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    • 5. 发明授权
    • Halogen-free flame-retardant thermoplastic polyester or polyamide composition
    • 无卤阻燃热塑性聚酯或聚酰胺组合物
    • US06642288B1
    • 2003-11-04
    • US09479941
    • 2000-01-10
    • Richerdes J. M. Hulskotte
    • Richerdes J. M. Hulskotte
    • C08K53492
    • C08K5/34928C08K5/54C08L77/02C08L67/02C08L77/00
    • The invention relates to a flame-retardant polyester or polyamide composition that contains a combination of a compound derived from triazine and an organic phosphorus compound. By choosing as the triazine compound a melamine condensation product, for example melam, a UL 94 V-0 and GWFI 960° classification can be obtained for glass-fibre reinforced polyester or polyamide with a relatively low concentration of flame-retardant additives, and without good mechanical properties being affected. Unusual is moreover that the CTI value can again be brought to 600 Volt for this glass-fibre reinforced polyester or polyamide. In a preferred embodiment use is made of a phosphorus-containing compound containing more than 14 wt. % P. The use thereof with for example melamine cyanurate results in optimum flame-retardant behaviour at a low total concentration of flame-retardant additives. Important additional aspects are improved crystallisation behaviour and a high stiffness.
    • 本发明涉及含有衍生自三嗪的化合物与有机磷化合物的组合的阻燃聚酯或聚酰胺组合物。 通过选择三嗪化合物,可以获得具有相对低浓度的阻燃添加剂的玻璃纤维增​​强聚酯或聚酰胺的三聚氰胺缩合产物,例如蜜胺,UL 94 V-0和GWFI 960°分级,并且没有 良好的机械性能受到影响。 此外,不寻常的是,对于该玻璃纤维增​​强聚酯或聚酰胺,CTI值可以再次达到600伏。 在优选的实施方案中,使用含有大于14wt。 %P.它与例如三聚氰胺氰尿酸酯的用途在低的阻燃添加剂总浓度下产生最佳的阻燃性能。 重要的附加方面是改善结晶行为和高刚度。
    • 7. 发明授权
    • Polymeric material composition
    • 聚合材料组成
    • US06500887B1
    • 2002-12-31
    • US09719421
    • 2001-02-22
    • Etsuo TobitaYoko NanbuShinichi IshikawaTakashi Ayabe
    • Etsuo TobitaYoko NanbuShinichi IshikawaTakashi Ayabe
    • C08K53492
    • C08K5/3492C08L33/12C08L69/00
    • A polymeric material composition with improved weatherability and resistance to discoloration, comprising 100 parts by weight of a polymer material and 0.001-10 parts by weight of a triazine compound represented by the following formula (I): (wherein A represents ring A; X and Y each independently represents ring A or ring B; R1 represents a C1-C25 alkyl group substituted by a (meth)acryloyloxy group, wherein the alkyl group may further be substituted by a hydroxyl group, a C1-C8 alkoxy group, or a C1-C8 acyloxy group, or the alkyl group my contain, as an insertion, an oxygen atom, a sulfur atom, a carbonyl group, an ester group, an amido group, or an imino group; R2 represents a hydrogen atom; R3, R4, R5 and R6 each independently represents a hydrogen atom, a halogen atom, a hydroxyl group, a C1-C12 alkyl group, a C1-C12 alkenyl group, a C1-C12 alkoxy group, a C1-C12 alkoxycarbonyl group, or an arylalkyl group, wherein the alkyl group, the alkoxy group, the alkoxycarbonyl group, and the arylalkyl group may be substituted by a hydroxyl group, a halogen atom, a C1-C12 alkyl group, a C1-C12 alkoxy group, a sulfonic acid group, a glycidyloxy group, a cyano group, an isocyanate group, or a (meth)acryloyl group, or, the alkyl group, the alkoxy group, the alkoxycarbonyl group, and the arylalkyl group may contain, as an insertion, an oxygen atom, a sulfur atom, a carbonyl group, an ester group, an amido group, or an imino group; and the substitution and the insertion may occur in combination, and R3 represents a hydrogen atom in the case of R3 being in the 5-position.)
    • 具有改善的耐候性和耐变质性的聚合物材料组合物,包含100重量份聚合物材料和0.001-10重量份由下式(I)表示的三嗪化合物:(其中A表示环A; X和 Y各自独立地表示环A或环B; R1表示被(甲基)丙烯酰氧基取代的C1-C25烷基,其中烷基可以进一步被羟基,C1-C8烷氧基或C1 -C8酰氧基或烷基,作为插入,含有氧原子,硫原子,羰基,酯基,酰胺基或亚氨基; R2表示氢原子; R3,R4 R 5和R 6各自独立地表示氢原子,卤素原子,羟基,C 1 -C 12烷基,C 1 -C 12烯基,C 1 -C 12烷氧基,C 1 -C 12烷氧基羰基或芳烷基 基团,其中烷基,烷氧基,烷氧基羰基和th 芳基烷基可以被羟基,卤素原子,C 1 -C 12烷基,C 1 -C 12烷氧基,磺酸基,缩水甘油氧基,氰基,异氰酸酯基或(甲基) )丙烯酰基,或者,烷基,烷氧基,烷氧基羰基和芳基烷基可以含有氧原子,硫原子,羰基,酯基,酰胺基,或 亚胺基 并且取代和插入可以组合发生,并且R 3表示在R3为5-位的情况下的氢原子。
    • 8. 发明授权
    • Trisaryl-1,3,5-triazine ultraviolet light absorbers
    • 三芳基-1,3,5-三嗪紫外光吸收剂
    • US06365652B2
    • 2002-04-02
    • US09848195
    • 2001-05-03
    • Ram Baboo GuptaDennis John JakielaThomas P. SassiGottfried Haacke
    • Ram Baboo GuptaDennis John JakielaThomas P. SassiGottfried Haacke
    • C08K53492
    • C07D251/24C08K5/3492
    • This invention relates generally to amido or carbamate substituted trisaryl-1,3,5-triazines and the use thereof to protect against degradation by environmental forces, inclusive of ultraviolet light, actinic radiation, oxidation, moisture, atmospheric pollutants and combinations thereof. The new class of trisaryl-1,3,5-triazines comprises an aryl ring attached to the triazine ring (and preferably an aryl ring containing a hydroxyl group, either free or blocked to form a latent stabilizer, ortho- to the point of attachment to the triazine ring) substituted with a group comprising a bondable amido/carbamate containing group para- to the point of attachment to the triazine ring. These materials may, under the appropriate circumstances, be bonded to formulations comprising coatings, polymers, resins, organic compounds and the like via reaction of the bondable functionality with the materials of the formulation. A method for stabilizing a material by incorporating such amido or carbamate substituted trisaryl-1,3,5-triazines is also disclosed.
    • 本发明一般涉及酰氨基或氨基甲酸酯取代的三芳基-1,3,5-三嗪及其用于防止包括紫外光,光化辐射,氧化,水分,大气污染物及其组合在内的环境力的降解。 新一类的三芳基-1,3,5-三嗪包括连接到三嗪环上的芳环(和优选含有羟基的芳环,游离或封闭形成潜稳定剂,与附着点相邻 至三嗪环),其被包含与可结合的酰氨基/氨基甲酸酯的基团组成的基团取代成与三嗪环的连接点。 这些材料可以在适当的情况下通过可结合的官能团与制剂的材料的反应与包含涂料,聚合物,树脂,有机化合物等的制剂结合。 还公开了通过并入这种酰氨基或氨基甲酸酯取代的三芳基-1,3,5-三嗪来稳定材料的方法。
    • 10. 发明授权
    • Flame resistant polymer composition and method for rendering polymers flame resistant
    • 耐火聚合物组合物和使聚合物具有阻燃性的方法
    • US06559207B1
    • 2003-05-06
    • US09524819
    • 2000-03-14
    • Larry EnglishCourtney TyvandKevin Kirkland
    • Larry EnglishCourtney TyvandKevin Kirkland
    • C08K53492
    • C08K5/34926C08L23/02
    • A flame resistant composition comprises (a) a polymer; (b) a synergistic mixture comprising(i) from about 0.6 to about 3 percent of a non-halogenated flame retardant compound; and (ii) at least about 0.06 percent of a compatible additive; wherein said percentages are based on weight percent of (a) plus (b), wherein (a) plus (b) equals 100 percent. A method of rendering a polymer flame resistant comprises compounding said polymer with a synergistic mixture comprising (i) from about 0.6 to about 3 percent of a non-halogenated flame retardant compound; and (ii) at least about 0.06 percent of a compatible additive; wherein the percentages are based on weight percent of polymer plus the synergistic mixture, and wherein polymer plus synergistic mixture equals 100 percent.
    • 阻燃组合物包含(a)聚合物; (b)协同混合物,其包含(i)约0.6至约3%的非卤化阻燃化合物; 和(ii)至少约0.06%的相容添加剂; 其中所述百分比基于(a)加(b)的重量百分数,其中(a)加(b)等于100%。 提供聚合物阻燃性的方法包括将所述聚合物与协同混合物混合,所述协同混合物包含(i)约0.6至约3%的非卤化阻燃化合物; 和(ii)至少约0.06%的相容添加剂; 其中百分比基于聚合物加上协同混合物的重量百分比,其中聚合物加协同混合物等于100%。