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1. 发明授权

US4148602A Phosphoramide-hydroxymethyl phosphine condensation products for textile fire retardation 失效
标题翻译：磷酰胺 - 羟甲基膦缩合产物用于纺织品阻燃
公开(公告)号：US4148602A
公开(公告)日：1979-04-10
申请号：US767404
申请日：1977-02-10
申请人： Destin A. LeBlanc , Robert B. LeBlanc
发明人： Destin A. LeBlanc , Robert B. LeBlanc
IPC分类号： C07F9/22 , C07F9/28 , D06M13/285 , D06M9/12
CPC分类号： C07F9/28 , C07F9/224 , D06M13/285 , Y10S428/921 , Y10T442/268
摘要： A water soluble product suitable for rendering textile materials flame retardant is produced by condensing (a) at least one hydroxymethyl phosphorus compound selected from the group consisting of(CH.sub.2 OH).sub.4 P--Y and (CH.sub.2 OH).sub.3 Pwith (b) about 0.33 to 3 times the molar amount of at least one substituted phosphoramide of the formulaPO(NR.sup.1 CH.sub.3)(NR.sup.2 CH.sub.3)(NR.sup.3 CH.sub.3)whereinR.sup.1 and R.sup.2 each independently is H or CH.sub.2 OH,R.sup.3 is H, CH.sub.2 OH, CH.sub.3 or [PO(NR.sup.1 CH.sub.3)NCH.sub.3 ]--.sub.1`R.sup.2, andY is an equivalent amount of at least one anion of an acid, such as chloride, bromide, carbonate, nitrate, sulfate, phosphate or carboxylate.Advantageously, the hydroxymethyl phosphorus compound is tetrakis(hydroxymethyl)phosphonium chloride or tris(hydroxymethyl)-phosphine, and is present in about 1 to 3 times the phosphoramide wherein preferably R.sup.1 and R.sup.2 are hydrogen and R.sup.3 is hydrogen or PO(NHCH.sub.3).sub.2. The condensation product, preferably dissolved in water, is padded onto fabric, preferably a polyester/cotton blend, which is thereafter dried and cured thermally and/or chemically. When a thermal cure is used it is preferred to include an aminoplast in the treatment. The fabrics are flame retardant even after multiple launderings.

2. 发明授权

US4020262A Method of applying phosphoramide-hydroxymethyl phosphine condensation products for textile fire retardation 失效
标题翻译：磷酰胺 - 羟甲基膦缩合产物用于纺织品阻燃的方法
公开(公告)号：US4020262A
公开(公告)日：1977-04-26
申请号：US552501
申请日：1975-02-24
申请人： Destin A. LeBlanc , Robert Bruce LeBlanc
发明人： Destin A. LeBlanc , Robert Bruce LeBlanc
IPC分类号： D06M13/44 , C07F9/24 , C07F9/50 , C08G79/00 , C08G79/02 , C08G79/04 , D06M13/02 , D06M13/322 , D06M13/402 , D06M13/432 , D06M15/673 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/16 , D06M101/30 , D06M101/32 , D06M101/34 , C09K3/28 , C09D5/18
CPC分类号： D06M15/673 , C07F9/5004 , C08G79/04 , Y10S428/921 , Y10T442/268
摘要： A water soluble product suitable for rendering textile materials flame retardant is produced by condensing (a) at least one hydroxymethyl phosphorus compound selected from the group consisting of(CH.sub.2 OH).sub.4 P--Y and (CH.sub.2 OH).sub.3 Pwith (b) about 0.33 to 3 times the molar amount of at least one substituted phosphoramide of the formulaPO(NR.sup.1 CH.sub.3)(NR.sup.2 CH.sub.3)(NR.sup.3 CH.sub.3)whereinR.sup.1 and R.sup.2 each independently is H or CH.sub.2 OH,R.sup.3 is H, CH.sub.2 OH or CH.sub.3, andY is an equivalent amount of at least one anion of an acid, such as chloride, bromide, carbonate, nitrate, sulfate, phosphate or carboxylate.Advantageously, the hydroxymethyl phosphorus compound is tetrakis(hydroxymethyl)phosphonium chloride or tris(hydroxymethyl)phosphine, and is present in about 1 to 3 times the phosphoramide which is preferably tris(N',N",N'"-methyl)phosphoramide [OP(NHCH.sub.3).sub.3 ]. The condensation product, preferably dissolved in water, is padded onto fabric, preferably a polyester/cotton blend, which is thereafter dried and cured thermally and/or chemically. When a thermal cure is used it is preferred to include an aminoplast in the treatment. The fabrics are flame-retardant even after multiple launderings.
摘要翻译：通过将选自（CH 2 OH）4 P-Y和（CH 2 OH）3 P的至少一种羟甲基磷化合物与（b）的至少一种羟甲基磷化合物缩合（a）为约0.33〜3倍，至少一种式PO（NR1CH3）（NR2CH3）（NR3CH3）的取代磷酰胺的摩尔量，其中R 1和R 2各自独立地是H或CH 2 OH，R 3是H，CH 2 OH或CH 3，Y是至少等同量的酸的一个阴离子，如氯化物，溴化物，碳酸盐，硝酸盐，硫酸盐，磷酸盐或羧酸盐。

3. 发明授权

US3936585A Fire retarding textile materials 失效
标题翻译：阻燃纺织材料
公开(公告)号：US3936585A
公开(公告)日：1976-02-03
申请号：US422058
申请日：1973-12-05
申请人： Robert Bruce Leblanc , Destin A. Leblanc
发明人： Robert Bruce Leblanc , Destin A. Leblanc
IPC分类号： D06M13/44 , C07F9/50 , D06M13/02 , D06M13/244 , D06M13/282 , D06M13/285 , D06M13/292 , D06M13/298 , D06M13/322 , D06M13/402 , D06M13/432 , D06M15/667
CPC分类号： D06M13/285 , C07F9/50 , D06M15/667 , Y10S428/921 , Y10T428/31739
摘要： A water soluble product suitable for rendering textile materials fire retardant is produced by condensing a poly (.alpha.-hydroxyalkyl)phosphorus compound of the formula(RCHOH).sub.n (RCHR').sub.4.sub.-n P-Yor(RCHOH).sub.m (RCHR').sub.3.sub.-m Pand a nitrogen compound of the formula RNH.sub.2, HO--R"NH.sub.2 or ##EQU1## wherein R is hydrogen or alkyl of 1 to 3 carbon atoms,R' is OR or ##EQU2## R" is alkylene of 1 to 3 carbon atoms, Y is at least one anion selected from the group consisting of chloride, sulfate, phosphate, acetate and formate,n is an integer from 2 to 4, andm is an integer from 2 to 3,The phosphorus compound being present in about 0.5 to 6 times the molar amount of the nitrogen compound.Advantageously the phosphorus compound is a tetrakis(hydroxy-methyl)phosphonium salt or a tris(hydroxymethyl) phosphine and is present in about 1 to 3 times the nitrogen compound which is preferably ammonia. The condensation product, dissolved in water, is padded onto a fabric, preferably a polyester-cotton blend, which is thereafter dried and cured thermally and/or chemically. The fabrics are fire retardant even after multiple launderings.
摘要翻译：通过将式（RCHOH）n（RCHR'）4-n PY或（RCHOH）m（RCHR'）3-PY的聚（α-羟基烷基）磷化合物缩合成适于提供纺织材料阻燃剂的水溶性产品， mP和式RNH2，HO-R''NH2或R ANGLEN-R''NH2，R的氮化合物，其中R是氢或1至3个碳原子的烷基，R'是OR或RN ANGLE，R R “是1至3个碳原子的亚烷基，Y是至少一个选自氯化物，硫酸盐，磷酸盐，乙酸盐和甲酸盐的阴离子，N是从2到4的整数，M是从2到 3，磷化合物在0.5至6时间内出现了氮化合物的摩尔量。

4. 发明授权

US3970425A Flame retardant process for textile materials including phosphorus, halogen and antimony oxide 失效
标题翻译：纺织材料的阻燃工艺，包括磷，卤素和氧化锑
公开(公告)号：US3970425A
公开(公告)日：1976-07-20
申请号：US461212
申请日：1974-04-15
申请人： Robert Bruce Leblanc , Destin A. Leblanc
发明人： Robert Bruce Leblanc , Destin A. Leblanc
IPC分类号： D06M11/47 , D06M11/56 , D06M11/71 , D06M13/26 , D06M13/44
CPC分类号： D06M11/47 , D06M11/56 , D06M11/71
摘要： An improvement in a process for imparting flame retardant properties to textile materials by reacting the textile materials with phosphorus-containing compounds or salts thereof and aftertreating the textile material with a salt of a heavy metal is disclosed. In the improved process, the phosphorus-containing compounds are applied in correlation with antimony oxide and a polymeric halogen-containing material. Reduced amounts of phosphorus may be affixed on the textile material (thus substantially reducing fabric shrinkage during processing) without substantially adversely affecting the flame retardant properties of the treated material. Titanyl sulfate is utilized as the heavy metal salt. In addition, the treatment is applicable to cellulosic fibers, e.g., cotton or rayon, as well as to wool, silk and other natural and man-made fibers or blends of these fibers.
摘要翻译：公开了通过使纺织材料与含磷化合物或其盐反应并且用重金属的盐对织物材料进行后处理来赋予纺织材料阻燃性能的方法的改进。在改进的方法中，含磷化合物与氧化锑和聚合物含卤素材料有关。减少的磷量可以固定在织物材料上（因此在加工过程中基本上减少了织物收缩），而基本上不利地影响了处理过的材料的阻燃性能。硫酸硫酸盐用作重金属盐。此外，该处理可应用于纤维素纤维，例如棉花或人造纤维，以及羊毛，丝绸和其他天然和人造纤维或这些纤维的混合物。

5. 发明授权

US3963437A Flame retardant process for cellulosic material including cyanamide, phosphonic acid, antimony oxide and polymeric halogen-containing material 失效
标题翻译：纤维素材料的阻燃方法，包括氰胺，膦酸，氧化锑和聚合物含卤素材料
公开(公告)号：US3963437A
公开(公告)日：1976-06-15
申请号：US461106
申请日：1974-04-15
申请人： Destin A. LeBlanc , Robert Bruce LeBlanc
发明人： Destin A. LeBlanc , Robert Bruce LeBlanc
IPC分类号： D06M13/08 , D06M13/288 , D06M13/432 , D06M15/244 , D06M13/30 , D06M13/44
CPC分类号： D06M15/244 , D06M13/08 , D06M13/288 , D06M13/432
摘要： A process for imparting durable flame-retardant properties to cellulosic fiber-containing materials without detrimentally affecting other properties (e.g., shrinkage, hand, etc.) of the material is disclosed. The material is contacted with cyanamide; at least one phosphonic acid represented by the structural formula: ##EQU1## wherein R.sup.1 represents a monovalent radical selected from the group consisting of hydrogen, halogen, hydroxy, lower alkyl and lower alkoxy, and wherein R.sup.2 represents a monovalent radical selected from the group consisting of hydrogen and lower alkyl; antimony oxide; and a polymeric halogen-containing material.
摘要翻译：公开了一种赋予含纤维素纤维素材料持久阻燃性能而不会有害地影响材料的其它性能（如收缩，手等））的方法。将材料与氨腈接触; 由结构式HOOH | PARALLEL R1-CP ANGLE | HOR2表示的至少一种膦酸，其中R1表示选自氢，卤素，羟基，低级烷基和低级烷氧基的一价基团，其中R2表示一价选自氢和低级烷基的基团; 氧化锑和聚合物含卤素材料。

6. 发明授权

US3957881A Fire retarding textile materials 失效
标题翻译：消防纺织材料
公开(公告)号：US3957881A
公开(公告)日：1976-05-18
申请号：US483747
申请日：1974-06-27
申请人： Robert Bruce LeBlanc , Destin A. LeBlanc
发明人： Robert Bruce LeBlanc , Destin A. LeBlanc
IPC分类号： D06M13/44 , C07F9/50 , D06M13/02 , D06M13/244 , D06M13/282 , D06M13/285 , D06M13/292 , D06M13/298 , D06M13/322 , D06M13/402 , D06M13/432 , D06M15/667 , C07F9/02
CPC分类号： D06M13/285 , C07F9/50 , D06M15/667 , Y10S428/921 , Y10T428/31739
摘要： A water soluble product suitable for rendering textile materials fire retardant is produced by condensing a poly (.alpha.-hydroxyalkyl) phosphorus compound of the formula(RCHOH).sub.n (RCHR').sub.4-n P-Y or(RCHOH).sub.m (RCHR').sub.3-m Pand a nitrogen compound of the formula RNH.sub.2, HO-R"NH.sub.2 or ##EQU1## wherein EACH R is independently hydrogen or alkyl of 1 to 3 carbon atoms,R' is OR or ##EQU2## R" is alkylene of 1 to 3 carbon atoms, Y is an equivalent amount of the anion of at least one acid,N is an integer from 2 to 4, andM is 2 or 3,The phosphorus compound being present in about 0.5 to 6 times the molar amount of the nitrogen compound.Advantageously the phosphorus compound is a tetrakis-(hydroxy-methyl)phosphonium salt or a tris(hydroxymethyl) phosphine and is present in about 1 to 3 times the nitrogen compound which is preferably ammonia. The condensation product, dissolved in water, is padded onto a fabric preferably a polyester-cotton blend, which is thereafter dried and cured thermally and/or chemically. The fabrics are fire retardant even after multiple launderings.

7. 发明授权

US4360450A Colloidal aqueous dispersion of an alkali metal polyantimonate and a process of making said 失效
标题翻译：碱金属聚锑酸盐的胶体水分散体及其制备方法
公开(公告)号：US4360450A
公开(公告)日：1982-11-23
申请号：US325079
申请日：1981-11-25
申请人： Destin A. LeBlanc
发明人： Destin A. LeBlanc
IPC分类号： C09K21/02 , D06M11/47 , B01J13/00 , C09K3/28
CPC分类号： D06M11/47 , C09K21/02
摘要： A process for improving the flame-retardant properties of cellulose containing fibrous materials in the absence of halogen compounds which comprises treating said fibrous materials with an effective amount of a colloidal aqueous dispersion of an alkali metal polyantimonate containing a mole ratio of alkali metal to antimony in the dispersion of at least about 0.3:1, and drying said materials is described.
摘要翻译：一种在不存在卤素化合物的情况下改善含纤维材料的阻燃性能的方法，其包括用有效量的含有碱金属与锑的摩尔比的碱金属聚锑酸盐的胶体水分散体处理所述纤维材料描述了至少约0.3:1的分散体和干燥所述材料。

8. 发明授权

US4307148A Flame retardant with improved durability comprising an alkali metal polyantimonate and cellulosic materials treated therewith in the absence of chlorine 失效
标题翻译：具有改进的耐久性的阻燃剂，其包含碱金属聚锑酸盐和在不存在氯的情况下用其处理的纤维素材料
公开(公告)号：US4307148A
公开(公告)日：1981-12-22
申请号：US68260
申请日：1979-08-20
申请人： Destin A. LeBlanc
发明人： Destin A. LeBlanc
IPC分类号： D06M11/47 , B27K3/28 , C09K3/28 , D06M11/04
CPC分类号： D06M11/47 , Y10S428/92 , Y10T428/3188 , Y10T428/31891 , Y10T428/31895 , Y10T428/31906 , Y10T428/31949 , Y10T428/31953 , Y10T428/31964 , Y10T442/2656
摘要： A process for improving the flame-retardant properties of cellulose containing fibrous materials in the absence of halogen compounds which comprises treating said fibrous materials with an effective amount of a colloidal aqueous dispersion of an alkali metal polyantimonate containing a mole ratio of alkali metal to antimony in the dispersion of at least about 0.3:1, and drying said materials is described.
摘要翻译：一种在不存在卤素化合物的情况下改善含纤维材料的阻燃性能的方法，其包括用有效量的含有碱金属与锑的摩尔比的碱金属聚锑酸盐的胶体水分散体处理所述纤维材料描述了至少约0.3:1的分散体和干燥所述材料。

9. 发明授权

US4136037A Phosphoramide-hydroxymethyl phosphine condensation products for textile fire retardation 失效
标题翻译：用于纺织消防的磷酰胺 - 羟甲基苯酚凝胶产品
公开(公告)号：US4136037A
公开(公告)日：1979-01-23
申请号：US872970
申请日：1978-01-27
申请人： Destin A. LeBlanc , Robert B. LeBlanc
发明人： Destin A. LeBlanc , Robert B. LeBlanc
IPC分类号： C07F9/22 , C07F9/28 , D06M13/285 , C09K3/28
CPC分类号： C07F9/28 , C07F9/224 , D06M13/285 , Y10S428/921 , Y10T442/268
摘要： A water soluble product suitable for rendering textile materials flame retardant is produced by condensing (a) at least one hydroxymethyl phosphorus compound selected from the group consisting of(CH.sub.2 OH).sub.4 P--Y and (CH.sub.2 OH).sub.3 Pwith (b) about 0.33 to 3 times the molar amount of at least one substituted phosphoramide of the formulaPO(NR.sup.1 CH.sub.3)(NR.sup.2 CH.sub.3)(NR.sup.3 CH.sub.3)whereinR.sup.1 and R.sup.2 each independently is H or CH.sub.2 OH,R.sup.3 is H, CH.sub.2 OH, CH.sub.3 or [PO(NR.sup.1 CH.sub.3)NCH.sub.3 ]-.sub.1-2 R.sup.2, andY is an equivalent amount of at least one anion of an acid, such as chloride, bromide, carbonate, nitrate, sulfate, phosphate or carboxylate.Advantageously, the hydroxymethyl phosphorus compound is tetrakis(hydroxymethyl)phosphonium chloride or tris(hydroxymethyl)phosphine, and is present in about 1 to 3 times the phosphoramide wherein preferably R.sup.1 and R.sup.2 are hydrogen and R.sup.3 is hydrogen or PO(NHCH.sub.3).sub.2. The condensation product, preferably dissolved in water, is padded onto fabric, preferably a polyester/cotton blend, which is thereafter dried and cured thermally and/or chemically. When a thermal cure is used it is preferred to include an aminoplast in the treatment. The fabrics are flame retardent even after multiple launderings.
摘要翻译：通过将选自（CH 2 OH）4 P-Y和（CH 2 OH）3 P的至少一种羟甲基磷化合物与（b）的至少一种羟甲基磷化合物缩合（a）为约0.33〜3倍，至少一种式PO（NR 1 CH 3）（NR 2 CH 3）（NR 3 CH 3）的取代磷酰胺的摩尔量，其中R 1和R 2各自独立地为H或CH 2 OH，R 3为H，CH 2 OH，CH 3或[PO（NR 1 CH 3）NCH 3] -1 R2和Y是等价量的至少一种酸阴离子，如氯化物，溴化物，碳酸盐，硝酸盐，硫酸盐，磷酸盐或羧酸盐。

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