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    • 2. 发明授权
    • Solid block and random elastomeric copolymers
    • 固体块和无规弹性共聚物
    • US5717035A
    • 1998-02-10
    • US740116
    • 1996-10-22
    • Thomas S. CoolbaughFrederick C. LovelessDemetreos N. Matthews
    • Thomas S. CoolbaughFrederick C. LovelessDemetreos N. Matthews
    • C08F8/00C08F8/04C08F236/04C08F297/02C08F297/04C08L53/00C08L53/02C08F8/20C08F8/36C08F8/46
    • C08L53/025C08F236/04C08F297/02C08F297/04C08F297/046C08F8/00C08F8/04C08L53/00Y10S525/94
    • There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of a polymerized conjugated diene of at least 5 carbon atoms, such as isoprene, and B is a block of a polymer of a conjugated diene, different from that of formula (1), of at least 4 carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from an aryl-substituted olefin, such as styrene, and the conjugated diene used to polymerize the block I, the second middle polymer block of the diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of double bonds to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing and selectively hydrogenating the polymers.
    • 公开了包含至少一个三嵌段IBI的线性嵌段共聚物,其中I是至少5个碳原子的聚合共轭二烯的嵌段,例如异戊二烯,B是共轭二烯的聚合物的嵌段,不同于 具有至少4个碳原子的式(1)的化合物,例如1,3-丁二烯。 B嵌段被选择性地氢化,而每个I嵌段保留足够量的其原始不饱和度以硫化共聚物。 还公开了一种替代的线性嵌段共聚物,其含有由芳基取代的烯烃如苯乙烯制成的第一聚合物嵌段的至少一个三嵌段,和用于聚合嵌段I的共轭二烯,二烯的第二中间聚合物嵌段 用于聚合嵌段B和与第一聚合物嵌段相同的第三聚合物嵌段。 在该替代共聚物中,中间嵌段也被选择性氢化,从而使末端聚合​​物嵌段具有足够量的双键硫化共聚物。 聚合物可以通过含有乙烯基不饱和键的末端嵌段交联或官能化。 还公开了由与线性嵌段共聚物相同的单体制备的无规和星形支链嵌段和无规共聚物。 还公开了制备和选择性氢化聚合物的方法。
    • 4. 发明授权
    • Solid block and random elastomeric copolymers
    • 固体块和无规弹性共聚物
    • US5268427A
    • 1993-12-07
    • US952127
    • 1992-09-28
    • Thomas S. CoolbaughFrederick C. LovelessDemetreos N. Matthews
    • Thomas S. CoolbaughFrederick C. LovelessDemetreos N. Matthews
    • C08F8/00C08F8/04C08F236/04C08F297/02C08F297/04C08L53/00C08L53/02
    • C08L53/025C08F236/04C08F297/02C08F297/04C08F297/046C08F8/00C08F8/04C08L53/00Y10S525/94
    • There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of a polymerized conjugated diene of at least 5 carbon atoms, such as isoprene, and B is a block of a polymer of a conjugated diene, different from that of formula (1), of at least 4 carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from an aryl-substituted olefin, such as styrene, and the conjugated diene used to polymerize the block I, the second middle polymer block of the diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of double bonds to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random and star-branched block and random copolymers made from the same monomers as the linear block copolymers.Also disclosed are methods of producing and selectively hydrogenating the polymers.
    • 公开了包含至少一个三嵌段IBI的线性嵌段共聚物,其中I是至少5个碳原子的聚合共轭二烯的嵌段,例如异戊二烯,B是共轭二烯的聚合物的嵌段,不同于 具有至少4个碳原子的式(1)的化合物,例如1,3-丁二烯。 B嵌段被选择性地氢化,而每个I嵌段保留足够量的其原始不饱和度以硫化共聚物。 还公开了一种替代的线性嵌段共聚物,其含有由芳基取代的烯烃如苯乙烯制成的第一聚合物嵌段的至少一个三嵌段,和用于聚合嵌段I的共轭二烯,二烯的第二中间聚合物嵌段 用于聚合嵌段B和与第一聚合物嵌段相同的第三聚合物嵌段。 在该替代共聚物中,中间嵌段也被选择性氢化,从而使末端聚合​​物嵌段具有足够量的双键来硫化共聚物。 聚合物可以通过含有乙烯基不饱和键的末端嵌段交联或官能化。 还公开了由与线性嵌段共聚物相同的单体制备的无规和星形支链嵌段和无规共聚物。 还公开了制备和选择性氢化聚合物的方法。