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    • 2. 发明授权
    • Process for chemicals and energy recovery from waste liquors
    • 从废液中回收化学品和能源的过程
    • US4808264A
    • 1989-02-28
    • US15137
    • 1987-01-28
    • Jean-Erik Kignell
    • Jean-Erik Kignell
    • B01D53/52B01D53/77C10J3/46D21C11/04D21C11/06D21C11/12D21C11/14
    • D21C11/063C10J3/485C10J3/84C10K1/004C10K1/02C10K1/04C10K1/101C10K1/103C10K1/122D21C11/127C10J2300/0959C10J2300/1223C10J2300/1606C10J2300/1675C10J2300/1687Y02P20/129Y02P70/24Y10S423/03
    • Process for recovering chemicals and energy from cellulose waste liquors preferably black kraft liquor obtained in a paper pulp sulphate process, comprising the following, three distinct and separate steps: In the first step the concentrated black liquor is gasified in a pressurized gasification reactor by so called flash-pyrolysis at 700.degree. to 1300.degree. C., normally 800.degree.-900.degree. C., whereby an energy rich gas is produced, and in which the inorganic chemicals of the black liquor are contained in the form of molten suspended droplets, mainly comprising sodium carbonate and sodium sulphide. In the second step the gas from the gasification reactor is rapidly cooled through direct contact with water, and with green liquor, which is formed when the molten droplets and the hydrogen sulphide are dissolved in the quench liquid. The cooled gas subsequently passes through a scrubber. In the lower section of the scrubber the gas is washed with circulating green liquor, and in the upper section of the scrubber the gas is washed with sodium hydroxide (or carbonate) solution and water for complete removal of any remaining sulfur bearing components in the gas. In the third step the now sulfur and particulate-free gas is used as a fuel for generating steam and, if it should be economically justified, also for production of electric power.
    • PCT No.PCT / SE86 / 00249 Sec。 371日期1987年1月28日 102(e)日期1987年1月28日PCT申请日1986年5月30日PCT出版物 公开号WO86 / 07396 日期:1986年12月18日。从纤维素废液中回收化学品和能量的方法,优选在纸浆硫酸盐方法中获得的黑色硫酸盐液,包括以下三个不同和分离的步骤:在第一步中,将浓缩的黑液气化 通过所谓的快速热解在700〜1300℃(通常为800-900℃)的加压气化反应器,由此产生富能气体,其中黑液的无机化学物质包含在 形式的熔融悬浮液滴,主要包括碳酸钠和硫化钠。 在第二步骤中,来自气化反应器的气体通过与水直接接触而迅速冷却,并且当熔融液滴和硫化氢溶解在骤冷液体中时形成绿色液体。 随后冷却的气体通过洗涤器。 在洗涤器的下部,气体用循环绿液洗涤,在洗涤器的上部,气体用氢氧化钠(或碳酸盐)溶液和水洗涤,以完全除去气体中剩余的含硫成分 。 在第三步中,现在使用无硫和无颗粒气体作为产生蒸汽的燃料,如果经济上合理,也用于生产电力。
    • 3. 发明授权
    • Method for wet combustion of organic material
    • 有机材料湿法燃烧方法
    • US4604957A
    • 1986-08-12
    • US703257
    • 1985-02-20
    • Karl N. Cederquist
    • Karl N. Cederquist
    • D21C11/14F23G7/04
    • D21C11/14
    • The wet method of combusting organic material dispersed in a liquid comprising waste liquor from wood pulping processes in which the organic material is oxidized by contact with air or other oxygenating gases at a temperature ranging between 180.degree. C. and 340.degree. C. and a correspondingly superatmospheric pressure. The combustion of oxygenation is carried out in two steps: namely, a first step in which the organic material is partially oxidized so that the major portion of the organic substances is converted into carbon dioxide and water, and a minor portion is converted to water-soluble low-molecular fatty acids resistant to oxidation; in a second oxidizing step, the residual oxygen-resistant fatty acids are combusted in the presence of a substantial excess of oxygen-enriched air or other molecular-oxygenating gas so as to liberate the total heat of combustion of the organic material and to impart to the resultant gaseous mixture of effluents a molecular oxygen content sufficient to achieve the partial oxidation in the first step.
    • 燃烧分散在包含来自木材制浆过程的废液的液体中的有机材料的湿法,其中有机材料通过与空气或其它氧化气体在180℃至340℃的温度范围内接触而被氧化,并相应地 超大气压。 氧合的燃烧分两步进行:即第一步骤,其中有机材料被部分氧化,使得主要部分的有机物质转化为二氧化碳和水,少量部分转化为水溶性, 耐氧化的可溶性低分子脂肪酸; 在第二氧化步骤中,残留的耐氧脂肪酸在大量过量的富氧空气或其它分子氧化气体的存在下燃烧,以释放有机材料的总燃烧热量并赋予 所得到的流出物气体混合物的分子氧含量足以在第一步中实现部分氧化。
    • 10. 发明授权
    • Reactor having a discontinuous conduit means between surfaces of a
downwardly extending stationary spiral
    • 具有不连续导管的反应器在向下延伸的固定螺旋的表面之间
    • US5171405A
    • 1992-12-15
    • US588993
    • 1990-09-27
    • Louis O. Torregrossa
    • Louis O. Torregrossa
    • B01F3/04B01F5/00B01F5/04B01J8/14B01J10/00B01J10/02B01J19/00C02F1/72C02F1/78C02F11/08D21C9/10D21C11/14
    • D21C11/14B01F5/0057B01F5/0476B01J10/02B01J19/006B01J8/14C02F1/725C02F11/08D21C9/10B01F2003/04319B01F2003/0439B01F3/04099B01J2219/00103B01J2219/0011B01J2219/00162B01J2219/00182B01J2219/00772C02F1/78
    • Organic constituents in a liquid, such as a waste water from a municipal or industrial process (e.g. bleach plant extraction liquor from the bleaching of paper pulp) may proceed effectively without the addition of alkali. When the organic constituents are reacted with an oxygen containing gas at appropriate pressure and temperature conditions, oxidized organics and gaseous acidic products of oxidation (e.g. CO.sub.2) that are produced are continuously and immediately removed from the liquid so that they do not significantly contribute to lowering of the pH of the liquid, so that the reaction may proceed and the liquid remain alkaline. This may be accomplished in a gas sparged hydrocyclone in which the liquid is introduced into the first end of a vortex while oxygen is introduced from exteriorly of the vortex into contact with the liquid, or may be accomplished by causing the liquid to flow in a thin film in a downwardly extending spiral path and removing the acidic gases from a center portion of the spiral path. A reactor for effecting the last mentioned specific procedure includes a pressurized vertical vessel having a downwardly extending stationary spiral surface mounted in the vessel substantially concentric with it. Surface manifestations may be provided on the spiral surface for enhancing mixing of liquid with surrounding gas.
    • 液体中的有机成分,例如来自市政或工业方法的废水(例如漂白纸浆漂白植物提取液)可以有效地进行而不加碱。 当有机成分在合适的压力和温度条件下与含氧气体反应时,产生的氧化有机物和氧化的气态酸性产物(例如CO 2)连续地立即从液体中除去,使得它们不显着地有助于降低 的液体的pH值,使得反应可以进行并且液体保持碱性。 这可以在气体喷射式水力旋流器中完成,其中液体被引入涡流的第一端,而氧气从涡流外部引入与液体接触,或者可以通过使液体以薄的方式流动 膜以向下延伸的螺旋路径并从螺旋路径的中心部分去除酸性气体。 用于实现最后提到的具体方法的反应器包括加压的垂直容器,其具有安装在容器中的与其基本同心的向下延伸的固定螺旋表面。 可以在螺旋表面上提供表面表现,以增强液体与周围气体的混合。