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1. 发明授权

US06384269B1 Esters with musky odor and their use in perfumery 有权
标题翻译：具有麝香味的酯类及其在香料中的用途
公开(公告)号：US06384269B1
公开(公告)日：2002-05-07
申请号：US09553376
申请日：2000-04-20
申请人： Alvin S. Williams
发明人： Alvin S. Williams
IPC分类号： C07C6702
CPC分类号： C11B9/0034 , C07C69/67 , C07C69/675 , C07C69/716 , C07C2601/14
摘要： The compounds of formula in which the symbols R1, R2, R3 and R4 represent independently from each other a hydrogen atom or a methyl or ethyl group, the symbol X represents an oxygen atom or an alkylene group of formula in which n is an integer from 1 to 3, the symbols R6 and R7 represent each a hydrogen atom or a methyl or ethyl group, and R5 represents an alkyl or alkoxy group from C1 to C4, linear or branched, an alkenyl group from C2 to C4, linear or branched, or a group of formula in which Y has the same meaning as X and R8 is a linear or branched alkyl group from C1 to C4 or a linear or branched alkenyl group from C2 to C4, are novel compounds showing musky odors and which confer musky-velvety, voluminous and very tenacious notes to the products to which they are added.
摘要翻译：符号R1，R2，R3和R4彼此独立地表示氢原子或甲基或乙基的甲醛化合物，符号X表示氧原子或甲醛的亚烷基，n是1至在图3中，符号R6和R7各自表示氢原子或甲基或乙基，R5表示直链或支链的C1至C4的烷基或烷氧基，直链或支链的C2至C4的链烯基，或 Y为与X和R相同意义的甲醛基，其为C1至C4的直链或支链烷基或C2至C4的直链或支链烯基，是表现出麝香气味的新型化合物，具有麝香柔软，体积大和他们添加的产品非常顽固的笔记。

2. 发明授权

US06433217B1 Process for the preparation of glycidylesters of branched carboxylic acids 有权
标题翻译：制备支链羧酸的缩水甘油酯的方法
公开(公告)号：US06433217B1
公开(公告)日：2002-08-13
申请号：US09404527
申请日：1999-09-23
申请人： Gerrit Gerardus Rosenbrand , Hendrik Stichter , Denis Marie Charles Heymans
发明人： Gerrit Gerardus Rosenbrand , Hendrik Stichter , Denis Marie Charles Heymans
IPC分类号： C07C6702
CPC分类号： C07D303/16
摘要： A process for the manufacture of glycidylesters of branched monocarboxylic acids, comprising (a) the reaction of the &agr;-branched monocarboxylic acid with a halo substituted monoepoxide such as an epihalohydrin (e.g. epichlorohydrin), in a 2-20 molar excess, in the presence of water and a water-miscible solvent as solvent, and in the presence of a catalyst, in an amount of at most 45 mol % of the molar amount of the monocarboxylic acid groups, and preferably at most 30 mol % at a temperature in the range of from 50 to 110, during a period in the range of from 0.8 to 2.5 hr, (b) addition of additional alkali metal hydroxide or alkali metal alkanolate up to about an equimolar amount as to the monocarboxylic acid and reaction at a temperature of from 40 to 80° C., (c) distillation of the obtained reaction mixture to remove the excess halo substituted monoepoxide and the solvent and water formed, and (d) removal of the alkali metal halide salt, in order to complete the dehydrohalogenation (and preferably a dehydrochlorination).
摘要翻译：一种制备支化单羧酸缩水甘油酯的方法，包括（a）在2-20摩尔过量存在下，α-支化的单羧酸与卤代取代的单环氧化物如表卤代醇（如表氯醇）的反应，以2-20摩尔过量的反应的水和与水混溶的溶剂作为溶剂，并且在催化剂存在下，所述单羧酸基团的摩尔量为至多45摩尔％，优选至多30摩尔％范围为50〜110，在0.8〜2.5小时的范围内，（b）添加额外的碱金属氢氧化物或碱金属链烷醇酯，直到一元羧酸约等摩尔量，并在 40℃至80℃，（c）蒸馏所得反应混合物以除去过量卤代的单环氧化物和形成的溶剂和水，和（d）除去碱金属卤化物盐，以完成脱卤化氢并优选脱氯化氢）。

3. 发明授权

US06359147B1 Reactions catalyzed by chromium (III) carboxylates 有权
标题翻译：铬（III）羧酸盐催化反应
公开(公告)号：US06359147B1
公开(公告)日：2002-03-19
申请号：US09445736
申请日：2000-04-03
申请人： Renato R. Rindone , W. Kenneth Musker
发明人： Renato R. Rindone , W. Kenneth Musker
IPC分类号： C07C6702
CPC分类号： C07D207/404 , B01J31/04 , B01J2231/48 , C07C67/03 , C07C67/08 , C07C67/24 , C07D209/48 , C07D303/04 , C07D305/06 , C07D309/30 , C07D331/02 , C08G59/685 , C08G65/18 , C08G65/266
摘要： Reactions of ring systems, such as aziridines, oxetanes and oxiranes with carboxylic acids, anhydrides, imides, lactones and carbonate esters are catalyzed by C3-C60, substituted or unsubstituted, straight or branched-chained, alkyl, aryl, or aralkyl carboxylate Cr+3 salts, preferably chromium +3 octoate. The catalysts also accelerate the reaction of hydroxy compounds with anhydrides, and of thiiranes with anhydrides. The catalysts selectively enhance the conversion of ring systems to form monomers, prepolymers, copolymers, functional end-group monomers, functional end-group prepolymers, and functional end-group polymers rather than forming homopolymers. By varying the catalyst concentration, molar ratios, and reaction temperatures, the reaction time required to form the desired product can be controlled.
摘要翻译：环系统，如氮丙啶，氧杂环丁烷和环氧乙烷与羧酸，酸酐，酰亚胺，内酯和碳酸酯的反应由C3-C60，取代或未取代的直链或支链烷基，芳基或芳烷基羧酸酯Cr + 3盐，优选铬+ 3辛酸。催化剂还加速了羟基化合物与酸酐的反应，和硫酸盐与硫酸盐的反应。催化剂选择性地增强环体系的转化，形成单体，预聚物，共聚物，官能端基单体，官能端基预聚物和官能端基聚合物，而不是形成均聚物。通过改变催化剂浓度，摩尔比和反应温度，可以控制形成所需产物所需的反应时间。

4. 发明授权

US06350895B1 Transesterification process using yttrium and samarium compound catalystis 失效
标题翻译：使用钇和钐化合物催化剂进行酯交换
公开(公告)号：US06350895B1
公开(公告)日：2002-02-26
申请号：US09505789
申请日：2000-02-17
申请人： Joseph Varapadavil Kurian
发明人： Joseph Varapadavil Kurian
IPC分类号： C07C6702
CPC分类号： C07C67/03 , C07C69/82 , C07C69/76
摘要： This invention relates to an improvement for the preparation of bis(3-hydroxypropyl) dicarboxylate monomers using 1,3-propanediol and a dialkyl dicarboxylate in the presence of a catalytic amount of such yttrium and/or samarium compounds as yttrium/samarium acetylacetonate or tris(2,2,6,6-tetramethyl-3,5-heptanedionato) yttrium/samarium which act as a catalyst for the transesterification reaction
摘要翻译：本发明涉及使用1,3-丙二醇和二羧酸二烷基酯在催化量的这种钇/钐化合物存在下制备双（3-羟丙基）二羧酸酯单体的改进，所述钇/钐化合物如钇/钐乙酰丙酮化物或三（2,2,6,6-四甲基-3,5-庚二酮酸）钇/钐，其用作酯交换反应的催化剂

5. 发明授权

US06342199B1 Method for carrying out reactions characterized by an equilibrium 有权
标题翻译：进行以平衡为特征的反应的方法
公开(公告)号：US06342199B1
公开(公告)日：2002-01-29
申请号：US09284464
申请日：1999-06-18
申请人： Vincent Simon Ellis
发明人： Vincent Simon Ellis
IPC分类号： C07C6702
CPC分类号： C07C231/02 , B01J19/0013 , B01J19/14 , B01J19/2465 , B01J19/26 , B01J2219/00083 , B01J2219/00103 , B01J2219/0011 , B01J2219/00164 , C07C67/03 , C07C67/08 , Y02P20/582 , C07C233/35
摘要： The invention relates to a process for conducting a chemical reaction characterized by an equilibrium in a reaction system designed as a loop reactor, said loop reactor comprising a reactor vessel (1), at least one loop connected to said reactor vessel (1) each by means of an outlet and an inlet, said loop comprising means (3) for pumping over a fluid reaction material, at least one he exchanger (4), optionally means (5) for feeding said reaction material into Me reactor vessel (1) and a separate gas loop (8) which is connected to the gas space of the reactor vessel (1) above the reaction mixture and has separate means for feeding a gas into the gas loop (8), for withdrawing gas from the gas loop (8) and/or for treating said gas circulating in the gas loop (8), said process comprising the steps of circulating and/or treating said gas in said gas loop (8), feeding said gas into the reactor vessel (1) for influencing the equilibrium of a reaction conducted in said reactor vessel (1) and being characterized by the equilibrium and, after influencing said equilibrium reaction conducted in said reactor vessel (1), exhausting said gas from said reactor vessel (1) into the gas loop (8).
摘要翻译：本发明涉及一种用于进行化学反应的方法，其特征在于设计为环管反应器的反应体系中的平衡，所述环管反应器包括反应器容器（1），至少一个回路，其连接到所述反应器容器（1）出口和入口的装置，所述环路包括用于泵送流体反应材料的装置（3），至少一个换热器（4），用于将所述反应材料进料到Me反应器容器（1）中的任选的装置（5）和连接到反应容器（1）的气体空间上的单独的气体回路（8），并且具有用于将气体供给气体回路（8）的单独装置，用于从气体回路（8）中排出气体）和/或用于处理在气体回路（8）中循环的所述气体，所述方法包括在所述气体回路（8）中循环和/或处理所述气体的步骤，将所述气体进料到反应器容器（1）中以影响在所述反应器容器（1）和其特征在于平衡，并且在影响在所述反应器容器（1）中进行的所述平衡反应之后，将所述气体从所述反应器容器（1）排出到气体回路（8）中。

6. 发明授权

US06727381B2 Process for producing vitamin A ester 有权
标题翻译：生产维生素A酯的方法
公开(公告)号：US06727381B2
公开(公告)日：2004-04-27
申请号：US10039056
申请日：2002-01-03
申请人： Runpu Shen , Shiqing Pi , Bin Xie , Hongjun Huang
发明人： Runpu Shen , Shiqing Pi , Bin Xie , Hongjun Huang
IPC分类号： C07C6702
CPC分类号： C07C403/12 , C07C2601/16 , C07F9/4018
摘要： The invention relates to a process for producing all trans-vitamin A ester (I). According to the present invention, vitamin A ester (I) can simply be synthesized in good yields and high purity by the reaction of phosphonate compound (IV) with aldehyde (II) in an organic solvent in the presence of a base.
摘要翻译：本发明涉及一种生产全部维生素A酯（I）的方法。根据本发明，通过膦酸酯化合物（IV）与醛（II）在有机溶剂中在碱的存在下的反应，可以简单地以高产率和高纯度合成维生素A酯（I）。

7. 发明授权

US06693213B1 Method of producing ethyl acetate and an equipment for carrying out this method 失效
标题翻译：生产乙酸乙酯的方法和实施该方法的设备
公开(公告)号：US06693213B1
公开(公告)日：2004-02-17
申请号：US10110641
申请日：2002-04-12
申请人： Jiri Kolena , Jaromir Lederer , Pavel Morávek , Jiri Hanika , Quido Smejkal , David Skála
发明人： Jiri Kolena , Jaromir Lederer , Pavel Morávek , Jiri Hanika , Quido Smejkal , David Skála
IPC分类号： C07C6702
CPC分类号： B01J8/025 , B01D3/009 , B01J2208/00274 , B01J2208/00283 , B01J2208/00513 , C07C67/08 , Y02P20/127 , C07C69/14
摘要： The invention relates to a method of producing ethyl acetate by reaction of ethyl alcohol with acetic acid and/or acetic anhydride in the presence of a solid acidic catalyst accompanied by simultaneous distillation separation of reaction components, in which acetic acid or acetic anhydride or a mixture thereof and ethyl alcohol, respectively, are introduced separately in a molar ratio of 2:1 to 1:2.5 and in a defined quantity, per unit volume of catalyst, into a system separated into three zones, whereby, in the reaction zone, the reaction runs simultaneously with distillation separation of components, acetic acid feed is introduced into the reaction zone or above the zone and ethyl alcohol feed is introduced into the reaction zone or below this zone; in the upper separation zone, the volatile mixture is separated; thereafter, it is cooled to 5 to 70° C. and then separated into water and organic phases and the organic phase with a high ethyl acetate content is drawn off and partially returned as reflux flow into this system, whereby, the ratio of the starting components feed and the organic reflux flow is 1:1 to 1:20. This invention also relates to equipment for carrying out this method.
摘要翻译：本发明涉及通过乙醇与乙酸和/或乙酸酐在固体酸性催化剂的存在下反应生产乙酸乙酯的方法，同时蒸馏分离反应组分，其中乙酸或乙酸酐或其混合物和乙醇分别以2:1至1:2.5的摩尔比和每单位体积的催化剂的规定量引入分离成三个区域的体系中，其中在反应区中，反应与成分的蒸馏分离同时进行，将乙酸进料引入反应区或该区以上，并将乙醇进料引入反应区或该区以下; 在上分离区，挥发性混合物分离; 然后将其冷却至5至70℃，然后分离成水和有机相，抽出具有高乙酸乙酯含量的有机相并部分地作为回流流回到该体系中，由此起始组分进料和有机回流为1:1至1:20。本发明还涉及用于执行该方法的设备。

8. 发明授权

US06541658B2 Process for synthesis of (meth) acrylic acid esters by transesterification in the presence of mixed catalysts containing alkali metal cyanate or thiocyanate 失效
公开(公告)号：US06541658B2
公开(公告)日：2003-04-01
申请号：US10042208
申请日：2002-01-11
申请人： Joachim Knebel , Ralf Merbach , Santa Maria Nuccio
发明人： Joachim Knebel , Ralf Merbach , Santa Maria Nuccio
IPC分类号： C07C6702
CPC分类号： C07D233/32 , C07C67/03 , C07C69/54
摘要： Acrylic or methacrylic acid esters may be efficiently prepared by the transesterification of a C1 to C4 alcohol ester of acrylic or methacrylic acid and a different alcohol in the presence of a mixture of a) an alkali metal cyanate or alkali metal thiocyanate, and b) an alkaline earth metal oxide, an alkaline earth metal hydroxide or an alkali metal halide.

9. 发明授权

US06342627B1 Producing unsaturated esters by a lanthanide metal alkoxide catalyzed transesterification process 失效
标题翻译：通过镧系金属醇盐催化酯交换法生产不饱和酯
公开(公告)号：US06342627B1
公开(公告)日：2002-01-29
申请号：US09459919
申请日：1999-12-14
申请人： Yoshiaki Oda , Makoto Yako , Kazunori Iwakura
发明人： Yoshiaki Oda , Makoto Yako , Kazunori Iwakura
IPC分类号： C07C6702
CPC分类号： C07C213/06 , C07C67/08 , C07C69/54 , C07C219/08
摘要： There is disclosed a process for producing an unsaturated ester of the formula (3): wherein R1, R2 and R3 independently represent hydrogen, halogen, alkyl, alkenyl and the like and R5 represents alkyl which may be substituted and the like, which process is characterized by subjecting an unsaturated ester of the formula (1): wherein R1, R2 and R3 have the same meaning as previously defined and R4 represents alkyl or phenyl and the like, to a transesterification reaction with a hydroxy compound of the formula (2): R5OH (2) wherein R5 has the same meaning as previously defined, in the presence of a lanthanoide metal alkoxide.
摘要翻译：公开了制备式（3）的不饱和酯的方法：其中R1，R2和R3独立地表示氢，卤素，烷基，烯基等，R5代表可被取代的烷基等，该方法是其特征在于使式（1）的不饱和酯：其中R 1，R 2和R 3具有与前述定义相同的含义，R 4表示烷基或苯基等，与式（2）的羟基化合物进行酯交换反应，：其中R 5具有与先前定义的相同的含义，在镧系金属醇盐存在下。

10. 发明授权

US06316664B1 Process for preparing hydroxy-containing compounds from formic acid esters 失效
标题翻译：从甲酸酯制备含羟基化合物的方法
公开(公告)号：US06316664B1
公开(公告)日：2001-11-13
申请号：US09068338
申请日：1998-05-08
申请人： Detlef Kratz , Christoph Sigwart
发明人： Detlef Kratz , Christoph Sigwart
IPC分类号： C07C6702
CPC分类号： C08G65/3312 , C07C29/1285 , C07C67/03 , C08F8/14 , C07C69/10 , C07C69/06 , C07C31/22
摘要： Formic ester is transesterified with a hydroxyl-containing compound in the presence of a tertiary amine as transesterification catalyst to form a formic ester which differs from the formic ester used as reactant, and of a hydroxyl-containing compound which is different from the hydroxyl-containing compound used as reactant.
摘要翻译：在叔胺作为酯交换催化剂存在下，将甲酸酯与含羟基的化合物进行酯交换反应，形成与用作反应物的甲酸酯不同的甲酸酯和不同于含羟基的羟基化合物用作反应物的化合物。

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