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1. 发明授权

US07608747B2 Aromatics hydrogenolysis using novel mesoporous catalyst system 失效
标题翻译：使用新型介孔催化剂体系进行芳烃氢解
公开(公告)号：US07608747B2
公开(公告)日：2009-10-27
申请号：US11234619
申请日：2005-09-23
申请人： Bala Ramachandran , Lawrence L. Murrell , Martin Kraus , Zhiping Shan , Philip J. Angevine
发明人： Bala Ramachandran , Lawrence L. Murrell , Martin Kraus , Zhiping Shan , Philip J. Angevine
IPC分类号： C07C5/29 , C07C5/31
CPC分类号： C10G45/52 , C10G45/60 , C10G45/64 , Y10S585/94
摘要： A process for the selective ring opening of ring-containing hydrocarbons in a feed stream having at least 10% ring-containing hydrocarbons includes contacting the feed stream with a ring opening catalyst containing a metal or a mixture of metals active for the selective ring opening of the ring-containing hydrocarbons on a support material, wherein the support material is a non-crystalline, porous inorganic oxide or mixture of inorganic oxides having at least 97 volume percent interconnected mesopores based on micropores and mesopores, and wherein the ring-containing hydrocarbons have at least one C6 ring and at least one substituent selected from the group consisting of fused 5- or 6-membered rings, alkyl, cycloalkyl and aryl groups.
摘要翻译：在具有至少10％含环烃的进料流中选择性开环含环烃的方法包括使进料流与开环催化剂接触，该开环催化剂含有金属或活性成分的金属混合物，用于选择性开环支撑材料上的含环烃，其中所述载体材料是非结晶多孔无机氧化物或具有基于微孔和介孔的至少97体积％互连的介孔的无机氧化物混合物，并且其中所述含环烃具有至少一个C 6环和至少一个选自稠合5-或6-元环，烷基，环烷基和芳基的取代基。

2. 发明授权

US07301064B1 Ethylbenzene conversion and xylene isomerization processes and catalysts therefor 失效
标题翻译：乙苯转化和二甲苯异构化方法及其催化剂
公开(公告)号：US07301064B1
公开(公告)日：2007-11-27
申请号：US11225976
申请日：2005-09-14
申请人： Paula L. Bogdan , Patrick C. Whitchurch , Robert B. Larson , James E. Rekoske , Dimitri A. Trufanov , Victor C. Patton , Suheil F. Abdo
发明人： Paula L. Bogdan , Patrick C. Whitchurch , Robert B. Larson , James E. Rekoske , Dimitri A. Trufanov , Victor C. Patton , Suheil F. Abdo
IPC分类号： C07C5/29 , C07C4/12
CPC分类号： B01J29/48 , B01J29/44 , B01J37/20 , B01J2229/20 , B01J2229/42 , C07C5/2775 , Y02P20/52 , C07C15/08
摘要： Catalysts comprising a combination of molecular sieve having a pore diameter of from about 4 to 8 angstroms and a catalytically-effective amount of molybdenum hydrogenation component in an amorphous aluminum phosphate binder provide processes for isomerizing xylene and dealkylating ethylbenzene in feed streams that exhibit stability, selectivity and low ring loss.
摘要翻译：包含孔径为约4至8埃的分子筛和无定形磷酸铝磷酸盐粘合剂中的催化有效量的钼氢化组分的催化剂提供异构化二甲苯和在进料流中脱烷基化乙苯的方法，其显示出稳定性，选择性和低环损耗。

3. 发明授权

US07091390B2 Hydrocarbon conversion processes using catalysts comprising UZM-8 and UZM-8HS compositions 有权
标题翻译：使用包含UZM-8和UZM-8HS组合物的催化剂的烃转化方法
公开(公告)号：US07091390B2
公开(公告)日：2006-08-15
申请号：US10828989
申请日：2004-04-21
申请人： Deng-Yang Jan , Raelynn M. Miller , Mathias P. Koljack , John E. Bauer , Paula L. Bogdan , Gregory J. Lewis , Gregory J. Gajda , Susan C. Koster , Michael G. Gatter , Jaime G. Moscoso
发明人： Deng-Yang Jan , Raelynn M. Miller , Mathias P. Koljack , John E. Bauer , Paula L. Bogdan , Gregory J. Lewis , Gregory J. Gajda , Susan C. Koster , Michael G. Gatter , Jaime G. Moscoso
IPC分类号： C07C2/68 , C07C5/29 , C07C2/58
CPC分类号： C07C2/66 , B01J29/06 , B01J29/70 , B01J29/7007 , B01J29/74 , B01J2229/42 , C01B39/026 , C01B39/06 , C01B39/065 , C01B39/48 , C01P2002/72 , C07C5/2708 , C07C6/126 , C07C2529/70 , C10G29/205 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G47/14 , C10G47/20 , C10G49/06 , C10G49/08 , Y02P20/52 , C07C15/073 , C07C15/085 , C07C15/08
摘要： Hydrocarbon conversion processes using a new family of zeolites identified as UZM-8 and UZM-8HS are described. The UZM-8 and UZM-8HS are related in that the UZM-8HS are derived from the UZM-8 zeolite by treating the UZM-8 with a fluoro-silicate salt, an acid, etc. The UZM-8 and -8HS have unique x-ray diffraction patterns. These zeolites can be used in alkylation of aromatics, transalkylation of aromatics, isomerization of aromatics and alkylation of isoparaffins.
摘要翻译：描述了使用识别为UZM-8和UZM-8HS的新型沸石族的烃转化方法。 UZM-8和UZM-8HS与UZM-8HS衍生自UZM-8沸石相关，通过用氟硅酸盐，酸等处理UZM-8。UZM-8和-8HS具有独特的X射线衍射图。这些沸石可用于芳族化合物的烷基化，芳烃的烷基转移，芳族化合物的异构化和异构烷烃的烷基化。

4. 发明授权

US5254794A Isomerization catalysts and preparation thereof 失效
标题翻译：异构化催化剂及其制备方法
公开(公告)号：US5254794A
公开(公告)日：1993-10-19
申请号：US935757
申请日：1992-08-26
申请人： An-hsiang Wu
发明人： An-hsiang Wu
IPC分类号： B01J27/053 , B01J37/04 , C07C5/22 , C07C5/27 , C07C5/29 , C07C6/10 , C07C5/13
CPC分类号： C07C6/10 , B01J27/053 , B01J37/04 , C07C5/2246 , C07C5/2789 , C07C5/29 , C07C2101/14 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2527/053 , C07C2527/126 , C07C2527/167
摘要： Isomerization catalyst compositions are prepared by heating aluminum chloride, at least one of several metal salts (preferably CuSO.sub.4), at least one of several inorganic support materials (alumina, silica, aluminum phosphate and combinations thereof) and at least one chlorinated hydrocarbon (preferably CCl.sub.4) at a temperature of about 40.degree.-90.degree. C. The dried catalyst compositions are used for the isomerization of C.sub.5 -C.sub.10 cycloalkanes and/or C.sub.4 -C.sub.10 alkanes.
摘要翻译：异构化催化剂组合物通过加热氯化铝，几种金属盐（优选CuSO 4）中的至少一种，几种无机载体材料（氧化铝，二氧化硅，磷酸铝及其组合）中的至少一种和至少一种氯化烃（优选CCl 4 ）。在干燥的催化剂组合物用于C5-C10环烷烃和/或C4-C10烷烃的异构化。

5. 发明授权

US5087785A Processes for preparing alkylated indanes and tetrahydronaphthalenes 失效
标题翻译：烷基化烷烃和四氢萘的制备方法
公开(公告)号：US5087785A
公开(公告)日：1992-02-11
申请号：US621688
申请日：1990-12-03
申请人： Walter C. Frank
发明人： Walter C. Frank
IPC分类号： C07C5/29
CPC分类号： C07C5/29 , C07C2102/08 , C07C2102/10
摘要： Improved processes for the production of secondary alkyl indanes, particularly mixtures of 1,1,3,5-tetramethyl-3-isopropylindanes and 1,3,3,5-tetramethyl-3-isopropylindane, and alkylated tetrahydronaphthalenes, particularly mixtures of 1,1,3,4,4,6-hexametyl-1,2,3,4-tetrahydronaphthalene and 1,1,2,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene, are described. In the processes of the invention, alkylated tetrahydronaphthalenes or secondary alkyl indanes are isomerized in the presence of a Lewis acid and a solvent which may be a halogenated or unhalogenated solvent and, optionally, a phase transfer agent, to produce, in the case of an alkylated tetrahydronaphthalene starting material, a secondary alkyl indane, and in the case of a secondary alkyl indane starting material, an aklylated tetrahydronaphthalene. The Lewis acid is present in the reaction medium in an amount of less than about 50 mole percent based on the amount of the alkylated tetrahydronaphthalene or secondary alkylindane charged. The subject processes produce the desired compounds at a high rate of reaction, using better, safer, more convenient, or less expensive process methodology than many processes known heretofore.
摘要翻译：用于制备仲烷基烷烃，特别是1,1,3,5-四甲基-3-异丙基丁烷和1,3,3,5-四甲基-3-异丙基茚的混合物的改进方法和烷基化四氢萘，特别是1， 1,3,4,4,6-六甲基-1,2,3,4-四氢化萘和1,1,2,4,4,6-六甲基-1,2,3,4-四氢化萘。在本发明的方法中，烷基化四氢萘或仲烷基烷基烷烃在路易斯酸和可以是卤化或非卤化溶剂的溶剂和任选的相转移剂的存在下异构化，以产生烷基化四氢萘原料，仲烷基二氢化茚，在仲烷基二氢化茚起始原料的情况下为烷基化四氢萘。路易斯酸以反应介质中的烷基化四氢萘或仲烷基二烷基的加入量少于约50摩尔％的量存在。使用比迄今为止已知的许多方法更好，更安全，更方便或更便宜的方法方法，本发明方法以高反应速率产生所需化合物。

6. 发明授权

US5036035A Solid strong acid catalyst process for the production of the same and use thereof 失效
标题翻译：固体强酸催化剂生产方法及其用途
公开(公告)号：US5036035A
公开(公告)日：1991-07-30
申请号：US326418
申请日：1989-03-21
申请人： Shigeo Baba , Yukio Shibata , Takahiro Kawamura , Hideo Takaoka , Tsuguo Kimura , Kazuo Kousaka , Yoshihiro Minato , Naruo Yokoyama , Kozo Iida , Tetsuya Imai
发明人： Shigeo Baba , Yukio Shibata , Takahiro Kawamura , Hideo Takaoka , Tsuguo Kimura , Kazuo Kousaka , Yoshihiro Minato , Naruo Yokoyama , Kozo Iida , Tetsuya Imai
IPC分类号： B01J27/053 , C07C2/54 , C07C2/58 , C07C4/06 , C07C5/22 , C07C5/27 , C07C5/29 , C10G45/60
CPC分类号： C10G45/60 , B01J27/053 , C07C2/54 , C07C2/58 , C07C4/06 , C07C5/226 , C07C5/2724 , C07C5/2791 , C07C5/29 , C07C2521/04 , C07C2521/06 , C07C2523/08 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/053
摘要： A solid strong acid catalyst useful for hydrocarbon reactions, especially for the skeletal isomerization of paraffinic hydrocarbons is provided by supporting sulfate (SO.sub.4) and at least one member selected from Group VIII metals on a support consisting of hydroxides and oxides of Group IV metals and Group III metals and mixtures thereof and then calcining and stabilizing the catalyst.
摘要翻译：通过将硫酸盐（SO 4）和至少一种选自第Ⅷ族金属的成员在由IV族金属的氢氧化物和氧化物组成的载体上进行支撑，提供了可用于烃反应的固体强酸催化剂，特别是用于链烷烃的骨架异构化 III金属及其混合物，然后煅烧和稳定催化剂。

7. 发明授权

US4912274A Azaphospholenes and use thereof 失效
标题翻译： Azaphospholenes及其用途
公开(公告)号：US4912274A
公开(公告)日：1990-03-27
申请号：US385614
申请日：1989-07-26
申请人： Gunther Wilke , Jaroslaw Monkiewicz , Herbert Kuhn
发明人： Gunther Wilke , Jaroslaw Monkiewicz , Herbert Kuhn
IPC分类号： B01J31/14 , B01J31/00 , B01J31/22 , B01J31/24 , C07B61/00 , C07C2/04 , C07C2/32 , C07C5/29 , C07C5/31 , C07C13/12 , C07C13/40 , C07C15/44 , C07F9/6564 , C07F9/6584
CPC分类号： C07F9/6584 , C07C2/04 , C07C5/31 , C07C2101/10 , C07C2102/42 , C07C2531/02 , C07C2531/14 , C07C2531/22
摘要： The invention relates to azaphospholenes of the type ##STR1## wherein R.sub.1 and R.sub.2 may be alkyl, aryl and aralkyl groups, processes for preparing same and the use thereof.

8. 发明授权

US4892720A Substituted aluminosilicate compositions and process for preparing same 失效
标题翻译：取代硅铝酸盐组合物及其制备方法
公开(公告)号：US4892720A
公开(公告)日：1990-01-09
申请号：US604179
申请日：1984-04-26
申请人： Gary W. Skeels , Richard Ramos
发明人： Gary W. Skeels , Richard Ramos
IPC分类号： C10G11/05 , B01J20060101 , B01J29/06 , B01J29/50 , B01J29/88 , B01J29/89 , C01B20060101 , C01B39/00 , C01B39/04 , C01B39/06 , C01B39/24 , C01B39/26 , C01B39/30 , C01B39/38 , C07B61/00 , C07C1/00 , C07C2/12 , C07C2/54 , C07C4/18 , C07C5/02 , C07C5/22 , C07C5/25 , C07C5/29 , C07C5/41 , C07C6/12 , C07C9/02 , C07C9/14 , C07C11/02 , C07C13/02 , C07C15/02 , C07C67/00 , C10G35/095 , C10G45/12 , C10G45/54 , C10G45/64 , C10G47/16 , C10G49/08 , C10G50/00
CPC分类号： C10G45/54 , B01J29/88 , B01J29/89 , C01B39/065 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/222 , C07C5/41 , C10G45/12 , C10G45/64 , C10G47/16 , C10G50/00 , C07C2529/88 , C07C2529/89
摘要： Molecular sieve compositions are prepared by extracting aluminum and substituting titanium and/or iron for extracted aluminum to give molecular sieve products containing framework titanium and/or iron atoms. The process of preparing the titanium and/or iron-containing molecular sieves involves contacting a starting zeolite with a solution or slurry of a fluoro salt of titanium and/or iron under effective process conditions to provide for aluminum extraction and substitution of titanium and/or iron.
摘要翻译：通过提取铝并用钛和/或铁代替提取的铝制备分子筛组合物，得到含有骨架钛和/或铁原子的分子筛产物。制备钛和/或含铁分子筛的方法包括在有效的工艺条件下使起始沸石与钛和/或铁的氟盐的溶液或浆料接触以提供钛和/或钛的铝的提取和取代铁。

9. 发明授权

US4721559A Boron, aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts 失效
标题翻译：硼，铝和镓全氟链烷磺酸盐和树脂磺酸盐催化剂
公开(公告)号：US4721559A
公开(公告)日：1988-01-26
申请号：US920329
申请日：1986-10-17
申请人： George A. Olah
发明人： George A. Olah
IPC分类号： B01J31/02 , B01J31/10 , C07C2/54 , C07C2/66 , C07C5/22 , C07C5/27 , C07C5/29 , C07C17/10 , C08G65/20 , C10G35/06
CPC分类号： C08G65/20 , B01J31/0227 , B01J31/10 , C07C17/10 , C07C2/54 , C07C2/66 , C07C5/2266 , C07C5/2794 , C07C5/29 , B01J2231/321 , B01J2231/4205 , B01J2231/52 , C07C2531/025 , C07C2531/10 , Y02P20/582
摘要： Boron, aluminum and gallium C.sub.1 -C.sub.18 perfluoroalkanesulfonates (CF.sub.3 (CF.sub.2).sub.n SO.sub.3).sub.3 M (M=B, A1, Ga; n=0-17) as well as perfluororesin sulfonates such as Nafionates are new, highly effective Friedel-Crafts catalysts. In contrast to volatile aluminum and boron trihalides, the Group III-B perfluoroalkanesulfonates are generally of low or no volatility and, except for boron triflate and some of its homologs, only sparingly soluble incommon organic solvents. This allows their use as solid or supported Friedel-Crafts catalysts of wide utility and scope in continuous heterogenous catalytic processes. At the same time, boron triflate and related lower perfluoroalkanesulfonates are particularly efficient soluble catalysts in solution reactions.
摘要翻译：硼，铝和镓C1-C18全氟烷基磺酸盐（CF3（CF2）nSO3）3M（M = B，A1，Ga; n = 0-17）以及全氟化物磺酸盐如Nafionates是新的，高效的Friedel-Crafts催化剂。与挥发性铝和三卤化硼相反，III-B族全氟烷基磺酸盐通常具有低挥发性或不挥发性，除了三氟甲磺酸硼和其一些同系物外，只有微溶于有机溶剂。这允许它们用作固体或支持的Friedel-Crafts催化剂，其在连续异质催化过程中具有广泛的用途和范围。同时，三氟甲磺酸硼和相关的低级全氟烷基磺酸盐在溶液反应中是特别有效的可溶性催化剂。

10. 发明授权

US4222800A Isomerization of endo-endo hexacyclic olefinic dimer of norbornadiene 失效
标题翻译：降冰片二烯的内六角六环烯属二聚体的异构化
公开(公告)号：US4222800A
公开(公告)日：1980-09-16
申请号：US964855
申请日：1978-11-30
申请人： Harry K. Myers, Jr. , Abraham Schneider
发明人： Harry K. Myers, Jr. , Abraham Schneider
IPC分类号： C07C5/03 , C07C5/29 , C07C13/64 , C10L1/04 , C06B23/00
CPC分类号： C10L1/04 , C07C13/64 , C07C5/03 , C07C5/29 , C07C2103/90 , C07C2521/04
摘要： The endo-endo olefinic hexacyclic dimer of 2,5-norbornadiene is isomerized using an acidic alumina catalyst. The isomerization temperatures ranges from between about an ambient temperature to about 300.degree. C. The isomerized product, after hydrogenation, can be used as a high density missile fuel.
摘要翻译：使用酸性氧化铝催化剂将2,5-降冰片二烯的内 - 内烯烃六环二聚体异构化。异构化温度范围为约环境温度至约300℃。氢化后的异构化产物可用作高密度导弹燃料。

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