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    • 4. 发明授权
    • Polymer composition and process for treating leather and fur skins
    • 用于处理皮革和毛皮的聚合物组合物和方法
    • US06200640B1
    • 2001-03-13
    • US09147078
    • 1998-11-09
    • Michael KneipAxel KistenmacherPeter DanischGerhard Wolf
    • Michael KneipAxel KistenmacherPeter DanischGerhard Wolf
    • C14C900
    • C09D123/08C14C9/00
    • Aqueous solutions or dispersions of copolymers obtainable by free-radical copolymerization of (a) from 20 to 90% by weight of at least one monoethylenically unsaturated C4-6-dicarboxylic acid or the anhydride thereof, as component A, (b) from 5 to 50% by weight of at least one olefin having 2 to 6 carbon atoms, as component B, (c) from 5 to 50% by weight of at least one hydrophobic comonomer from the group consisting of long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, long-chain amides of acrylic acid or methacrylic acid, and long-chain alkyl vinyl ethers, as component C, (d) from 0 to 40% by weight of further comonomers which can be copolymerized with the above monomers, as component D, where the sum of the amounts of components A, B, C and, if used, D is 100% by weight, followed by at least partial esterification or hydrolysis and neutralization and/or reaction of the carboxyl groups formed during the hydrolysis with bases, for treating leather and/or fur skins.
    • 通过(a)20至90重量%的至少一种单烯属不饱和C4-6二羧酸或其酸酐作为组分A,(b)的自由基共聚获得的共聚物的水溶液或分散体,从5至 50重量%的至少一种具有2至6个碳原子的烯烃作为组分B,(c)5至50重量%的至少一种疏水性共聚单体,其由长链烯烃,长链烯烃, 具有丙烯酸或甲基丙烯酸的链醇,丙烯酸或甲基丙烯酸的长链酰胺和作为组分C的长链烷基乙烯基醚,(d)0至40重量%的可共聚合的另外的共聚单体 上述单体作为组分D,其中组分A,B,C和(如果使用的话)D的量的总和为100重量%,然后至少部分酯化或水解和中和和/或羧基的反应 在用碱水解过程中形成的基团,用于处理皮革和/ 或毛皮。
    • 9. 发明授权
    • Use of amphiphilic copolymers containing a fluorinated monomer to impart waterproofness to leather
    • 使用含有氟化单体的两亲共聚物可赋予皮革防水性
    • US06294103B1
    • 2001-09-25
    • US09297814
    • 1999-05-04
    • Dirk M. Coppens
    • Dirk M. Coppens
    • C14C900
    • C14C9/00
    • The present invention provides an amphiphilic copolymer comprising recurring units (I) and (II), wherein: Rf represents a fluorinated alkyl group having at least 3 carbon atoms; Q and Q′ each independently represents an organic liking group or a chemical linkage; R1 and R2 each independently represents hydrogen or a C1 to C4 alkyl group; and Rh represents a hydrocarbon group having at least 8 carbon atoms and optionally containing 1 to 3 substituents; and a recurring unit comprising at least one carboxylic acid group or salt thereof. The present invention also provides a method for making the above amphiphilic copolymer. The amphiphilic copolymer can be used in a leather treatment to provide waterproofness to the leather.
    • 本发明提供了包含重复单元(I)和(II)的两亲共聚物,其中:Rf表示具有至少3个碳原子的氟化烷基; Q和Q'各自独立地表示有机喜好基团或化学键; R 1和R 2各自独立地表示氢或C 1至C 4烷基; 并且Rh表示具有至少8个碳原子并且任选地含有1至3个取代基的烃基; 和包含至少一个羧酸基团或其盐的重复单元。 本发明还提供了制备上述两亲性共聚物的方法。 两亲性共聚物可以用于皮革处理以为皮革提供防水性。