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1. 发明授权

US06759494B2 Fluoroelastomers 有权
标题翻译：氟弹性体
公开(公告)号：US06759494B2
公开(公告)日：2004-07-06
申请号：US10283166
申请日：2002-10-30
申请人： Ivan Wlassics , Marco Apostolo , Margherita Albano
发明人： Ivan Wlassics , Marco Apostolo , Margherita Albano
IPC分类号： C08F21422
CPC分类号： C08F214/222 , C08F214/262
摘要： Curable fluoroelastomers comprising monomeric units formed by a triazine iodinated derivative having general formula: wherein Y′ is independently H, Cl, F, CH3, or CF3, m′ and t′ are 0 or 1, and m′+t′=0 or 1, preferably m′+t′=0; p′ is an integer and is equal to 1 when t′=1, or p′=0; X′ is independently H, Cl, F, alkyl or perfluoroalkyl C1-C3, preferably F; n′ is an integer between 2 and 20, preferably between 4 and 12, more preferably between 4 and 8.
摘要翻译：包含由具有以下通式的三嗪碘化衍生物形成的单体单元的固化含氟弹性体：其中Y'独立地为H，Cl，F，CH 3或CF 3，m'和t'为0或1，m'+ t'= 0或 1，优选m'+ t'= 0; p'是一个整数，当t'= 1或p'= 0时，它等于1; X'独立地是H，Cl，F，烷基或全氟烷基C1-C3，优选F; n'为2〜20，优选为4〜12，更优选为4〜8的整数。

2. 发明授权

US06500903B2 Fluoroelastomers 有权
标题翻译：氟弹性体
公开(公告)号：US06500903B2
公开(公告)日：2002-12-31
申请号：US09370254
申请日：1999-08-09
申请人： Ivan Wlassics , Marco Apostolo , Margherita Albano
发明人： Ivan Wlassics , Marco Apostolo , Margherita Albano
IPC分类号： C08F21418
CPC分类号： C08F214/222 , C08F214/262
摘要： Curable fluoroelastomers comprising monomeric units formed by triazine iodinated derivative having general formula: wherein Y′ is independently H, Cl, F, CH3, or CF3, m′ and t′ are 0 or 1, and m′+t′=0 or 1, preferably m′+t′=0; p′ is an integer and is equal to 1 when t′=1, or p′=0; X′ is independently H, Cl, F, alkyl or perfluoroalkyl C1-C3, preferably F; n′ is an integer between 2 and 20, preferably between 4 and 12, more preferably between 4 and 8.
摘要翻译：其中Y'独立地为H，Cl，F，CH 3或CF 3，m'和t'为0或1，m' ，优选m'+ t'= 0; p'是一个整数，当t'= 1或p'= 0时，它等于1; X'独立地是H，Cl，F，烷基或全氟烷基C1-C3，优选F; n'为2〜20，优选为4〜12，更优选为4〜8的整数。

3. 发明授权

US07408006B2 Perfluoroelastomeric compositions 有权
标题翻译：全氟弹性组合物
公开(公告)号：US07408006B2
公开(公告)日：2008-08-05
申请号：US11155890
申请日：2005-06-20
申请人： Giovanni Comino , Margherita Albano , Marco Apostolo
发明人： Giovanni Comino , Margherita Albano , Marco Apostolo
IPC分类号： C08F259/00
CPC分类号： C08K5/02 , C08F14/18 , C08K5/0025 , C08K5/14 , C08F2/02 , C08L27/12
摘要： A crosslinking system of perfuoroelastomers curable by peroxidic way comprising: as crosslinking agent, a bis-olefin having general formula: wherein: R1, R2, R3, R4, R5, R6, equal to or different from each other, are H or C1-C5 alkyls; Z is a C1-C18 linear or branched alkylene or cycloalkylene radical, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylene radical; the bis-olefin amount, expressed in per cent by weight on the total of polymer, being from 0.6% to 1.8%; peroxides for the peroxidic curing, capable to generate radicals by heating, in an amount from 0.2% to 1.3% by weight on the polymer.
摘要翻译：一种通过过氧化物可固化的增塑弹性体的交联体系，包括：作为交联剂，具有以下通式的双烯烃：其中：R 1，R 2，R 3 H或C 1，R 3，R 5，R 6，R 6，R 6，R 6和R 6彼此相同或不同， C 1 -C 5烷基; Z是任选含有氧原子的直链或支链亚烷基或亚环烷基，或（全）氟聚氧亚烷基; 以聚合物总量计的重量百分比表示的双烯烃含量为0.6％至1.8％; 能够通过加热产生自由基的过氧化物，其量为聚合物重量的0.2％至1.3％。

4. 发明申请

US20050282969A1 Perfluoroelastomeric compositions 有权
标题翻译：全氟弹性组合物
公开(公告)号：US20050282969A1
公开(公告)日：2005-12-22
申请号：US11155890
申请日：2005-06-20
申请人： Giovanni Comino , Margherita Albano , Marco Apostolo
发明人： Giovanni Comino , Margherita Albano , Marco Apostolo
IPC分类号： C08F14/18 , C08K5/00 , C08K5/02 , C08K5/14 , C08L27/12
CPC分类号： C08K5/02 , C08F14/18 , C08K5/0025 , C08K5/14 , C08F2/02 , C08L27/12
摘要： A crosslinking system of perfuoroelastomers curable by peroxidic way comprising: as crosslinking agent, a bis-olefin having general formula: wherein: R1, R2, R3, R4, R5, R6, equal to or different from each other, are H or C1-C5 alkyls; Z is a C1-C18 linear or branched alkylene or cycloalkylene radical, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylene radical; the bis-olefin amount, expressed in per cent by weight on the total of polymer, being from 0.6% to 1.8%; peroxides for the peroxidic curing, capable to generate radicals by heating, in an amount from 0.2% to 1.3% by weight on the polymer.
摘要翻译：一种通过过氧化物可固化的增塑弹性体的交联体系，包括：作为交联剂，具有以下通式的双烯烃：其中：R 1，R 2，R 3 H或C 1，R 3，R 5，R 6，R 6，R 6，R 6和R 6彼此相同或不同， C 1 -C 5烷基; Z是任选含有氧原子的直链或支链亚烷基或亚环烷基，或（全）氟聚氧亚烷基; 以聚合物总量计的重量百分比表示的双烯烃含量为0.6％至1.8％; 能够通过加热产生自由基的过氧化物，其量为聚合物重量的0.2％至1.3％。

5. 发明授权

US5948868A Fluoroelastomeric compositions 失效
标题翻译：氟弹性组合物
公开(公告)号：US5948868A
公开(公告)日：1999-09-07
申请号：US733936
申请日：1996-10-18
申请人： Margherita Albano , Claudio Pizzi , Ivan Wlassics , Vincenzo Arcella
发明人： Margherita Albano , Claudio Pizzi , Ivan Wlassics , Vincenzo Arcella
IPC分类号： C09K3/10 , C08F8/00 , C08K5/00 , C08K5/01 , C08K5/02 , C08K5/04 , C08K5/14 , C08L27/12
CPC分类号： C08K5/14
摘要： Curing system for fluoroelastomers curable by peroxidic route which comprise iodine comprising as curing agent a bis-olefin having general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, equal to or different from each other, are H or alkyl C.sub.1 -C.sub.5 ; Z is a linear or branched alkylenic or cycloalkylenic radical C.sub.1 -C.sub.18, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylenic radical.
摘要翻译：含有可通过过氧化途径固化的含氟弹性体的固化体系，其包含含有作为固化剂的碘的含有通式的双烯烃，其中R 1，R 2，R 3，R 4，R 5，R 6彼此相同或不同，为H或C 1 -C 5烷基 ; Z是任选地含有氧原子，优选至少部分氟化的或（全）氟聚氧亚烷基的直链或支链亚烷基或环烷基基团C1-C18。

6. 发明授权

US5902857A Fluoroelastomeric compositions 失效
标题翻译：氟弹性组合物
公开(公告)号：US5902857A
公开(公告)日：1999-05-11
申请号：US733938
申请日：1996-10-18
申请人： Ivan Wlassics , Vito Tortelli , Walter Navarrini , Margherita Albano
发明人： Ivan Wlassics , Vito Tortelli , Walter Navarrini , Margherita Albano
IPC分类号： C09K3/10 , C08F8/00 , C08K5/00 , C08K5/01 , C08K5/02 , C08K5/04 , C08K5/14 , C08K5/49 , C08K5/54 , C08K5/56 , C08K5/57 , C08L27/12
CPC分类号： C08K5/54 , C08K5/0025 , C08K5/14 , C08K5/57
摘要： Curing systems for fluoroelastomers curable by peroxidic route which comprise bromine, optionally iodine, the bromine always being higher than iodine, comprising as essential elements:(I) a curing agent comprising a bis-olefin having general formula: ##STR1## wherein: R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, equal to or different from each other, are H or alkyl C.sub.1 -C.sub.5 ; Z is a linear or branched alkylenic or cycloalkylenic radical C.sub.1 -C.sub.18, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylenic radical.(II) a metallorganic hydride of formula: ##STR2## wherein: M is selected from Sn, Si, Ge, Pb; x is an integer from 1 to 3; y, z are zero or integers from 1 to 3, with the proviso y+z=4-x; w is an integer from 1 to 3; the R groups, equal to or different from each other, are selected from: alkyls C.sub.1 -C.sub.4, aryls C.sub.6 -C.sub.12, arylalkyls and alkylaryls C.sub.7 -C.sub.14, optionally containing nitrile and/or hydroxyl groups.
摘要翻译：包含溴，任选碘，总是高于碘的溴可以固化的含氟弹性体的固化体系包含作为必需元素：（I）包含具有以下通式的双烯烃的固化剂：其中：R1，R2，R3 相同或不同的R 4，R 5，R 6为H或C 1 -C 5烷基; Z是任选含有氧原子的直链或支链亚烷基或环烷基C1-C18，或（全）氟聚氧亚烷基。（II）下式的金属有机氢化物：其中：M选自Sn，Si，Ge，Pb; x是1至3的整数; y，z为零或1至3的整数，条件是y + z = 4-x; w为1〜3的整数; R基彼此相同或不同，选自烷基C1-C4，芳基C6-C12，芳基烷基和烷基芳基C7-C14，任选地含有腈和/或羟基。

7. 发明授权

US07022773B2 Fluoroelastomer compositions 有权
公开(公告)号：US07022773B2
公开(公告)日：2006-04-04
申请号：US10843440
申请日：2004-05-12
申请人： Margherita Albano , Marco Apostolo , Vincenzo Arcella , Enrico Marchese
发明人： Margherita Albano , Marco Apostolo , Vincenzo Arcella , Enrico Marchese
IPC分类号： C08L23/00 , C08L27/04 , C08L27/12 , C08L33/02 , C08L33/14
CPC分类号： C08L27/12 , C08L27/18 , C08L29/10 , C08L2205/02 , C08L2666/04
摘要： Fluoropolymers comprising a fluoroelastomer matrix incorporating therein particles of a semicrystalline fluoropolymer formed of tetrafluoroethylene (TFE) homopolymers or copolymers, wherein the average particle sizes of the semicrystalline fluoropolymer latex range from 10 to 100 nm.

8. 发明授权

US06750295B2 Fluoroelastomeric compositions 有权
标题翻译：氟弹性组合物
公开(公告)号：US06750295B2
公开(公告)日：2004-06-15
申请号：US10151960
申请日：2002-05-22
申请人： Margherita Albano , Marco Apostolo , Stefano Arrigoni
发明人： Margherita Albano , Marco Apostolo , Stefano Arrigoni
IPC分类号： C08L2700
CPC分类号： C08F285/00 , C08L27/16 , C08L27/18 , C08L51/003 , C08L2205/02 , C08F214/18 , C08L2666/04 , C08L2666/24
摘要： Fluoroelastomeric compositions comprising: A) a fluoroelastomeric matrix based on vinylidene fluoride (VDF); B) a semi-crystalline fluoropolymer, in an amount from 1 to 40% by weight based on the total of A)+B), comprising a semi-crystalline fluoropolymer core coated by a semi-crystalline fluoropolymer shell containing bromine and/or iodine in the polymer chain; the fluoroelastomer A) incorporates the fluoropolymer B), the fluoropolymer B) being formed by tetrafluoroethylene (TFE) homopolymers, or by TFE copolymers with one or more monomers containing at least one unsaturation of ethylene type, the average sizes of the semi-crystalline fluoropolymer particles being from 10 to 100 nm, preferably from 10 to 60 nm.
摘要翻译：含氟弹性体组合物，其包含：A）基于偏二氟乙烯（VDF）的氟弹性体基体; B）基于A）+ B）的总量为1至40重量％的半结晶含氟聚合物，其包含半 - 结晶含氟聚合物芯由在聚合物链中含有溴和/或碘的半结晶含氟聚合物外壳涂覆;含氟弹性体A）包含含氟聚合物B），含氟聚合物B）由四氟乙烯（TFE）均聚物形成，或通过TFE共聚物与一种或多种含有至少一种乙烯型不饱和度的单体，半结晶含氟聚合物颗粒的平均尺寸为10至100nm，优选10至60nm。

9. 发明授权

US06323283B1 Peroxide curable fluoroelastomers 有权
标题翻译：过氧化物固化的含氟弹性体
公开(公告)号：US06323283B1
公开(公告)日：2001-11-27
申请号：US09334562
申请日：1999-06-21
申请人： Marco Apostolo , Margherita Albano
发明人： Marco Apostolo , Margherita Albano
IPC分类号： C08L2712
CPC分类号： C08L27/12 , C08L27/16 , C08L2205/02 , C08L2666/04
摘要： Curable fluoroelastomers formed from the following fluoroelastomer mixtures: a) from 20 to 70% by weight of a fluorolastomer having the Mooney viscosity value, ML (1+10) at 121° C., of greater than 60 points and containing from 0.01 to 3% by weight of iodine; b) from 0 to 70% by weight of a fluoroelastomer having the Mooney viscosity value, ML (1+10) at 121° C., in the range of 20-60 points and containing from 0.2 to 5% by weight of iodine; c) from 5 to 60% by weight of a fluoroelastomer having the Mooney viscosity value, ML (1+10) at 121° C., in the range of 1-20 points and containing an iodine percentage by weight greater than 0.3; said Mooney viscosity ML (1+10) at 121° C. determined according to the ASTM D 1646 method; where said fluoroelastomers comprise monomeric units derived from a bis-olefin.
摘要翻译：由以下含氟弹性体混合物形成的可固化的含氟弹性体：a）20至70重量％的具有门尼粘度值（121℃下的ML（1 + 10））大于60分，含有0.01至3 重量百分比的碘; b）0至70重量％的具有门尼粘度值，121℃下的ML（1 + 10），20-60点范围内且含有0.2至5的含氟弹性体重量％的碘; c）5至60重量％的具有门尼粘度值，121℃下的ML（1 + 10）的含氟弹性体，在1-20分的范围内，并且含有碘百分比为重量大于0.3; 根据ASTM D1646方法测定121℃下的门尼粘度ML（1 + 10）;其中所述含氟弹性体包含衍生自双烯烃的单体单元。

10. 发明申请

US20060189760A1 Fluoroelastomer compositions 审中-公开
公开(公告)号：US20060189760A1
公开(公告)日：2006-08-24
申请号：US11305107
申请日：2005-12-19
申请人： Margherita Albano , Marco Apostolo , Vincenzo Arcella , Enrico Marchese
发明人： Margherita Albano , Marco Apostolo , Vincenzo Arcella , Enrico Marchese
IPC分类号： C08L27/12
CPC分类号： C08L27/12 , C08L27/18 , C08L29/10 , C08L2205/02 , C08L2666/04
摘要： Fluoropolymers comprising a fluoroelastomer matrix incorporating therein particles of a semicrystalline fluoropolymer formed of tetrafluoroethylene (TFE) homopolymers or copolymers, wherein the average particle sizes of the semicrystalline fluoropolymer latex range from 10 to 100 nm.

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