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    • 5. 发明授权
    • Polar polymeric coating
    • 极性聚合物涂层
    • US06746721B1
    • 2004-06-08
    • US09601709
    • 2000-08-02
    • Eva Maria Moser
    • Eva Maria Moser
    • B22F326
    • B05D1/62
    • The coating of substrates, particularly polymers and ceramic or metal substrate, for the production of a polar, polymeric coating is conducted by plasma polymerization. The process gas used for this purpose is free from water or water vapor and contains at least one organic compound, in addition to an inorganic gas and/or carbon monoxide and/or carbon dioxide and/or ammonium and/or nitrogen and/or another gas containing nitrogen.
    • 用于生产极性聚合物涂层的基底,特别是聚合物和陶瓷或金属基底的涂层通过等离子体聚合进行。 用于此目的的工艺气体除了无机气体和/或一氧化碳和/或二氧化碳和/或铵和/或氮和/或另一种以外还含有至少一种有机化合物,不含水或水蒸汽,并含有至少一种有机化合物 含氮气体。
    • 8. 发明授权
    • Techniques for infiltration of a powder metal skeleton by a similar alloy with melting point depressed
    • 通过熔点相似的合金浸入粉末金属骨架的技术
    • US06719948B2
    • 2004-04-13
    • US09863073
    • 2001-05-21
    • Adam M. LorenzEmanuel M. SachsSamuel M. Allen
    • Adam M. LorenzEmanuel M. SachsSamuel M. Allen
    • B22F326
    • B22F3/26B33Y80/00
    • In infiltrating a porous metal skeleton an infiltrant composition is used similar to that of the powder skeleton, but with the addition of a melting point depressant. The infiltrant quickly fills the skeleton. As the melting point depressant diffuses into the base powder, the liquid may undergo diffusional solidification and the material eventually homogenizes. Maintaining the infiltrant at a liquidus composition for the infiltration temperature typically ensures that the bulk composition or properties will remain uniform throughout the part, particularly in the direction of infiltration. Success of such an infiltration is enhanced by effective means of maintaining the molten infiltrant at a liquidus composition. It is also beneficial, in some cases, for the time scale of the infiltration to be much faster than the time scale of the diffusion of the melting point depressant and the subsequent solidification and homogenization. The relative rates of infiltration and diffusion/solidification rate are significantly impacted by the choice of materials system. Other factors also influence these rates. They include: selection of powder size (diameter), shape, surface roughness, and size distribution, feeding liquid from different locations, liquid feeder channels, smoothing of the part surface with fine powder and affecting infiltrant fluid properties. Various material systems are also disclosed, as are methods of designing a process of infiltrating a part, including binary and ternary and higher component systems. Homogeneous composition may be achieved using these techniques, particularly along the direction of infiltration.
    • 在渗透多孔金属骨架时,使用类似于粉末骨架的浸润剂组合物,但加入了降低熔点的组合物。 渗透剂快速填满骨架。 当熔点降低剂扩散到基础粉末中时,液体可能经历扩散凝固,并且材料最终均匀化。 为了渗透温度将浸润剂维持在液相线组合物上通常确保整个组分或性质在整个部分,特别是在渗透方向上保持均匀。 通过将熔融浸润剂保持在液相组成的有效手段来增强这种浸渗的成功。 在某些情况下,渗透的时间尺度比熔点抑制剂的扩散时间尺度和随后的凝固和均化也快得多也是有益的。 渗透和扩散/凝固速率的相对速率受材料体系选择的影响很大。 其他因素也影响这些利率。 它们包括:选择粉末尺寸(直径),形状,表面粗糙度和尺寸分布,从不同位置输送液体,液体进料通道,用细粉进行部分表面的平滑处理并影响浸润液的性质。 还公开了各种材料系统,以及设计渗透部件的方法的方法,包括二元和三元和更高分量系统。 使用这些技术可以实现均匀组合,特别是沿渗透方向。
    • 9. 发明授权
    • Powder injection molding and infiltration process
    • 粉末注射成型和渗透过程
    • US06319437B1
    • 2001-11-20
    • US09250148
    • 1999-02-16
    • Norbert B. ElsnerStanley ZalkindIan Sidney R. ClarkFred Leavitt
    • Norbert B. ElsnerStanley ZalkindIan Sidney R. ClarkFred Leavitt
    • B22F326
    • C22C1/1036A63B53/047A63B53/0487A63B2053/0416A63B2209/00A63B2209/02B22F3/26B22F2998/10C22C2001/1021C22C2204/00B22F3/1121B22F7/062
    • A powder injection molding and infiltration process. A powder of a skeleton material having a relatively high melting point is mixed with a composite binder to form a mold mixture. The composite binder is comprised of at least two binder materials. The mold mixture is molded into a desired shape in a mold device to produce a molded part. The composite binder is then removed to produce voids in the molded part and the voids are filled by infiltrating an infiltrant comprised of an infiltrant material having a relatively low melting point to produce a composite molded part. In a preferred embodiment the skeleton material is TiB2 and the infiltrant material is aluminum and the composite binder is comprised of a plastic and a wax. In this embodiment the wax portion of the composite binder is removed using a solvent and the plastic is removed during the infiltration step. The resulting composite part has a TiB2 skeleton with voids substantially filled with aluminum. This process is especially useful for making light and strong parts with complex shapes such as golf club heads, tools, cutting implements, thermal management products, rocket motor components and bicycle parts. In another preferred embodiment, a golf club head is comprised of three parts: an non-sintered TiB2 part for the body of the head, a sintered TiB2 part for the striking surface of the head, and a heavy tungsten part to provide weight for the head. In this embodiment, the aluminum infiltrant substantially fills the voids in all three parts to create a golf club head with optimum characteristics.
    • 粉末注射成型和渗透过程。 将具有较高熔点的骨架材料的粉末与复合粘合剂混合以形成模具混合物。 复合粘合剂由至少两种粘合剂材料组成。 将模具混合物在模具装置中模制成所需形状以制造模制件。 然后去除复合粘合剂以在模制部件中产生空隙,并且通过浸渍由具有相对低熔点的渗透材料组成的渗透剂来填充空隙以产生复合模制部件。 在优选的实施方案中,骨架材料是TiB 2,浸润材料是铝,复合粘合剂由塑料和蜡组成。 在该实施方案中,使用溶剂除去复合粘合剂的蜡部分,并且在渗透步骤期间除去塑料。 所得的复合部件具有基本上填充有铝的空隙的TiB2骨架。 该方法对于制造具有复杂形状的轻型和强力部件特别有用,例如高尔夫球杆头,工具,切割工具,热管理产品,火箭发动机部件和自行车部件。 在另一个优选实施例中,高尔夫球杆头由三部分组成:用于头部主体的非烧结TiB2部件,用于头部打击表面的烧结TiB2部件,以及重钨部件,用于为 头。 在该实施例中,铝浸渍剂基本上填满所有三个部分的空隙,以形成具有最佳特性的高尔夫球杆头。
    • 10. 发明授权
    • Method of controlling infiltration of complex-shaped ceramic-metal composite articles and the products produced thereby
    • 控制复合陶瓷 - 金属复合制品渗透的方法及由此产生的产品
    • US06200526B1
    • 2001-03-13
    • US09297968
    • 1999-05-11
    • Richard T. FoxAleksander J. PyzikChan HanRobert T. Nilsson
    • Richard T. FoxAleksander J. PyzikChan HanRobert T. Nilsson
    • B22F326
    • G11B5/7315C04B41/5155C04B41/52C04B41/88C04B41/89C22C1/1036C22C2001/1021C22C2001/1057G11B5/8404
    • A process for preparing complex-shaped, ceramic-metal composite articles, comprising: (a) contacting a non-wettable powder that is non-wetting to a metal to be used for infiltration with a shaped ceramic body to form a layer of the non-wettable powder on one or more surfaces of the shaped ceramic body, wherein the shaped ceramic body has a region where there is no layer of the non-wettable powder, and (b) infiltration the shaped ceramic body with the metal through the region or regions where there is no layer of the non-wettable powder, such that a complex-shaped ceramic-metal composite comprising one or more metal phases and one or more ceramic phases is formed, wherein the article has substantially the net shape of the shaped ceramic body and undesirable regions of excess metal on the surface and undesirable phases within the complex-shaped ceramic-metal composite article near the surface are located only in the region or regions where there is no layer of the non-wettable powder. The process of the invention allows the preparation of complex-shaped ceramic-metal composite articles with undesirable regions of excess metal and undesirable phases on the surface(s), of, or within, the article only in the regions where there is, or was, no layer of non-wettable powder. The process of the invention allows the preparation of a complex-shaped ceramic-metal composite article which requires little or no machining of the surface(s) to achieve a finished article. A complex-shaped ceramic-metal composite article is prepared which contains few undesirable regions of excess metal and undesirable phases.
    • 一种制备复杂形状的陶瓷 - 金属复合制品的方法,包括:(a)将不湿润的非可润湿粉末与用于渗透的金属与成形陶瓷体接触以形成非 - 在成形陶瓷体的一个或多个表面上的可润湿粉末,其中成形陶瓷体具有不存在不可湿性粉末层的区域,(b)使成形陶瓷体与金属渗透穿过该区域或 没有不可湿粉末层的区域,使得形成包含一个或多个金属相和一个或多个陶瓷相的复合形状的陶瓷 - 金属复合材料,其中制品具有基本上成形陶瓷的净形状 表面上的多余金属的主体和不期望的区域以及表面附近的复合陶瓷 - 金属复合制品内的不期望的相位仅位于不具有不可湿性粉末层的区域或区域中。 本发明的方法允许制备复合形状的陶瓷 - 金属复合制品,其具有不需要的过量金属区域和不期望的相,仅在制品的表面上或内部存在, ,无层不可湿粉。 本发明的方法允许制备复杂形状的陶瓷 - 金属复合制品,其需要很少或不需要加工表面以实现最终制品。 制备复杂形状的陶瓷 - 金属复合制品,其包含少量不需要的过量金属和不期望的相的区域。