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    • 3. 发明授权
    • Curable composition and cured article thereof
    • 固化性组合物及其固化物
    • US06495653B1
    • 2002-12-17
    • US09673374
    • 2000-12-08
    • Toshihiko Kinsho
    • Toshihiko Kinsho
    • C08G7500
    • C08G64/42C08G59/40C08G63/914C08G67/04C08G75/00
    • It is an object of the present invention to provide a curable composition retaining curability even at a low temperature of −20 to 5° C. and having a low viscosity at such low temperature, the cured product of which is an artifact having excellent water resistance, chemical resistance, mechanical strength and other physical properties. The present invention is directed to a curable composition which comprises a hetero ring-containing compound (A) of the following general formula (1), a compound (B) having 2 or more electrophilic groups reactive with thiol or —S— groups per molecule, and a compound (C) having 2 or more nucleophilic groups per molecule: wherein n represents an integer of 1 to 10; X1, Y1 and Z1 each represents an oxygen or sulfur atom; R1 represents the residue of a cyclic ether group-containing compound (D) or a hydrogen atom; R2 represents a hydrocarbon group of 2 to 10 carbon atoms.
    • 本发明的目的是提供即使在-20〜5℃的低温下也能保持固化性的固化性组合物,并且在这样低的温度下具有低粘度,其固化产物是具有优异耐水性的假象 ,耐化学性,机械强度等物理性能。 本发明涉及一种可固化组合物,其包含以下通式(1)的含杂环化合物(A),每分子具有与硫醇或-S-基反应的2个以上亲电子基团的化合物(B) 和每分子具有2个以上亲核基团的化合物(C):n表示1〜10的整数, X1,Y1和Z1各自表示氧或硫原子; R1表示含环状醚基的化合物(D)或氢原子的残基; R2表示2〜10个碳原子的烃基。
    • 6. 发明授权
    • Process for producing polyarylene sulfide and apparatus used therein
    • 聚芳硫醚的制造方法及其中使用的装置
    • US06750319B2
    • 2004-06-15
    • US10117193
    • 2002-04-08
    • Yoshinari Koyama
    • Yoshinari Koyama
    • C08G7500
    • C08G75/025C08G75/0204Y10S526/92
    • There are disclosed a process for producing a polyarylene sulfide through polymerization condensation of a sulfur source and a dihalogenated aromatic compound by using a polymerization vessel equipped with baffles that are asymmetrically arranged in the polymerization vessel or in the form of round bar, or by using a polymerization vessel equipped with an agitational blade which is devoid of a notch in the vicinity of the tip portion of the blade, and is in such a configuration as substantially equalizing the spacing between the tip portion thereof and the opposite bottom portion and/or end portion of the polymerization vessel all over the tip portion thereof; and an apparatus used for the process. The process and apparatus enables to form a uniform dispersion state of polymer phase in the vessel and to produce polyarylene sulfide having a high molecular weight.
    • 公开了一种通过使用配备有在聚合容器中不对称排列的挡板或呈圆棒形式的聚合容器的硫源和二卤代芳族化合物的聚合缩合制备聚芳硫醚的方法,或者使用 聚合容器装备有在叶片的尖端部分附近没有切口的搅拌叶片,并且处于这样的构造,使得其顶端部分和相对的底部部分和/或端部部分之间的间隔基本相等 的聚合容器的整个顶端部分; 以及用于该过程的装置。 该方法和装置能够在容器中形成聚合物相的均匀分散状态并产生具有高分子量的聚芳硫醚。