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1. 发明授权

US07741514B2 Catalyst comprising N-substituted cyclic imide compound and process for producing organic compound using the catalyst 失效
标题翻译：包含N-取代的环状酰亚胺化合物的催化剂和使用该催化剂制备有机化合物的方法
公开(公告)号：US07741514B2
公开(公告)日：2010-06-22
申请号：US11504019
申请日：2006-08-15
申请人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
IPC分类号： C07C63/00 , C07C51/16 , C07C51/00 , C07D207/00
CPC分类号： C07C45/34 , B01J23/34 , B01J23/75 , B01J31/0247 , B01J31/2208 , B01J2231/348 , B01J2231/42 , B01J2531/72 , B01J2531/845 , C07C45/00 , C07C45/33 , C07C45/36 , C07C51/265 , C07C51/313 , C07D207/46 , C07D209/48 , C07D215/54 , Y02P20/55 , C07C49/403 , C07C49/78 , C07C65/32 , C07C63/26 , C07C63/04 , C07C55/14
摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
摘要翻译：本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。催化剂可以组合包括酰亚胺化合物和金属化合物。在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物，或其衍生物。作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

2. 发明授权

US06235851B1 Polymerizable adamantane derivatives and process for producing the same 失效
标题翻译：可聚合的金刚烷衍生物及其制备方法
公开(公告)号：US06235851B1
公开(公告)日：2001-05-22
申请号：US09214724
申请日：1999-01-11
申请人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
IPC分类号： C08F2000
CPC分类号： C07C67/03 , C07C2603/74 , C07C69/54
摘要： A compound shown by the following formula: wherein each of R1a, R2a, R3a and R4a represents a substituent selected from a non-reactive atom, a non-reactive group, a hydroxyl group and an amino group, and at least two members selected from R1a, R2a, R3a and R4a are a hydroxyl group, a carboxyl group or an amino group; is subjected to an esterification reaction or an amidation reaction with a polymerizable unsaturated compound (e.g., an alcohol, a carboxylic acid, an amine) in the presence of a catalyst comprising an element selected from the Group 3 elements, such as a samarium compound, to obtain a polymerizable adamantane derivative having at least one polymerizable unsaturated group in high yield.
摘要翻译：下式表示的化合物：其中R1a，R2a，R3a和R4a各自表示选自非反应性原子，非反应性基团，羟基和氨基的取代基，以及选自以下的至少两种： R1a，R2a，R3a和R4a是羟基，羧基或氨基; 在包含选自第3族元素的元素如钐化合物的催化剂存在下，与可聚合不饱和化合物（例如醇，羧酸，胺）进行酯化反应或酰胺化反应，以高收率得到具有至少一个聚合性不饱和基团的聚合性金刚烷衍生物。

3. 发明授权

US06429314B1 Methods of acylating adamantane, tricyclo[5.2.1.02,6], and decalin compounds 失效
标题翻译：酰化金刚烷，三环[5.2.1.02,6]和十氢化萘化合物的方法
公开(公告)号：US06429314B1
公开(公告)日：2002-08-06
申请号：US09402898
申请日：1999-10-13
申请人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
IPC分类号： C07D22102
CPC分类号： C07D303/14 , C07B41/06 , C07C1/24 , C07C45/33 , C07C45/455 , C07C49/323 , C07C49/345 , C07C49/453 , C07C2603/74 , C07D303/04 , C07C13/615
摘要： An acylating agent of the invention includes (A) a 1,2-dicarbonyl compound or its hydroxy reductant, (B) oxygen, and (C) at least one compound selected from (c1) a metallic compound and (C2) N-hydroxyphthalimide or another imide compound. As the 1,2-dicarbonyl compound or its hydroxy reductant (A), biacetyl, 2,3-butanediolor the like canbeused. As the metallic compound (c1), cobalt acetate, or another cobalt compound, for example, can be employed. By reacting an adamantane derivative or another compound having a methine carbon atom with the acylating agent, an acyl group can be introduced to the methine carbon atom with efficiency.
摘要翻译：本发明的酰化剂包括（A）1,2-二羰基化合物或其羟基还原剂，（B）氧，和（C）至少一种选自（c1）金属化合物和（C2）N-羟基邻苯二甲酰亚胺或另一种酰亚胺化合物。作为1,2-二羰基化合物或其羟基还原剂（A），可以使用二乙酰基，2,3-丁二醇等。作为金属化合物（c1），可以使用例如乙酸钴或其他钴化合物。通过使金刚烷衍生物或具有次甲基碳原子的另一种化合物与酰化剂反应，可以有效地将酰基引入次甲基碳原子。

4. 再颁专利

USRE39744E1 Adamantane derivatives and process for producing them 失效
标题翻译：金刚烷衍生物及其制备方法
公开(公告)号：USRE39744E1
公开(公告)日：2007-07-24
申请号：US10830494
申请日：1998-03-05
申请人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
IPC分类号： C07C35/22 , C07C61/12 , C07C211/00 , C07D207/40 , C07D207/444 , C07D204/24 , B01J31/00
CPC分类号： C07C29/50 , C07C35/37 , C07C62/06 , C07C62/24 , C07C67/05 , C07C67/08 , C07C67/29 , C07C67/31 , C07C68/02 , C07C69/757 , C07C69/96 , C07C205/18 , C07C205/41 , C07C205/55 , C07C219/24 , C07C233/23 , C07C233/32 , C07C233/74 , C07C235/40 , C07C265/10 , C07C271/34 , C07C2603/74 , C07C69/753 , C07C69/157
摘要： In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the formula (2): wherein R1 and R2 independently represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group; or R1 and R2 may bond together to form a double bond or an aromatic or non-aromatic ring; Y is O or OH and n=1 to 3; or the imide compound and a co-catalyst (e.g., a transition metal compound), an adamantane derivative having a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is oxidized with oxygen. According to the above method, an adamantane derivative having a hydroxyl group together with a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is efficiently obtained.
摘要翻译：在式（2）所示的酰亚胺化合物（例如，N-羟基邻苯二甲酰亚胺）存在下，其中R 1和R 2独立地表示氢原子，卤素原子，烷基，芳基，环烷基; 或R 1和R 2可以键合在一起形成双键或芳族或非芳族环; Y为O或OH且n = 1至3; 或酰亚胺化合物和助催化剂（例如过渡金属化合物），具有硝基，氨基，羟基，羧基，羟甲基和异氰酸基的官能团的金刚烷衍生物被氧气氧化。根据上述方法，有效地获得具有羟基的金刚烷衍生物与硝基，氨基，羟基，羧基，羟甲基和异氰酸基等官能团。

5. 发明授权

US07115541B2 Catalyst comprising n-substituted cyclic imides and processes for preparing organic compounds with the catalyst 有权
标题翻译：包含正取代的环状酰亚胺的催化剂和用催化剂制备有机化合物的方法
公开(公告)号：US07115541B2
公开(公告)日：2006-10-03
申请号：US10181239
申请日：2001-11-08
申请人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
IPC分类号： B01J31/00 , C07D209/56 , C07C63/00 , C07C63/14
CPC分类号： C07C45/34 , B01J23/34 , B01J23/75 , B01J31/0247 , B01J31/2208 , B01J2231/348 , B01J2231/42 , B01J2531/72 , B01J2531/845 , C07C45/00 , C07C45/33 , C07C45/36 , C07C51/265 , C07C51/313 , C07D207/46 , C07D209/48 , C07D215/54 , Y02P20/55 , C07C49/403 , C07C49/78 , C07C65/32 , C07C63/26 , C07C63/04 , C07C55/14
摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
摘要翻译：本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。催化剂可以组合包括酰亚胺化合物和金属化合物。在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物，或其衍生物。作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

6. 发明授权

US06392104B1 Adamantane derivatives and process for producing them 有权
标题翻译：金刚烷衍生物及其制备方法
公开(公告)号：US06392104B1
公开(公告)日：2002-05-21
申请号：US09180478
申请日：1998-11-10
申请人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Naruhisa Hirai
IPC分类号： C07C3522
CPC分类号： C07C29/50 , C07C35/37 , C07C62/06 , C07C62/24 , C07C67/05 , C07C67/08 , C07C67/29 , C07C67/31 , C07C68/02 , C07C69/757 , C07C69/96 , C07C205/18 , C07C205/41 , C07C205/55 , C07C219/24 , C07C233/23 , C07C233/32 , C07C233/74 , C07C235/40 , C07C265/10 , C07C271/34 , C07C2603/74 , C07C69/753 , C07C69/157
摘要： In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the formula (2): wherein R1 and R2 independently represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group; or R1 and R2 may bond together to form a double bond or an aromatic or non-aromatic ring; Y is O or OH and n=1 to 3; or the imide compound and a co-catalyst (e.g., a transition metal compound), an adamantane derivative having a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is oxidized with oxygen. According to the above method, an adamantane derivative having a hydroxyl group together with a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is efficiently obtained.
摘要翻译：在式（2）所示的酰亚胺化合物（例如，N-羟基邻苯二甲酰亚胺）存在下，其中R1和R2独立地表示氢原子，卤素原子，烷基，芳基，环烷基; 或者R 1和R 2可以键合在一起形成双键或芳族或非芳族环; Y为O或OH且n = 1至3;或酰亚胺化合物和助催化剂（例如过渡金属化合物），具有硝基，氨基，羟基等官能团的金刚烷衍生物，羧基，羟甲基和异氰酸酯基被氧氧化。根据上述方法，有效地获得具有羟基的金刚烷衍生物与硝基，氨基，羟基，羧基，羟甲基和异氰酸基等官能团。

7. 发明申请

US20060281629A1 Catalyst comprising N-substituted cyclic imide compound and process for producing organic compound using the catalyst 失效
标题翻译：包含N-取代的环状酰亚胺化合物的催化剂和使用该催化剂制备有机化合物的方法
公开(公告)号：US20060281629A1
公开(公告)日：2006-12-14
申请号：US11504019
申请日：2006-08-15
申请人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
IPC分类号： B01J31/00 , C07C51/16 , C07C51/255
CPC分类号： C07C45/34 , B01J23/34 , B01J23/75 , B01J31/0247 , B01J31/2208 , B01J2231/348 , B01J2231/42 , B01J2531/72 , B01J2531/845 , C07C45/00 , C07C45/33 , C07C45/36 , C07C51/265 , C07C51/313 , C07D207/46 , C07D209/48 , C07D215/54 , Y02P20/55 , C07C49/403 , C07C49/78 , C07C65/32 , C07C63/26 , C07C63/04 , C07C55/14
摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
摘要翻译：本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。催化剂可以组合包括酰亚胺化合物和金属化合物。在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物，或其衍生物。作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

8. 发明申请

US20100331569A1 PROCESS FOR PRODUCTION OF OXYGEN-CONTAINING ORGANIC COMPOUND 失效
标题翻译：生产含氧有机化合物的方法
公开(公告)号：US20100331569A1
公开(公告)日：2010-12-30
申请号：US12919494
申请日：2009-02-27
申请人： Minoru Takano , Naruhisa Hirai , Yasutaka Ishii
发明人： Minoru Takano , Naruhisa Hirai , Yasutaka Ishii
IPC分类号： C07C51/50
CPC分类号： C07C45/33 , B01J27/053 , B01J37/0201 , C07C29/50 , C07C45/36 , C07C51/00 , C07C51/265 , C07C2603/74 , Y02P20/55 , C07C35/37 , C07C47/542 , C07C49/417 , C07C63/04
摘要： Disclosed is a process for the production of an oxygen-containing organic compound by oxidizing an organic compound with molecular oxygen in a liquid phase in the presence both of a catalytic nitrogen-containing cyclic compound and a catalyst including a solid superacid and, supported thereon, a transition metal compound, in which the nitrogen-containing cyclic compound contains, as a ring constituent, a skeleton represented by following Formula (1), wherein X represents an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group. The process gives the oxygen-containing organic compound in a high yield and enables easy recovery and reuse of the catalyst.
摘要翻译：本发明公开了一种在含有催化含氮环状化合物和含有固体超强酸的催化剂存在的条件下，通过在液相中用分子氧氧化有机化合物来制备含氧有机化合物的方法，其中含氮环状化合物含有作为环成分的由下式（1）表示的骨架的过渡金属化合物，其中X表示-OR基，其中R表示氢原子或羟基保护基。该方法以高产率提供含氧有机化合物，并且能够容易地回收和再利用催化剂。

9. 发明申请

US20100317869A1 IMMOBILIZED CYCLIC IMIDE CATALYST AND PROCESS FOR OXIDATION OF ORGANIC COMPOUNDS WITH THE SAME 审中-公开
标题翻译：固定化的环化催化剂及其有机化合物氧化方法
公开(公告)号：US20100317869A1
公开(公告)日：2010-12-16
申请号：US12526010
申请日：2008-02-28
申请人： Yasutaka Ishii , Minoru Takano , Naruhisa Hirai
发明人： Yasutaka Ishii , Minoru Takano , Naruhisa Hirai
IPC分类号： C07F7/10 , C07C45/38 , C07C51/235
CPC分类号： B01J31/0247 , B01J21/08 , B01J31/0254 , B01J31/04 , B01J2531/72 , B01J2531/845 , C07B41/06 , C07B41/08 , C07C45/36 , C07C51/265 , C07D209/48 , Y02P20/55 , C07C47/542 , C07C63/04 , C07C63/26
摘要： To provide a solid catalyst containing a cyclic imide skeleton which is easily available and easily separable from reaction products and which is easily recovered and regenerated, and free from reaction inhibitory factors; and a process for oxidation of organic compounds with the solid catalyst.An immobilized cyclic imide catalyst having a structure represented by following Formula (1), wherein X is oxygen or an —OR group (wherein R is hydrogen atom or a hydroxyl-protecting group); n is 0 or 1; Z1 is a five- or six-membered cyclic imide skeleton to which an aromatic or nonaromatic ring Z2 may be adjacent; elliptically shaped moiety S is an inorganic support; A1 is a group linking silicon atom with the cyclic imide skeleton Z1 or with the ring Z2 and is either a divalent hydrocarbon group or a group composed of a divalent hydrocarbon group and an amide bond (—NHCO—); and the cyclic imide skeleton Z1 and the ring Z2 may each be substituted.
摘要翻译：提供含有环状酰亚胺骨架的固体催化剂，其易于获得并且易于与反应产物分离并易于回收和再生，并且没有反应抑制因子; 以及用固体催化剂氧化有机化合物的方法。具有下式（1）表示的结构的固定化的环状酰亚胺催化剂，其中X为氧或-OR基（其中R为氢原子或羟基保护基）; n为0或1; Z1是芳族或非芳族环Z2可以相邻的五元或六元环酰亚胺骨架; 椭圆形部分S是无机载体; A1是将硅原子与环状酰亚胺骨架Z1或环Z2连接的基团，为二价烃基或由二价烃基和酰胺键（-NHCO-）构成的基团。并且环状酰亚胺骨架Z1和环Z2可各自被取代。

10. 发明授权

US07759515B2 Catalyst comprising N-substituted cyclic imide compound and process for producing organic compounds using the catalyst 有权
标题翻译：包含N-取代的环状酰亚胺化合物的催化剂和使用该催化剂制备有机化合物的方法
公开(公告)号：US07759515B2
公开(公告)日：2010-07-20
申请号：US11434243
申请日：2006-05-16
申请人： Yasutaka Ishii , Naruhisa Hirai , Masahiko Terada
发明人： Yasutaka Ishii , Naruhisa Hirai , Masahiko Terada
IPC分类号： C07C63/00
CPC分类号： C07C45/36 , B01J31/0247 , B01J31/2243 , B01J2231/42 , B01J2231/70 , B01J2231/72 , B01J2531/72 , B01J2531/845 , Y02P20/55
摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
摘要翻译：本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。催化剂可以组合包括酰亚胺化合物和金属化合物。在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物，或其衍生物。作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

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