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1. 发明授权

US5039757A Method of manufacturing cationic acrylamide polymers, cationic acrylamide polymers, and the applications of these polymers 失效
标题翻译：制备阳离子丙烯酰胺聚合物，阳离子丙烯酰胺聚合物的方法以及这些聚合物的应用
公开(公告)号：US5039757A
公开(公告)日：1991-08-13
申请号：US454526
申请日：1989-12-21
申请人： Toshihiko Takaki , Kenji Tsuboi , Hiroshi Itoh , Atsuhiko Nitta
发明人： Toshihiko Takaki , Kenji Tsuboi , Hiroshi Itoh , Atsuhiko Nitta
IPC分类号： C08F8/44
CPC分类号： C08F8/44
摘要： This invention provides cationic acrylamide polymers which are highly effective as paper strength agents, drainage agents and suspension flocculants, and which do not show much temporal deterioration; it also provides a method of manufacturing said polymers wherein the manufacturing equipment is compact and can be installed on site, and the cationicity of the polymers can be modified in a short time.This invention comprises a method of manufacturing cationic acrylamide polymers by reaction, with a hypohalogenite, of a (meth)acrylamide homopolymer, a copolymer of (meth)acrylamide and acrylonitrile, a copolymer of (meth)acrylamide and N,N-dimethylacrylamide, in a high temperature range of 50.degree.-110.degree. C. for a short time; the polymers manufactured by said process; and paper strength agents, drainage agents and flocculants having these polymers as their principal constituent.

2. 发明授权

US4729834A Method for adsorbing and desorbing 失效
标题翻译：吸附和解吸方法
公开(公告)号：US4729834A
公开(公告)日：1988-03-08
申请号：US878647
申请日：1986-06-26
申请人： Hiroshi Itoh , Toshimi Nakagawa , Atsuhiko Nitta , Tomio Tanaka , Hideo Kamio , Katsutoshi Nagai
发明人： Hiroshi Itoh , Toshimi Nakagawa , Atsuhiko Nitta , Tomio Tanaka , Hideo Kamio , Katsutoshi Nagai
IPC分类号： B01J20/26 , C08F8/00 , C08F220/54 , C08L33/26 , B01D15/00
CPC分类号： C08F220/54 , B01J20/26 , C08F8/00 , C08L33/26 , C08L2205/02
摘要： Disclosed herein is a high molecular composite material, which comprises as one component thereof a water insolubilized homopolymer of at least one monomer selected from specific N-alkyl- or N-alkylene-substituted (meth)acrylamides, a second copolymer of said at least one monomer with one or more monomers other than the (meth)acrylamides and copolymerizable therewith, or a water-insolubilized product of the homopolymer or either first or second copolymer. The water-insoluble product can form, with a low or high molecular compound containing one or more active hydrogen or hydrophobic groups, a composite material which may be applied widely for absorbing and desorbing a variety of valuable synthetic compounds and natural matter.
摘要翻译：本文公开了一种高分子复合材料，其包含至少一种选自特定N-烷基 - 或N-亚烷基取代的（甲基）丙烯酰胺的单体的水不溶性均聚物作为其一种组分，所述至少一种单体与一种或多种除（甲基）丙烯酰胺之外且可与其共聚的单体，或均聚物或第一或第二共聚物的水不溶性产物。水不溶性产物可以与含有一种或多种活性氢或疏水基团的低分子或高分子化合物形成，其可广泛用于吸收和解吸各种有价值的合成化合物和天然物质的复合材料。

3. 发明授权

US4659773A Process for preparing amidoalkanesulfonic acids polymers 失效
标题翻译：制备酰氨基链烷磺酸聚合物的方法
公开(公告)号：US4659773A
公开(公告)日：1987-04-21
申请号：US755780
申请日：1985-08-23
申请人： Hiroshi Itoh , Atsuhiko Nitta , Hideo Kamio
发明人： Hiroshi Itoh , Atsuhiko Nitta , Hideo Kamio
IPC分类号： C07B61/00 , B01J27/00 , B01J27/02 , C07C67/00 , C07C301/00 , C07C303/22 , C07C309/15 , C07C309/24 , C08F2/22 , C08F2/44 , C08F220/58 , C08F28/02
CPC分类号： C08F220/58
摘要： Disclosed is a novel process for preparing amidoalkanesulfonic acids of the general formula ##STR1## or derivatives thereof by reacting a nitrile compound (1) with a .beta.-hydroxyalkanesulfonic acid or a derivative thereof (2) in concentrated sulfuric acid.Among the compounds of the general formula (3) and derivatives thereof, unsaturated amido- and phenyl-substituted alkanesulfonic acids and derivatives thereof (in particular, 2-acrylamido-2-phenylpropanesulfonic acid and derivatives thereof) represented by the general formula ##STR2## can be copolymerized with other monomers and the like to provide useful materials such as copolymer-coated solid materials, copolymer emulsions, pigment dispersants and the like.
摘要翻译：公开了通过使腈化合物（1）与β-羟基链烷磺酸或其衍生物（2）在浓硫酸中反应来制备通式为（3）的酰胺基链烷磺酸或其衍生物的新方法。在通式（3）的化合物及其衍生物中，由通式（IMAGE）表示的不饱和酰氨基和苯基取代的链烷磺酸及其衍生物（特别是2-丙烯酰胺基-2-苯基丙磺酸及其衍生物）（4）可以与其它单体等共聚以提供有用的材料，例如共聚物涂覆的固体材料，共聚物乳液，颜料分散剂等。

4. 发明授权

US4654177A Hydroxyalkanesulfonic acids and their derivatives and process for preparing same 失效
标题翻译：羟基链烷磺酸及其衍生物及其制备方法
公开(公告)号：US4654177A
公开(公告)日：1987-03-31
申请号：US776797
申请日：1985-09-17
申请人： Hiroshi Itoh , Atsuhiko Nitta , Hideo Kamio
发明人： Hiroshi Itoh , Atsuhiko Nitta , Hideo Kamio
IPC分类号： C07C309/08 , C07C143/42
CPC分类号： C07C309/00
摘要： Hydroxyalkanesulfonic acids of the general formula ##STR1## where R is a lower alkyl group having 1 to 10 carbon atoms, and derivatives (such as alkali metal salts and the like) of the sulfonic acids are novel compounds. These compounds can be prepared, for example, by a process which comprises reacting an .alpha.-alkylstyrene with the hydrogensulfite ion in an aqueous medium in the presence of oxygen. These compounds are useful as raw materials for the manufacture of amidoalkanesulfonic acid derivatives having such applications as lime soap dispersants, raw materials for the synthesis of water-soluble polymers, fiber modifiers and the like.
摘要翻译：其中R是具有1-10个碳原子的低级烷基，和磺酸的衍生物（如碱金属盐等）的通式为“IMAGE”（I）的羟基链烷磺酸是新的化合物。这些化合物可以例如通过包括在氧气存在下在水性介质中使α-烷基苯乙烯与亚硫酸氢盐离子反应的方法来制备。这些化合物可用作制备具有钙皂分散剂，合成水溶性聚合物的原料，纤维改性剂等的应用的酰氨基磺酸衍生物的原料。

5. 发明授权

US5624998A Hardenable composition, aqueous gel and applications 失效
标题翻译：可硬化组合物，水凝胶和应用
公开(公告)号：US5624998A
公开(公告)日：1997-04-29
申请号：US600029
申请日：1996-02-12
申请人： Hiroshi Itoh , Takashi Abe , Hideo Kamio , Hitoshi Yamashita , Atsuhiko Nitta
发明人： Hiroshi Itoh , Takashi Abe , Hideo Kamio , Hitoshi Yamashita , Atsuhiko Nitta
IPC分类号： C08F220/54 , C08F220/56 , C08K3/22 , C08K3/10
CPC分类号： C08K3/22 , C08F220/54 , C08F220/56
摘要： The present invention provides an aqueous gel comprising a polymer of (meth)acrylamide or particular (meth)acrylamide derivative(s), particulate metal oxide(s) and an aqueous medium, a process for producing said gel, and products utilizing said gel.This aqueous gel can be produced so as to have transparency, has fire resistance and can prevent the spreading of flames, and is highly elastic. The aqueous gel, when produced as a transparent gel, becomes cloudy when heated or cooled and is useful for the shielding of heat rays or cold radiation.
摘要翻译：本发明提供一种包含（甲基）丙烯酰胺或特定（甲基）丙烯酰胺衍生物的聚合物，颗粒金属氧化物和水性介质的聚合物的水凝胶，所述凝胶的制备方法和利用所述凝胶的产物。该水性凝胶可以制造成具有透明性，具有耐火性，并且可以防止火焰蔓延，并且具有高弹性。水凝胶当作为透明凝胶生产时，在加热或冷却时变得浑浊，并且可用于屏蔽热射线或冷辐射。

6. 发明授权

US5519088A Hardenable composition, aqueous gel and applications thereof 失效
标题翻译：可硬化组合物，水凝胶及其应用
公开(公告)号：US5519088A
公开(公告)日：1996-05-21
申请号：US320786
申请日：1994-10-11
申请人： Hiroshi Itoh , Takashi Abe , Hideo Kamio , Hitoshi Yamashita , Atsuhiko Nitta
发明人： Hiroshi Itoh , Takashi Abe , Hideo Kamio , Hitoshi Yamashita , Atsuhiko Nitta
IPC分类号： C08F220/54 , C08F220/56 , C08K3/22 , C08K3/10
CPC分类号： C08K3/22 , C08F220/54 , C08F220/56
摘要： The present invention provides an aqueous gel comprising a polymer of (meth)acrylamide or particular (meth)acrylamide derivative(s), particulate metal oxide(s) and an aqueous medium, a process for producing said gel, and products utilizing said gel.This aqueous gel can be produced so as to have transparency, has fire resistance and can prevent the spreading of flames, and is highly elastic. The aqueous gel, when produced as a transparent gel, becomes cloudy when heated or cooled and is useful for the shielding of heat rays or cold radiation.
摘要翻译：本发明提供一种包含（甲基）丙烯酰胺或特定（甲基）丙烯酰胺衍生物的聚合物，颗粒金属氧化物和水性介质的聚合物的水凝胶，所述凝胶的制备方法和利用所述凝胶的产物。该水性凝胶可以制造成具有透明性，具有耐火性，并且可以防止火焰蔓延，并且具有高弹性。水凝胶当作为透明凝胶生产时，在加热或冷却时变得浑浊，并且可用于屏蔽热射线或冷辐射。

7. 发明授权

US5155191A Preparation process of granular polymers 失效
标题翻译：颗粒聚合物的制备方法
公开(公告)号：US5155191A
公开(公告)日：1992-10-13
申请号：US835115
申请日：1992-02-14
申请人： Hiroshi Itoh , Takashi Abe , Kouji Ohkoshi , Atsuhiko Nitta
发明人： Hiroshi Itoh , Takashi Abe , Kouji Ohkoshi , Atsuhiko Nitta
IPC分类号： C08F2/18 , C08F2/44 , C08F4/12 , C08F20/54
CPC分类号： C08F2/44 , C08F20/54
摘要： By dispersing and polymerizing at least one N-alkyl-or N-alkylene-substituted (meth)acrylamide or a mixture of at least one N-alkyl- or N-alkylene-substituted (meth)acrylamide and other copolymerizable monomer is an aqueous inorganic salt solution having inorganic particulates suspended, there is provided a preparation process of granular polymers containing no impurities such as polymer stabilizers, surface active agents, etc. The granular polymers are useful as concentrating agents, slow releasing base materials, etc.
摘要翻译：通过分散和聚合至少一种N-烷基 - 或N-亚烷基取代的（甲基）丙烯酰胺或至少一种N-烷基 - 或N-亚烷基取代的（甲基）丙烯酰胺和其它可共聚单体的混合物，具有悬浮无机颗粒的盐溶液，提供了不含杂质的粒状聚合物如聚合物稳定剂，表面活性剂等的制备方法。粒状聚合物可用作浓缩剂，缓释基材等。

8. 发明授权

US5306572A EL element comprising organic thin film 失效
标题翻译： EL元件包括有机薄膜
公开(公告)号：US5306572A
公开(公告)日：1994-04-26
申请号：US993882
申请日：1992-12-23
申请人： Yutaka Ohashi , Nobuhiro Fukuda , Atsuhiko Nitta , Sadao Kobayashi
发明人： Yutaka Ohashi , Nobuhiro Fukuda , Atsuhiko Nitta , Sadao Kobayashi
IPC分类号： H01L51/52 , H05B33/10 , H05B33/14 , B32B9/00
CPC分类号： H05B33/14 , H01L51/5206 , H01L51/5221 , H05B33/10 , H01L51/5088 , H01L51/5092 , Y10S428/917
摘要： Herein disclosed are organic thin film EL element having layer structures each of which comprises at least one organic thin film sandwiched between two electrodes, at least one of which is a metal thin film or one of which is a metal thin film and the other of which is a transparent conductive inorganic thin film, and an optional thin film of an inorganic semiconductor positioned between the transparent conductive thin film and the organic thin film, wherein an interfacial layer is fromed between the organic thin film and the metal thin film adjacent to the organic thin film by treating the organic thin film and/or the metal thin film with an organic phosphorus atom-containing compound; and/or wherein an interfacial layer is formed between the organic thin film and the inorganic thin film adjacent to the inorganic thin film by treating the organic thin film and/or the inorganic thin film with a silane-coupling agent. In the EL element, the metal thin film formed on the organic thin film has low unevenness, the metal thin film is strongly adhered to the organic thin film.
摘要翻译：这里公开了具有层结构的有机薄膜EL元件，每个层结构包括夹在两个电极之间的至少一个有机薄膜，其中至少一个是金属薄膜或其中一个是金属薄膜，另一个是金属薄膜是透明导电性无机薄膜，和位于透明导电薄膜与有机薄膜之间的无机半导体薄膜，其中界面层从有机薄膜与邻近有机薄膜的金属薄膜之间形成用有机磷原子化合物处理有机薄膜和/或金属薄膜的薄膜; 和/或其中通过用硅烷偶联剂处理有机薄膜和/或无机薄膜，在有机薄膜和与无机薄膜相邻的无机薄膜之间形成界面层。在EL元件中，形成在有机薄膜上的金属薄膜具有低的不均匀性，金属薄膜牢固地附着在有机薄膜上。

9. 发明授权

US5292821A Catonic acrylamide polymers and the applications of these polymers 失效
标题翻译：催化丙烯酰胺聚合物和这些聚合物的应用
公开(公告)号：US5292821A
公开(公告)日：1994-03-08
申请号：US82773
申请日：1993-06-28
申请人： Toshihiko Takaki , Kenji Tsuboi , Hiroshi Itoh , Atsuhiko Nitta
发明人： Toshihiko Takaki , Kenji Tsuboi , Hiroshi Itoh , Atsuhiko Nitta
IPC分类号： C08F8/44 , C08F8/20
CPC分类号： C08F8/44
摘要： This invention provides cationic acrylamide polymers which are highly effective as paper strength agents, drainage agents and suspension flocculants, and which do not show much temporal deterioration; it also provides a method of manufacturing said polymers wherein the manufacturing equipment is compact and can be installed on site, and the cationicity of the polymers can be modified in a short time.This invention comprises a method of manufacturing cationic acrylamide polymers by reaction, with a hypohalogenite, of a (meth)acrylamide homopolymer, a copolymer of (meth)acrylamide and acrylonitrile, a copolymer of (meth)acrylamide and, N,N-dimethylacrylamide, in a high temperature range of 50.degree.-110.degree. C. for a short time; the polymers manufactured by said process; and paper strength agents, drainage agents and flocculants having these polymers as their principal constituent.
摘要翻译：本发明提供了作为纸张强度剂，引流剂和悬浮絮凝剂非常有效的阳离子丙烯酰胺聚合物，并且不显示出太多的时效性; 它还提供了一种制造所述聚合物的方法，其中制造设备紧凑并且可以现场安装，聚合物的阳离子度可以在短时间内被改变。本发明包括使用（甲基）丙烯酰胺均聚物，（甲基）丙烯酰胺和丙烯腈的共聚物，（甲基）丙烯酰胺和N，N-二甲基丙烯酰胺的共聚物与（甲基）丙烯酰胺均聚物的次卤酸盐反应制备阳离子丙烯酰胺聚合物的方法，在50度-110摄氏度的高温范围内短时间; 由所述方法制造的聚合物; 和具有这些聚合物作为其主要成分的纸强度剂，引流剂和絮凝剂。

10. 发明授权

US5239014A Cationic acrylamide polymers and the applications of these polymers 失效
标题翻译：阳离子丙烯酰胺聚合物和这些聚合物的应用
公开(公告)号：US5239014A
公开(公告)日：1993-08-24
申请号：US725611
申请日：1991-07-03
申请人： Toshihiko Takaki , Kenji Tsuboi , Hiroshi Itoh , Atsuhiko Nitta
发明人： Toshihiko Takaki , Kenji Tsuboi , Hiroshi Itoh , Atsuhiko Nitta
IPC分类号： C08F8/44
CPC分类号： C08F8/44
摘要： This invention provides cationic acrylamide polymers which are highly effective as paper strength agents, drainage agents and suspension flocculants, and which do not show much temporal deterioration; it also provides a method of manufacturing said polymers wherein the manufacturing equipment is compact and can be installed on site, and the cationicity of the polymers can be modified in a short time.This invention comprises a method of manufacturing cationic acrylamide polymers by reaction, with a hypohalogenite, of a (meth)acrylamide homopolymer, a copolymer of (meth)acrylamide and acrylonitrile, a copolymer of (meth)acrylamide and N,N-dimethylacrylamide, in a high temperature range of 50.degree.-110.degree. C. for a short time; the polymers manufactured by said process; and paper strength agents, drainage agents and flocculants having these polymers as their principal constituent.
摘要翻译：本发明提供了作为纸张强度剂，引流剂和悬浮絮凝剂非常有效的阳离子丙烯酰胺聚合物，并且不显示出太多的时效性; 它还提供了一种制造所述聚合物的方法，其中制造设备紧凑并且可以现场安装，聚合物的阳离子度可以在短时间内被改变。本发明包括通过与（甲基）丙烯酰胺均聚物，（甲基）丙烯酰胺和丙烯腈的共聚物，（甲基）丙烯酰胺和N，N-二甲基丙烯酰胺的共聚物与（甲基）丙烯酰胺均聚物的次卤酸盐反应制备阳离子丙烯酰胺聚合物的方法， 50°-110℃的高温范围短时间; 由所述方法制造的聚合物; 和具有这些聚合物作为其主要成分的纸强度剂，引流剂和絮凝剂。

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