙烯酸单体和单烯基单体的混合物，停留时间为60分钟以下，则反应温度大于 310℃

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