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    • 7. 发明授权
    • Perfluoroalkylthioaminimide derivatives
    • 全氟烷基硫代氨基亚胺衍生物
    • US4102916A
    • 1978-07-25
    • US747112
    • 1976-12-02
    • Robert A. Falk
    • Robert A. Falk
    • C07C143/155C07C143/08
    • C07D309/12
    • The perfluoroalkyl compounds containing aminimide groups have the formulaR.sub.f R,SCH.sub.2 CH(R.sub.2 CONN(R.sub.3) (R.sub.4)R.sub.5wherein R.sub.f is a perfluoroalkyl, R, is alkylene, oxy or thioalkylene, or alkyleneiminoalkylene; R.sub.2 is hydrogen or alkyl; R.sub.3 and R.sub.4 are alkyl or together with the nitrogen form a heterocyclic ring and R.sub.5 is alkyl which may contain hydroxyl or carboxyl groups or an anionic function such as sulfonate, sulfate or carboxylate, are prepared by the addition of a perfluoroalkylthiol to an aminimide of an .alpha., .beta.-unsaturated acid. These compounds are useful as surfactants.
    • 含有氨基酰亚胺基团的全氟烷基化合物具有式RfR,SCH2CH(R2CONN(R3)(R4)R5,其中Rf是全氟烷基,R是亚烷基,氧基或硫代亚烷基或亚烷基亚氨基亚烷基; R2是氢或烷基; R3和R4是烷基 或与氮一起形成杂环,并且R 5是可以含有羟基或羧基的烷基或阴离子官能团如磺酸盐,硫酸盐或羧酸盐,通过向α,β-不饱和的氨基酰亚胺中加入全氟烷基硫醇制备 这些化合物可用作表面活性剂。