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1. 发明申请

US20040192983A1 Acetylene hydrogenation catalyst with segregated palladium skin 审中-公开
标题翻译：具有分离钯皮的乙炔加氢催化剂
公开(公告)号：US20040192983A1
公开(公告)日：2004-09-30
申请号：US10775913
申请日：2004-02-10
申请人： Chevron Phillips Chemical Co.
发明人： Joseph J. Bergmeister , Tin-Tack P. Cheung , Gary A. Delzer
IPC分类号： C07C005/03 , B01J027/13
CPC分类号： B01J35/10 , B01J23/44 , B01J23/50 , B01J23/58 , B01J35/008 , B01J35/0093 , B01J35/08 , B01J35/1009 , B01J35/1071 , B01J35/1076 , C07C5/09 , C07C7/167 , C07C2521/04 , C07C2521/06 , C07C2523/02 , C07C2523/06 , C07C2523/44 , C07C2523/50 , C07C2523/66 , Y02P20/52 , C07C11/04
摘要： A catalyst for the selective hydrogenation of acetylene comprising a support having a uniformly round external surface; palladium in the range of about 0.01 to 1.0 weight percent of the catalyst and substantially all of the palladium being concentrated in a skin periphery of the catalyst; and silver in the range of about 0.5 to 10.0 times the weight of the palladium. Preferably, the support is selected from the group consisting of alumina, titania, zirconia, zinc aluminate, zinc titanate and mixtures thereof, and/or the skin has a thickness less than about 400 microns.
摘要翻译：用于乙炔选择性氢化的催化剂，包括具有均匀圆形外表面的载体; 钯在催化剂的约0.01至1.0重量％的范围内，并且基本上所有的钯都集中在催化剂的皮肤周边; 和银的重量的约0.5至10.0倍的范围内。优选地，载体选自氧化铝，二氧化钛，氧化锆，铝酸锌，钛酸锌及其混合物，和/或皮肤具有小于约400微米的厚度。

2. 发明申请

US20040030207A1 Selective hydrogenation of acetylenes 审中-公开
标题翻译：乙炔的选择氢化
公开(公告)号：US20040030207A1
公开(公告)日：2004-02-12
申请号：US10215096
申请日：2002-08-08
申请人： CATALYTIC DISTILLATION TECHNOLOGIES
发明人： J. Yong Ryu , John R. Adams , Willibrord A. Groten
IPC分类号： C07C005/00 , C07C005/03 , C07C005/08
CPC分类号： C07C7/167 , C07C5/09 , C07C2523/755 , C07C2523/80 , C07C2523/89
摘要： A process for removing acetylenic compounds using unsulfided metallic nickel or unsulfided metallic nickel modified with metallic Mo, Re, Bi or mixtures in which the catalyst is used alone or is used in combination with other acetylenic selective catalysts. The unsulfided metallic nickel catalyst or modified catalyst must be the first catalyst to contact the hydrocarbon stream.
摘要翻译：使用用金属Mo，Re，Bi改性的未硫化金属镍或未硫化金属镍除去炔属化合物的方法或其中催化剂单独使用或与其它炔属选择性催化剂组合使用的混合物。未硫化的金属镍催化剂或改性催化剂必须是与烃流接触的第一催化剂。

3. 发明申请

US20020038065A1 Hydrogenation catalysts 有权
公开(公告)号：US20020038065A1
公开(公告)日：2002-03-28
申请号：US09969054
申请日：2001-10-02
申请人： Sud-Chemie Inc.
发明人： Dinah C. Huang , William M. Faris , P. Donald Hopkins , Paul Jerus
IPC分类号： C07C005/02 , C07C005/03 , C07C005/10
CPC分类号： C10G45/52 , B01J23/44
摘要： A hydrogenation catalyst which is sulfur tolerant and which includes from about 0.1 to about 1 percent platinum by weight and from 0.2 to about 2 percent by weight palladium on a predominantly theta alumina carrier. Also disclosed is a process for the manufacture and use of the hydrogenation catalyst.

4. 发明申请

US20020022754A1 Process for hydrogenating cuts containing hydrocarbons, in particular unsaturated molecules containing at least two double bonds or at least one triple bond 有权
标题翻译：氢化含有烃的切割的方法，特别是含有至少两个双键或至少一个三键的不饱和分子
公开(公告)号：US20020022754A1
公开(公告)日：2002-02-21
申请号：US09892764
申请日：2001-06-28
申请人： Institut Francais du Petrole
发明人： Christophe Boyer , Vincent Coupard , Quentin Debuisschert
IPC分类号： C07C005/02 , C07C005/03 , C07C005/05 , C07C005/08
CPC分类号： C07C7/163 , C10G45/32 , C10G65/06 , C10G2300/4081
摘要： Hydrogenation of a liquid cut containing hydrocarbons, in particular unsaturated molecules containing at least two double bonds or at least one triple bond, is described wherein the unsaturated molecules are at hydrogenated to less unsaturated molecules containing at least one double bond, in at least one reactor comprising at least two distinct beds of at least one hydrogenation catalyst, and wherein a gas phase containing hydrogen is introduced, a portion thereof being mixed with said cut upstream of the first catalyst bed and a portion thereof being introduced upstream of the subsequent beds contained in said reactor.
摘要翻译：描述含有烃，特别是含有至少两个双键或至少一个三键的不饱和分子的液体切割的氢化，其中不饱和分子在至少一个反应器中被氢化成含有至少一个双键的较不饱和分子包括至少两个不同的床的至少一个氢化催化剂，并且其中引入含有氢的气相，其一部分与所述第一催化剂床的上游的所述切口混合，并且其一部分被引入到随后的床的上游说反应堆。

5. 发明申请

US20040171903A1 Methods and systems for purifying styrene feedstock comprising use of low palladium catalyst 审中-公开
标题翻译：用于纯化苯乙烯原料的方法和系统，包括使用低钯催化剂
公开(公告)号：US20040171903A1
公开(公告)日：2004-09-02
申请号：US10793005
申请日：2004-03-04
发明人： James T. Merrill
IPC分类号： C07C005/03 , C07C007/163 , B01J008/00
CPC分类号： C07C15/46 , C07C7/167 , C07C2521/04 , C07C2523/02
摘要： Apparatus, methods and systems useful for removing phenylacetylene from crude styrene feedstock are disclosed. Generally the processes and systems comprise the catalytic reduction of phenylacetylene to produce styrene via injection of a phenylacetylene reducing agent, such as hydrogen. A phenylacetylene reduction catalyst preferred Wherein comprises palladium on a calcium aluminate carrier, wherein the catalyst comprises less than 0.3 weight percent palladium.
摘要翻译：公开了用于从粗苯乙烯原料中除去苯乙炔的装置，方法和系统。通常，该方法和系统包括苯基乙炔的催化还原以通过注入苯乙炔还原剂如氢气来生产苯乙烯。苯乙炔还原催化剂优选，其中在铝酸钙载体上包含钯，其中催化剂包含小于0.3重量％的钯。

6. 发明申请

US20030023121A1 Carrier catalytic converter for theselective hydrogenation of alkines and dienes 失效
标题翻译：用于烷烃和二烯烃的选择性氢化的载体催化转化器
公开(公告)号：US20030023121A1
公开(公告)日：2003-01-30
申请号：US10148798
申请日：2002-06-05
发明人： Andrea Frenzel , Michael Hesse , Andreas Ansmann , Ekkehard Schwab
IPC分类号： B01J023/56 , C07C005/03 , C07C005/08 , C07C005/09
CPC分类号： C07C7/163 , B01J23/48 , B01J23/50 , B01J23/66 , B01J35/0006 , C07C7/167 , C07C2521/08 , C07C2523/44 , C07C2523/50 , C07C11/02
摘要： A catalyst for the selective hydrogenation of alkynes and dienes in C2-C5null-olefin mixtures is described. These catalysts contain (a) a metal of the tenth group of the Periodic Table, (b) a metal of the eleventh group of the Periodic Table and (c) if required, a compound of a metal of the first or second group of the Periodic Table, these metals being applied to a support which is selected from the group consisting of silica, titanium dioxide, zirconium oxides, spinels, zinc aluminates, zinc titanates or mixtures of these substances, and the metal of the eleventh group being distributed homogeneously over the cross section of the catalyst particle and the metal of the tenth group being present in the edge layer close to the surface of the catalyst particle. Such a catalyst is prepared by applying the metal of the eleventh group, preferably during the preparation of the support itself, by impregnation with a solution of a suitable metal salt.
摘要翻译：描述了在C2-C5 + - 烯烃混合物中选择氢化炔烃和二烯烃的催化剂。这些催化剂含有（a）元素周期表第十组的金属，（b）元素周期表第十一组的金属和（c）如果需要，可以使用第一组或第二组的金属化合物周期表中，这些金属被施加到选自二氧化硅，二氧化钛，氧化锆，尖晶石，铝酸锌，钛酸锌或这些物质的混合物的载体上，并且第十一基团的金属均匀地分布在催化剂颗粒的横截面和第十组的金属存在于靠近催化剂颗粒表面的边缘层中。这样的催化剂是通过施加第十一基团的金属，优选在制备载体本身期间通过用合适的金属盐的溶液浸渍来制备的。

7. 发明申请

US20020004621A1 Selective hydrogenation process for removing C10 -C16 diolefins 有权
标题翻译：用于去除C10-C16二烯烃的选择性氢化方法
公开(公告)号：US20020004621A1
公开(公告)日：2002-01-10
申请号：US09837986
申请日：2001-04-19
发明人： Yi Xu , Peicheng Wu , Yu Wang , Dong Liu , Zhengguo Ling , Xiaolei Huang
IPC分类号： C07C005/03
CPC分类号： C07C11/02 , C07C7/163 , C07C2521/04 , C07C2523/04 , C07C2523/14 , C07C2523/44 , C07C2523/50 , C07C2523/52
摘要： The present invention provides an improved selective hydrogenation process for removing C10-C16 diolefins in the product from dehydrogenation of C10-C16 paraffins to mono-olefins, which process includes bringing the mixture stream of paraffins and olefins containing C10-C16 mono-olefins and C10-C16 diolefins into contact with a specific hydrogenation catalyst in a plurality of hydrogenation reactors connected in series under the reaction conditions for hydrogenation. Hydrogen is injected into each reactor respectively. To convert the diolefins in the mixture stream of paraffins and olefins into mono-olefins, null-alumina having a specific surface area of 50-300 m2/g and a pore volume of 0.2-2.0 cm3/g is used as the supporter of the hydrogenation catalyst, palladium is supported on the supporter as the main catalyst element and an element selected from silver, gold, tin, lead or potassium is supported on the supporter as the promoter.
摘要翻译：本发明提供了一种改进的选择性氢化方法，用于从C10-C16链烷烃脱氢成单烯烃中除去产物中的C 10 -C 16二烯烃，该方法包括使含有C 10 -C 16单烯烃和C 10 -C 16单烯烃的链烷烃和烯烃的混合物流 -C16二烯烃与在氢化反应条件下串联连接的多个氢化反应器中的特定氢化催化剂接触。将氢气分别注入每个反应器。为了将链烷烃和烯烃的混合物流中的二烯烃转化为单烯烃，使用比表面积为50-300m 2 / g和孔体积为0.2-2.0cm 3 / g的γ-氧化铝作为氢化催化剂，钯负载在作为主要催化剂元素的载体上，并且选自银，金，锡，铅或钾的元素作为助催化剂负载在载体上。

8. 发明申请

US20010014764A1 Process for the production of catalyst packing, reactor containing catalyst packing, and the use thereof 失效
标题翻译：用于生产催化剂填料的方法，含有催化剂填料的反应器及其用途
公开(公告)号：US20010014764A1
公开(公告)日：2001-08-16
申请号：US09777849
申请日：2001-02-07
发明人： Franz Josef Brocker , Heinrich Laib , Gerd Rohrbacher , Ekkehard Schwab , Helmut Jansen
IPC分类号： C07C005/03 , B01J035/02
CPC分类号： B01J19/32 , B01J35/04 , B01J2219/32268 , B01J2219/32279 , B01J2219/32286 , B01J2219/32408 , B01J2219/32425 , B01J2219/32433 , B01J2219/32466 , B01J2219/32483 , B01J2219/3306
摘要： The invention relates to catalyst packing and a production process for catalyst packing in which a fabricated woven or knitted fabric in the form of continuous web goods is shaped to give a package by stacking a plurality of layers, and segments (S) are cut out of the package and assembled to give one or more course(s) which completely fill the reactor cross section. A reactor containing catalyst packing of this type is particularly suitable for catalytic reactions, preferably for hydrogenations, selective hydrogenations, selective oxidations or isomerizations.
摘要翻译：本发明涉及催化剂填料和催化剂填料的生产方法，其中以连续网状物料形式制成的编织物或针织物被成形为通过堆叠多层来形成包装，并将片段（S）从包装并组装以给出完全填充反应器横截面的一个或多个过程。含有这种催化剂填料的反应器特别适用于催化反应，优选氢化，选择性氢化，选择性氧化或异构化。

9. 发明申请

US20040019245A1 OLEFIN PLANT RECOVERY SYSTEM EMPLOYING A COMBINATION OF CATALYTIC DISTILLATION AND FIXED BED CATALYTIC STEPS 失效
标题翻译：使用催化蒸馏和固定床催化步骤的组合的烯烃回收系统
公开(公告)号：US20040019245A1
公开(公告)日：2004-01-29
申请号：US10202702
申请日：2002-07-24
发明人： Robert J. Gartside , Robert I. Haines , Thomas Skourlis , Charles Sumner
IPC分类号： C07C005/03 , C07C005/08
CPC分类号： C10G70/02 , C07C7/163 , C07C7/167 , C10G2400/20 , Y02P20/127 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： Presented is an improvement to a previous invention involving the catalytic hydrogenation of the C2 to C5 and heavier acetylenes and dienes in a thermally cracked feed stream without significantly hydrogenating the C2 and C3 olefins. The improvement involves the use of a fixed bed hydrogenation reactor system in combination with a modified version of the catalytic distillation unit used in the prior art. The modification to the catalytic distillation unit involves improvement of the liquid recycle scheme. The fixed bed reactors combined with the modified catalytic distillation allows for 100% conversion of acetylene and helps to maintain high conversion of the other dienes and acetylenes with no ethylene or propylene conversion under a variety of conditions. These condition variations include but are not limited to the feed diene and acetylene composition, the mol % carbon monoxide in the feed, and catalyst deactivation. With catalytic distillation alone, complete conversion of the acetylene as stated above can not be achieved without ethylene loss, nor would satisfactory operation and control be possible under the variety of conditions experienced during a commercial operation.
摘要翻译：本发明涉及一种先前的发明，涉及在热裂化的进料流中C2至C5和较重的乙炔和二烯的催化氢化，而不显着氢化C2和C3烯烃。该改进涉及使用固定床氢化反应器系统与现有技术中使用的催化蒸馏单元的改进形式。对催化蒸馏装置的改进涉及液体循环方案的改进。与改性催化蒸馏相结合的固定床反应器允许乙炔转化率为100％，并且有助于在各种条件下不用乙烯或丙烯转化，保持其它二烯和乙炔的高转化率。这些条件变化包括但不限于进料二烯和乙炔组成，进料中的一氧化碳摩尔％和催化剂失活。单独进行催化蒸馏，如果没有乙烯损失，则不能实现如上所述的乙炔的完全转化，在商业操作中经历的各种条件下也不能令人满意的操作和控制。

10. 发明申请

US20020173650A1 Metal complexes for hydrogenation of unsaturated compounds 失效
标题翻译：用于氢化不饱和化合物的金属络合物
公开(公告)号：US20020173650A1
公开(公告)日：2002-11-21
申请号：US10011680
申请日：2001-12-04
发明人： Steven P. Nolan , Hon Man Lee , Anna C. Hillier
IPC分类号： C07F015/00 , C07C005/03
CPC分类号： C07F15/0033 , B01J31/181 , B01J31/2273 , B01J31/2291 , B01J31/2295 , B01J2231/645 , B01J2531/0288 , B01J2531/827 , C07C5/03 , C07C2531/22
摘要： The cationic iridium carbene complexes nullIr(cod)(N)(L)nullX have been synthesized by reaction of nullIr(cod)(py)2nullPF6 with L or NL ligands. Complexes of this type are active hydrogenation catalysts capable of hydrogenating simple olefins at room temperature and atmospheric pressure of hydrogen or by transfer hydrogenation.
摘要翻译：通过[Ir（cod）（py）2] PF6与L或NL配体的反应合成了阳离子铱卡宾配合物[Ir（cod）（N）（L）] X。这种类型的络合物是能够在室温和氢气的大气压下或通过转移氢化使单烯烃氢化的活性氢化催化剂。

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