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1. 发明授权

US09034994B2 Systems and methods for real-time catalyst particle size control in a polymerization reactor 有权
标题翻译：聚合反应器中实时催化剂粒度控制的系统和方法
公开(公告)号：US09034994B2
公开(公告)日：2015-05-19
申请号：US14191485
申请日：2014-02-27
申请人： Chevron Phillips Chemical Company LP
发明人： Max P. McDaniel , Joel A. Mutchler
IPC分类号： C08F2/00 , C08F2/12 , C08F2/34 , B01J19/18 , C08F210/14 , B01J8/08 , B01J8/10 , B01J8/18 , B01J8/22 , B01J8/36 , B01J8/00 , B02C4/00 , B02C15/00 , B02C19/06 , B02C23/08
CPC分类号： C08F210/14 , B01J8/0035 , B01J8/082 , B01J8/10 , B01J8/1809 , B01J8/224 , B01J8/36 , B01J2208/00672 , B01J2208/00752 , B01J2219/002 , B01J2219/00202 , B01J2219/00211 , B01J2219/0024 , Y10S526/906 , Y10S526/92 , C08F210/16 , C08F210/08 , C08F2500/18 , C08F210/06
摘要： Polymerization reactor systems providing real-time control of the average particle size of catalyst system components are disclosed. Methods for operating such polymerization reactor systems also are described.
摘要翻译：公开了提供实时控制催化剂体系组分的平均粒度的聚合反应器系统。还描述了操作这种聚合反应器体系的方法。

2. 发明申请

US20140114038A1 METHOD AND APPARATUS FOR DISCHARGING A POLYMER FROM A GAS-PHASE REACTOR 有权
标题翻译：从气相反应器中排出聚合物的方法和装置
公开(公告)号：US20140114038A1
公开(公告)日：2014-04-24
申请号：US14125777
申请日：2012-06-19
申请人： Manfred Hecker , Paulus-Petrus Maria De Lange , Klaus Berhalter , Thomas Andreas Hora , Axel Hamann
发明人： Manfred Hecker , Paulus-Petrus Maria De Lange , Klaus Berhalter , Thomas Andreas Hora , Axel Hamann
IPC分类号： C08F2/34
CPC分类号： C08F2/34 , B01J8/003 , B01J8/008 , B01J8/24 , B01J2208/00274 , B01J2208/00761 , B01J2208/00991 , C08F10/00 , Y10S526/92 , C08F2/01
摘要： Process for discharging polyolefin particles from a gas-phase polymerization reactor of a pressure from 1.0 MPa to 10 MPa to a discharge vessel of a pressure from 0.1 MPa to 1.0 MPa wherein the discharging is carried out discontinuously through at least two discharge lines in which the polyolefin particles are transported horizontally or upwards, process for polymerizing olefins at temperatures of from 30° C. to 160° C. and pressures of from 1.0 MPa to 10 MPa in the presence of a polymerization catalyst in a gas-phase polymerization reactor comprising discharging the obtained polyolefin particles from the gas-phase polymerization reactor by the process for discharging polyolefin particles and apparatus for polymerizing olefins in the gas-phase comprising a polymerization reactor, a discharge vessel and at least two pipes connecting the polymerization reactor and the discharge vessel for discharging polyolefin particles, wherein the discharge lines are constructed in a way that the polyolefin particles conveyed from the polymerization reactor to the discharge vessel are transported horizontally or upwards.
摘要翻译：从压力为1.0MPa至10MPa的气相聚合反应器中将聚烯烃颗粒排放至压力为0.1MPa至1.0MPa的放电容器的方法，其中通过至少两个排放管线不连续地进行排放，其中，聚烯烃颗粒水平或向上输送，在气相聚合反应器中在聚合催化剂存在下，在30℃至160℃的温度和1.0MPa至10MPa的压力下聚合烯烃的方法，包括排出通过排出聚烯烃颗粒的方法从气相聚合反应器获得的聚烯烃颗粒和在气相中聚合烯烃的装置包括聚合反应器，放电容器和连接聚合反应器和放电容器的至少两个管，排出聚烯烃颗粒，其中排出管线以这样的方式构造从聚合反应器输送到放电容器的裂解烯烃颗粒被水平或向上输送。

3. 发明授权

US08114944B2 Olefin polymerisation process 有权
标题翻译：烯烃聚合方法
公开(公告)号：US08114944B2
公开(公告)日：2012-02-14
申请号：US12736864
申请日：2009-05-18
申请人： Marc Parisel , Brent Walworth
发明人： Marc Parisel , Brent Walworth
IPC分类号： C08F2/12 , C08F6/24 , B01D43/00
CPC分类号： C08F10/00 , B01J19/2435 , B01J19/245 , Y10S526/92 , C08F2/14 , C08F2/001
摘要： Continuous process for manufacturing a polyolefin resin in at least two reactors in which in a first polymerization reactor, an olefin is polymerized continuously in the presence of a catalyst and a diluent to produce a first suspension comprising the diluent and polyolefin particles. At least a portion of the first suspension is transferred from the first polymerisation reactor to a second polymerisation reactor where further polymerisation takes place. A further suspension containing diluent and polymer particles is withdrawn from the second reactor and transferred to two separators, in each of which separators a diluent-rich flow and a concentrated suspension of polyolefin particles are formed and separated. The diluent-rich flow from one separator is recycled to a reactor preceding the second reactor, and the diluent-rich flow from the other separator is recycled to the second reactor. The invention enables higher separator efficiencies to be achieved.
摘要翻译：在至少两个反应器中制造聚烯烃树脂的连续方法，其中在第一聚合反应器中，烯烃在催化剂和稀释剂存在下连续聚合以产生包含稀释剂和聚烯烃颗粒的第一悬浮液。第一悬浮液的至少一部分从第一聚合反应器转移到进一步聚合的第二聚合反应器中。将含有稀释剂和聚合物颗粒的另外的悬浮液从第二反应器中排出并转移到两个分离器中，其中每个分离器形成和分离富含稀释剂的流和聚集体颗粒的浓缩悬浮液。来自一个分离器的稀释剂富集的流被再循环到第二反应器之前的反应器中，并且来自另一个分离器的富含稀释剂的流被再循环到第二反应器。本发明可实现更高的分离效率。

4. 发明授权

US07582723B2 Process and apparatus for the polymerization of ethylene 有权
标题翻译：用于乙烯聚合的方法和设备
公开(公告)号：US07582723B2
公开(公告)日：2009-09-01
申请号：US11883713
申请日：2006-01-30
申请人： Giuseppe Penzo , Cyrus Ahmadzade-Youssefi , Rainer Karer , Ulrich Nieken
发明人： Giuseppe Penzo , Cyrus Ahmadzade-Youssefi , Rainer Karer , Ulrich Nieken
IPC分类号： C08F6/00 , C08F2/34 , B01D53/72
CPC分类号： C08F10/02 , B01J8/0035 , B01J8/006 , B01J8/24 , B01J2208/00274 , B01J2208/00761 , B01J2219/00006 , C08F6/005 , C08F10/00 , C08F110/02 , C08F210/16 , Y02P20/582 , Y10S526/92 , C08L23/06 , C08L23/0815 , C08F4/69 , C08F2/34 , C08F2/01 , C08F210/08 , C08F210/14
摘要： Process for the polymerization of ethylene or of ethylene with further 1-olefins, in which the ethylene is polymerized in the presence of a catalyst in a gas-phase reactor and reaction gas comprising propane and unpolymerized ethylene is circulated to remove the heat of polymerization, wherein the polymer particles are discharged continuously or discontinuously from the reactor, the polymer particles are separated from the major part of the concomitantly discharged gas and the polymer particles are degassed, the gas is freed of entrained fine particles and is separated from a low-boiling fraction comprising ethylene or from a high boiling fraction containing further 1-olefins or alkanes having from 4 to 12 carbon atoms in a first separation stage, a propane fraction is separated off in a second separation stage and this propane fraction is used for degassing the polymer particles discharged from the reactor, with the proportion of ethylene in the propane fraction being less than 1 mol % and the proportion of 1-olefins and alkanes having from 4 to 12 carbon atoms in the propane fraction being less than 4 mol %, in each case based on the total propane fraction. Furthermore, an apparatus for carrying out the process. In this way, a high heat discharge from the reactor, satisfactory degassing of the discharged polymer particles and recovery of the reaction gas discharged together with the polymer particles and also the gas used for degassing the polymer particles are made possible.
摘要翻译：乙烯或乙烯与进一步的1-烯烃聚合的方法，其中乙烯在催化剂存在下在气相反应器和包含丙烷和未聚合乙烯的反应气体中聚合循环以除去聚合热，其中聚合物颗粒从反应器中连续或不连续地排出，聚合物颗粒与伴随排出气体的主要部分分离，聚合物颗粒脱气，气体不含夹带的细颗粒，并从低沸点在第一分离阶段，包含乙烯或含有另外的具有4至12个碳原子的1-烯烃或烷烃的高沸点馏分的馏分在第二分离阶段分离出丙烷馏分，该丙烷馏分用于使聚合物脱气从反应器排出的颗粒，丙烷馏分中乙烯的比例小于1mol ％，丙烷馏分中具有4至12个碳原子的1-烯烃和烷烃的比例小于4mol％，基于总丙烷馏分。此外，一种用于执行该过程的装置。以这种方式，可以从反应器的高热放电，排出的聚合物颗粒的令人满意的脱气和与聚合物颗粒一起排放的反应气体的回收以及用于使聚合物颗粒脱气的气体成为可能。

5. 发明授权

US07527175B2 Metering of catalysts 有权
标题翻译：计量催化剂
公开(公告)号：US07527175B2
公开(公告)日：2009-05-05
申请号：US10470686
申请日：2002-01-30
申请人： Hermann Gebhart , Volker Dolle , Elisabeth Glattki-Mayer, legal representative , Angel Sanchez , Herbert Plötz , Peter Götz , Franz Langhauser
发明人： Klaus-Peter Mayer
IPC分类号： G01F22/00 , C08F2/00 , C08F10/06
CPC分类号： B01J8/20 , B01J8/0035 , B01J2208/00752 , C08F10/06 , C08F210/06 , Y10S526/919 , Y10S526/92 , C08F2/00 , C08F210/16 , C08F2500/24
摘要： To meter catalysts into a reactor, the catalyst is firstly suspended in a hydrocarbon in a reservoir and the suspension obtained is kept in motion by stirring and then fed via a three-way metering valve and an ejector into the actual reactor, wherein the suspension containing the catalyst is firstly discharged from the reservoir by means of a pump and continuously circulated by returning the suspension via the three-way metering valve within a closed piping system to the reservoir, subsequently setting a pressure in the reservoir which is from 0.1 to 30 bar higher than the pressure in the reactor and then continuously introducing the suspension into the reactor via a flow meter which controls the three-way metering valve and via a downstream ejector by pulse operation of the now open three-way metering valve.
摘要翻译：为了将催化剂计量到反应器中，首先将催化剂悬浮在储存器中的烃中，并通过搅拌将获得的悬浮液保持运动，然后通过三通计量阀和喷射器进料到实际反应器中，其中含有催化剂首先通过泵从储存器中排出，并通过三通计量阀将闭合管道系统中的悬浮液返回到储存器中而连续循环，随后将储存器中的压力设定在0.1至30巴高于反应器中的压力，然后经由流量计连续引入悬浮液，该流量计通过现在开放的三通计量阀的脉冲操作经由下游喷射器控制三通计量阀。

6. 发明授权

US07459520B2 Poly(arylene ether) and an apparatus for producing the same 有权
标题翻译：聚（亚芳基醚）及其制造装置
公开(公告)号：US07459520B2
公开(公告)日：2008-12-02
申请号：US11565396
申请日：2006-11-30
申请人： Hugo Gerard Eduard Ingelbrecht
发明人： Hugo Gerard Eduard Ingelbrecht
IPC分类号： C08G65/38 , C08G65/46 , C08G65/48
CPC分类号： C08J3/07 , C08J2371/02 , C08L71/10 , Y10S526/92
摘要： A poly(arylene ether) produced by combining a poly(arylene ether) solution with an antisolvent at a shear rate of greater than 50,000 sec−1. The high shear mixing conditions produce a poly(arylene ether) dispersion in which the poly(arylene ether) solid contains reduced amounts of undesirably fine particles.
摘要翻译：通过在大于50,000sec -1的剪切速率下将聚（亚芳基醚）溶液与抗溶剂结合而制备的聚（亚芳基醚）。高剪切混合条件产生聚（亚芳基醚）分散体，其中聚（亚芳基醚）固体含有减少量的不期望的细颗粒。

7. 发明申请

US20070037936A1 Loop reactor with varying diameter for olefin polymerization 有权
标题翻译：具有不同直径的环烯烃反应器用于烯烃聚合
公开(公告)号：US20070037936A1
公开(公告)日：2007-02-15
申请号：US10572816
申请日：2004-09-16
申请人： Shahram Mihan , Wolfgang Gsella , Peter Kolle , Joachim Wulff-Doring
发明人： Shahram Mihan , Wolfgang Gsella , Peter Kolle , Joachim Wulff-Doring
IPC分类号： C08F2/00
CPC分类号： B01J19/1837 , B01J3/008 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , Y10S526/92 , C08F2/14 , C08F2/01 , C08F210/14
摘要： Process for polymerizing at least one olefinic monomer in a loop reactor at from 20 to 150° C., but below the melting point of the polymer to be formed, and a pressure of from 5 to 100 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and this suspension is circulated by means of an axial pump, wherein the loop reactor comprises a cyclic reactor tube whose diameter varies by at least 10%, based on the predominant reactor tube diameter, and in which there is at least one widening and narrowing in a region other than that of the axial pump.
摘要翻译：在环管反应器中在20-150℃下聚合至少一种烯属单体的方法，但低于待形成的聚合物的熔点，压力为5-100巴，其中所形成的聚合物存在于在液体或超临界悬浮介质中的悬浮液，并且该悬浮液通过轴向泵循环，其中环流反应器包括基于主要的反应器管直径，其直径变化至少10％的循环反应器管，其中在轴向泵以外的区域中至少有一个变宽和变窄。

8. 发明申请

US20060235170A1 Process for producing radical polymer and microapparatus for chemical reaction 失效
标题翻译：生产用于化学反应的自由基聚合物和微型装置的方法
公开(公告)号：US20060235170A1
公开(公告)日：2006-10-19
申请号：US10565652
申请日：2004-07-16
申请人： Takeshi Iwasaki , Junichi Yoshida
发明人： Takeshi Iwasaki , Junichi Yoshida
IPC分类号： C08F2/00
CPC分类号： C08F2/01 , B01J19/0093 , B01J19/2425 , B01J2219/00085 , B01J2219/0086 , B01J2219/00869 , B01J2219/00873 , Y10S526/92
摘要： An object of the present invention is to provide a method for effectively producing, within a short period of time, a radical polymer having controlled molecular weight distribution or a narrow molecular weight distribution profile, the method including polymerizing a radical-polymerizable monomer. Another object of the invention is to provide a microreactor which can be readily fabricated. The invention attains the objects through provision of a method for producing a radical polymer, which method includes feeding a radical polymerization initiator and a radical-polymerizable monomer into a reaction tube having an inner diameter of 2 mm or less and performing polymerization in the reaction tube in a homogeneous liquid state under flow conditions, and a microreactor having a jacket for allowing a temperature-regulating fluid to pass therethrough and a plurality of round tubes which are arranged in parallel in the jacket, each having an inner diameter of 2 mm or less, wherein reaction temperature in the round tubes can be regulated through flowing of the temperature-regulating fluid in the jacket.
摘要翻译：本发明的目的是提供一种在短时间内有效地制备具有受控分子量分布或窄分子量分布曲线的自由基聚合物的方法，该方法包括使可自由基聚合的单体聚合。本发明的另一个目的是提供一种可以容易地制造的微反应器。本发明通过提供自由基聚合物的制造方法来实现目的，该方法包括将自由基聚合引发剂和可自由基聚合的单体进料到内径为2mm以下的反应管中，并在反应管中进行聚合在流动条件下处于均匀的液体状态，以及具有用于允许温度调节流体通过的护套的微反应器和平行于套管布置的多个圆形管，每个圆形管的内径为2mm或更小其中圆管中的反应温度可以通过温度调节流体在夹套中的流动来调节。

9. 发明授权

US06958376B2 Inlet distribution device for upflow polymerization reactors 失效
标题翻译：用于上流聚合反应器的入口分配装置
公开(公告)号：US06958376B2
公开(公告)日：2005-10-25
申请号：US10659126
申请日：2003-09-10
申请人： Gregory P. Muldowney
发明人： Gregory P. Muldowney
IPC分类号： B01J8/18 , B01J8/24 , C08F2/01 , C08F10/00 , C08F2/00
CPC分类号： B01J8/1827 , B01J8/1818 , B01J2208/00256 , B01J2208/00274 , B01J2208/00283 , C08F10/00 , Y10S526/92 , C08F2/01 , C08F2/34
摘要： A polymerization process and polymerization reactor are provided. For example, a polymerization process is described, including passing a feed stream including liquid and gas through a feed stream inlet disposed proximate an upflow polymerization reactor, passing the feed stream through a member configured to impart an angular velocity to the feed stream and entrain the liquid in the gas, and contacting the feed stream with a catalyst to polymerize the feed stream. The upflow polymerization reactor includes a housing having a lower region and an upper region, the upper region and lower region being separated by a catalyst bed, a feed stream inlet disposed proximate the lower region of the housing configured to pass a feed stream therethrough comprising liquid and gas, a fluid outlet disposed proximate the upper region of the housing, and a member mounted in the housing between the feed stream inlet and the catalyst bed having a plurality of apertures positioned at an angle of greater than about 0 degrees and less than about 90 degrees from horizontal.
摘要翻译：提供聚合方法和聚合反应器。例如，描述聚合方法，包括使包含液体和气体的进料流通过设置在上流聚合反应器附近的进料流入口，使进料流通过构件以赋予进料流角速度并夹带气体中的液体，并使进料流与催化剂接触以聚合进料流。上流聚合反应器包括具有下部区域和上部区域的壳体，上部区域和下部区域由催化剂床分隔开，设置在壳体的下部区域附近的进料流入口，该进料流入口配置成使进入流通过，该进料流入口包括液体以及气体，设置在壳体的上部区域附近的流体出口，以及安装在进料流入口和催化剂床之间的壳体中的构件，其具有以大于约0度并且小于约0度的角度定位的多个孔水平90度。

10. 发明申请

US20040082739A1 Inlet distribution device for upflow polymerization reactors 失效
标题翻译：用于上流聚合反应器的入口分配装置
公开(公告)号：US20040082739A1
公开(公告)日：2004-04-29
申请号：US10659126
申请日：2003-09-10
发明人： Gregory P. Muldowney
IPC分类号： C08F004/44
CPC分类号： B01J8/1827 , B01J8/1818 , B01J2208/00256 , B01J2208/00274 , B01J2208/00283 , C08F10/00 , Y10S526/92 , C08F2/01 , C08F2/34
摘要： A polymerization process and polymerization reactor are provided. For example, a polymerization process is described, including passing a feed stream including liquid and gas through a feed stream inlet disposed proximate an upflow polymerization reactor, passing the feed stream through a member configured to impart an angular velocity to the feed stream and entrain the liquid in the gas, and contacting the feed stream with a catalyst to polymerize the feed stream. The upflow polymerization reactor includes a housing having a lower region and an upper region, the upper region and lower region being separated by a catalyst bed, a feed stream inlet disposed proximate the lower region of the housing configured to pass a feed stream therethrough comprising liquid and gas, a fluid outlet disposed proximate the upper region of the housing, and a member mounted in the housing between the feed stream inlet and the catalyst bed having a plurality of apertures positioned at an angle of greater than about 0 degrees and less than about 90 degrees from horizontal.
摘要翻译：提供聚合方法和聚合反应器。例如，描述了聚合方法，包括使包含液体和气体的进料流通过设置在上流聚合反应器附近的进料流入口，使进料流通过构件以赋予进料流角速度并夹带气体中的液体，并使进料流与催化剂接触以聚合进料流。上流聚合反应器包括具有下部区域和上部区域的壳体，上部区域和下部区域由催化剂床分隔开，设置在壳体的下部区域附近的进料流入口，该进料流入口配置成使进入流通过，该进料流入口包括液体以及气体，设置在壳体的上部区域附近的流体出口，以及安装在进料流入口和催化剂床之间的壳体中的构件，其具有以大于约0度并且小于约0度的角度定位的多个孔水平90度。

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