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    • 1. 发明授权
    • Room temperature cross-linkage aqueous composition
    • 室温交联含水组成
    • US5322890A
    • 1994-06-21
    • US145530
    • 1993-11-04
    • Naotami AndoToshiyuki MasudaTakanori Hatano
    • Naotami AndoToshiyuki MasudaTakanori Hatano
    • C08F230/08C08Z43/04
    • C08F230/08
    • A room temperature cross-linkable aqueous composition which contains an emulsion-polymerized copolymer comprising (I) a reaction product prepared by reacting (A) a monomer having at least one polymerizable double bond and a silyl group represented by the general formula (I): ##STR1## wherein R.sup.1 : monovalent hydrocarbon selected from the group consisting of C.sub.1-10 alkyl, aryl and aralkyl, X: a halogen, alkoxy, hydroxyl, acyloxy, aminoxy, phenoxy, thioalkoxy, or amino, a: 0, 1 or 2, and (B) a basic compound; and (II) a vinyl monomer copolymerizable with said (I) reaction product, and a process for preparing the same. The composition of the present invention has excellent storage stability and excellent room temperature cross-linkability which can be polymerized in stable condition without gelation.
    • 一种室温可交联水性组合物,其含有乳液聚合共聚物,其包含(I)通过使(A)具有至少一个可聚合双键的单体和由通式(I)表示的甲硅烷基反应制备的反应产物: (I)其中R 1:选自C 1-10烷基,芳基和芳烷基,X:卤素,烷氧基,羟基,酰氧基,氨氧基,苯氧基,硫代烷氧基或氨基的一价烃,a:0, 1或2,和(B)碱性化合物; 和(II)可与所述(I)反应产物共聚的乙烯基单体及其制备方法。 本发明的组合物具有优异的储存稳定性和优异的室温可交联性,可以在没有凝胶化的条件下稳定地聚合。