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1. 发明授权

US06333438B1 Process for producing adamantanols 有权
标题翻译：生成金刚烷醇的方法
公开(公告)号：US06333438B1
公开(公告)日：2001-12-25
申请号：US09617293
申请日：2000-07-14
申请人： Minoru Kakuda , Takanobu Okamoto , Takashi Onozawa , Hiroshi Kurata
发明人： Minoru Kakuda , Takanobu Okamoto , Takashi Onozawa , Hiroshi Kurata
IPC分类号： C07C3522
CPC分类号： C07C29/48 , C07C2603/74 , C22B11/048 , Y02P10/214 , C07C35/37
摘要： A process for efficiently separating and recovering a ruthenium compound used as the catalyst in the production of adamantanols. The adamantanols are produced by hydroxylating an adamantane compound in the presence of a ruthenium compound and a salt of hypochlorous acid in a water/organic solvent two-phase system. The hydroxylation product liquid is added with an oxidizing agent to allow the ruthenium compound to be extracted into the organic phase. The ruthenium compound is separated and recovered from the organic phase. Alternatively, the ruthenium compound is back-extracted into the aqueous phase by adding an aqueous alkali solution to the organic phase. Then, the ruthenium compound is separated and recovered from the aqueous phase.
摘要翻译：用于在金刚烷醇的制备中有效分离和回收用作催化剂的钌化合物的方法。金刚烷醇通过在水/有机溶剂两相体系中在钌化合物和次氯酸盐的存在下羟化化金刚烷化合物来制备。向羟基化产物液中加入氧化剂以使钌化合物萃取到有机相中。从有机相中分离并回收钌化合物。或者，通过向有机相中加入碱水溶液将钌化合物反萃取到水相中。然后，从水相中分离回收钌化合物。

2. 发明授权

US06639095B1 Process for preparing optically active &agr;-hydroxy acids and derivatives thereof 失效
标题翻译：光学活性α-羟基酸及其衍生物的制备方法
公开(公告)号：US06639095B1
公开(公告)日：2003-10-28
申请号：US10148465
申请日：2002-10-08
申请人： Biing-Jiun Uang , Jia-Wen Chang , Der-Pin Jang
发明人： Biing-Jiun Uang , Jia-Wen Chang , Der-Pin Jang
IPC分类号： C07C3522
CPC分类号： C07C51/09 , C07C67/03 , C07C59/01 , C07C59/48 , C07C69/732 , C07C69/657
摘要： The present invention provides a process for preparing optically active &agr;-hydroxy acids and derivatives thereof by subjecting the alkylated 1,3-dioxolanones of formula (IV) wherein R1 and R2 are the same or different and are each independently H or C1-6 alkyl; R5 is H, C1-16 alkyl, or unsubstituted or substituted phenyl; and R6 is C1-8 alkyl, C2-7 alkenyl or unsubstituted or substituted benzyl, to either alcoholysis or hydrolysis, in which the alkylated 1,3-dioxolanones are obtained by using 10-camphorsulfonamide as a chiral auxiliary.
摘要翻译：本发明提供了通过使其中R 1和R 2相同或不同并且各自独立地为H或C 1-6烷基的式（Ⅳ）的烷基化1,3-二氧戊环酮来制备光学活性α-羟基酸及其衍生物的方法 ; R5是H，C1-16烷基，或未取代或取代的苯基; R6为C1-8烷基，C2-7烯基或未取代或取代的苄基，用于醇解或水解，其中通过使用10-樟脑磺酰胺作为手性助剂获得烷基化1,3-二氧戊环。

3. 发明授权

US06566562B2 Process for the preparation of isolongifolanol 失效
标题翻译：异龙醇的制备方法
公开(公告)号：US06566562B2
公开(公告)日：2003-05-20
申请号：US10014046
申请日：2001-12-11
申请人： Ingo Wöhrle , Jürgen Nienhaus
发明人： Ingo Wöhrle , Jürgen Nienhaus
IPC分类号： C07C3522
CPC分类号： C07C29/56 , C07C29/172 , C07C35/37 , C07C2603/66 , C11B9/0042
摘要： The invention relates to the preparation of the compounds isolongifolanol (IUPAC name: 2,2,7,7-tetramethyltricyclo[6.2.1.01,6]undecan-6-ol) and isolongifolenol (IUPAC name: 2,2,7,7-tetramethyltricyclo[6.2.1.01,6]undec4-en-6-ol) and to the use thereof as fragrance or aroma substance.
摘要翻译：本发明涉及化合物异二醇的制备（IUPAC名称：2,2,7,7-四甲基三环[6.2.1.01,6]十一烷-6-醇）和异链球菌醇（IUPAC名称：2,2,7,7- 四甲基三环[6.2.1.01,6]十一烷-4-烯-6-醇）及其作为香料或芳香物质的用途。

4. 发明授权

US06187967B1 Process of producing adamantanols 有权
标题翻译：生产金刚烷醇的方法
公开(公告)号：US06187967B1
公开(公告)日：2001-02-13
申请号：US09493207
申请日：2000-01-28
申请人： Minoru Kakuda , Takanobu Okamoto , Takashi Onozawa , Hiroshi Kurata
发明人： Minoru Kakuda , Takanobu Okamoto , Takashi Onozawa , Hiroshi Kurata
IPC分类号： C07C3522
CPC分类号： C07C29/48 , C07C29/86 , C07C2603/74 , C07C35/37 , C07C35/14
摘要： Adamantanols are produced in high selectivity and high yields by hydroxylation of adamantane compounds in a specific two-phase solvent system of water and an organic solvent in the presence of a ruthenium compound and hypochlorous acid or its salt. Adamantanediols transfer into the organic phase by adding a specific alcohol to a reaction liquid containing the adamantanols, thereby facilitating extraction of the adamantanediols. The ruthenium compound transfers into the water phase by treating the reaction liquid with alkali prior to the addition of the alcohol and precipitates therein, thereby facilitating the recovery of the ruthenium compound.
摘要翻译：金刚烷醇通过在钌化合物和次氯酸或其盐的存在下在水和有机溶剂的特定两相溶剂体系中金刚烷化合物的羟化反应以高选择性和高收率生产。通过向含有金刚烷醇的反应液中加入特定的醇，将金刚烷二醇转移到有机相中，从而促进金刚烷二醇的萃取。钌化合物通过在加入醇之前用碱处理反应液并在其中沉淀而转移到水相中，从而有助于钌化合物的回收。

5. 发明授权

US06570042B2 Production of adamantanediols 有权
公开(公告)号：US06570042B2
公开(公告)日：2003-05-27
申请号：US09955077
申请日：2001-09-19
申请人： Minoru Kakuda , Takashi Onozawa , Hiroshi Kurata , Kikuo Furukawa
发明人： Minoru Kakuda , Takashi Onozawa , Hiroshi Kurata , Kikuo Furukawa
IPC分类号： C07C3522
CPC分类号： C07C29/48 , C07C2603/74 , C07C35/37
摘要： Adamantanediols are produced by the hydroxylation of adamantane compounds in a water/organic solvent two-phase system in the presence of a ruthenium compound and a hypochlorite. Throughout the hydroxylation, the hypochlorite concentration in the water phase is regulated within a narrow limited range, for example, by monitoring the pH of the reaction system. With such a control of the hypochlorite concentration, the adamantanediols are produced in a high selectivity and a high yield.

6. 发明授权

US06469220B2 Tertiary alcohol compounds having an alicyclic structure 有权
标题翻译：具有脂环结构的叔醇化合物
公开(公告)号：US06469220B2
公开(公告)日：2002-10-22
申请号：US10025064
申请日：2001-12-19
申请人： Koji Hasegawa , Takeshi Kinsho , Takeru Watanabe
发明人： Koji Hasegawa , Takeshi Kinsho , Takeru Watanabe
IPC分类号： C07C3522
CPC分类号： C07C33/14 , C07C35/21 , C07C2601/08 , C07C2601/14 , C07C2603/90 , G03F7/0395 , G03F7/0397
摘要： The present invention provides novel tertiary alcohol compounds which are useful as monomers for the preparation of photoresist materials having high transparency and a great affinity for the substrate and hence suitable for use in photolithography using a light source comprising preferably light having a wavelength of 300 nm or less and more preferably light emitted from an ArF excimer laser. Specifically, the present invention provides tertiary alcohols compounds represented by the following general formula (1): wherein R1 and R2 each independently represent a straigh-chain, branched or cyclic alkyl group having 1 to 10 carbon atoms, in which some or all of the hydrogen atoms on the constituent carbon atoms may be replaced by a halogen atom or halogen atoms, or R1 and R2 may be joined together to form an aliphatic hydrocarbon ring; Z represents a straight-chain, branched or cyclic divalent organic group having 2 to 10 carbon atoms; and k is 0 or 1.
摘要翻译：本发明提供新颖的叔醇化合物，其可用作制备具有高透明度和对基材的极好亲和力的光致抗蚀剂材料的单体，因此适用于使用光源的光刻法，该光源优选包含波长为300nm的光或更优选由ArF准分子激光器发出的光。特别地，本发明提供由以下通式（1）表示的叔醇化合物：其中R 1和R 2各自独立地表示具有1个 10个碳原子，其中构成碳原子上的一些或全部氢原子可以被卤素原子或卤素原子取代，或者R1和R2可以连接在一起形成脂族烃环; Z表示具有2〜10个碳原子的直链，支链或环状二价有机基团; k为0或1。

7. 发明授权

US06392104B1 Adamantane derivatives and process for producing them 有权
标题翻译：金刚烷衍生物及其制备方法
公开(公告)号：US06392104B1
公开(公告)日：2002-05-21
申请号：US09180478
申请日：1998-11-10
申请人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
IPC分类号： C07C3522
CPC分类号： C07C29/50 , C07C35/37 , C07C62/06 , C07C62/24 , C07C67/05 , C07C67/08 , C07C67/29 , C07C67/31 , C07C68/02 , C07C69/757 , C07C69/96 , C07C205/18 , C07C205/41 , C07C205/55 , C07C219/24 , C07C233/23 , C07C233/32 , C07C233/74 , C07C235/40 , C07C265/10 , C07C271/34 , C07C2603/74 , C07C69/753 , C07C69/157
摘要： In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the formula (2): wherein R1 and R2 independently represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group; or R1 and R2 may bond together to form a double bond or an aromatic or non-aromatic ring; Y is O or OH and n=1 to 3; or the imide compound and a co-catalyst (e.g., a transition metal compound), an adamantane derivative having a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is oxidized with oxygen. According to the above method, an adamantane derivative having a hydroxyl group together with a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is efficiently obtained.
摘要翻译：在式（2）所示的酰亚胺化合物（例如，N-羟基邻苯二甲酰亚胺）存在下，其中R1和R2独立地表示氢原子，卤素原子，烷基，芳基，环烷基; 或者R 1和R 2可以键合在一起形成双键或芳族或非芳族环; Y为O或OH且n = 1至3;或酰亚胺化合物和助催化剂（例如过渡金属化合物），具有硝基，氨基，羟基等官能团的金刚烷衍生物，羧基，羟甲基和异氰酸酯基被氧氧化。根据上述方法，有效地获得具有羟基的金刚烷衍生物与硝基，氨基，羟基，羧基，羟甲基和异氰酸基等官能团。

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