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    • 5. 发明申请
    • Production Of High-Pressure Gaseous Nitrogen
    • 高压气态氮的生产
    • US20130042647A1
    • 2013-02-21
    • US13212461
    • 2011-08-18
    • Paul Musicus
    • Paul Musicus
    • F25J3/08
    • F25J3/04212F25J3/0406F25J3/04218F25J3/04303F25J3/04351F25J3/04424F25J3/0486F25J2200/20F25J2200/54F25J2235/42F25J2245/42
    • The present invention is an improved process for producing elevated pressure nitrogen. This method includes providing an air separation unit with at least two columns, an LP column and an MP column, and cooling a compressed feed air stream in a heat exchanger, then expanding the resulting cooled feed air stream in an expander, thereby producing a quantity of work and a cooled inlet air stream, feeding the cooled inlet air stream into the LP column. Then extracting a nitrogen stream from the MP column, and warming a first portion of the nitrogen stream in the heat exchanger, thereby producing a product nitrogen stream. Then compressing a second portion of the nitrogen stream in a compressor, thereby producing medium pressure nitrogen stream, and introducing the medium pressure nitrogen stream into an LP column vaporizer. Then extracting a second nitrogen stream from the LP column, and cooling the second nitrogen stream in a condenser thereby producing a liquid nitrogen stream. Then introducing a first portion of the liquid nitrogen stream into the LP column, increasing the pressure of a second portion of the liquid nitrogen stream, thereby producing a pressurized liquid nitrogen stream, and introducing a first portion of the pressurized liquid nitrogen stream into the MP column, and export a second portion of the pressurized liquid nitrogen stream as product.
    • 本发明是用于生产高压氮的改进方法。 该方法包括提供具有至少两个柱的空气分离单元,LP塔和MP塔,并且在热交换器中冷却压缩的进料空气流,然后将所得到的冷却的进料空气流膨胀在膨胀机中,从而产生一定量 的工作和冷却的入口空气流,将冷却的入口空气流供给到LP塔中。 然后从MP柱中提取氮气流,并且在热交换器中加热氮气流的第一部分,从而产生产物氮气流。 然后压缩压缩机中氮气流的第二部分,从而产生中压氮气流,并将中压氮气流引入LP塔蒸发器。 然后从LP塔提取第二氮气流,并在冷凝器中冷却第二氮气流,从而产生液氮流。 然后将液氮流的第一部分引入LP塔中,增加液氮流的第二部分的压力,从而产生加压液氮流,并将第一部分加压液氮流引入MP 柱,并将加压液氮流的第二部分作为产物输出。
    • 7. 发明授权
    • Process for producing ultrapure nitrogen
    • 超纯氮生产工艺
    • US06276172B1
    • 2001-08-21
    • US09437263
    • 1999-11-10
    • Dietrich RottmanChristian Kunz
    • Dietrich RottmanChristian Kunz
    • F25J300
    • F25J3/04218F25J3/04084F25J3/04212F25J3/04284F25J3/04351F25J3/04454F25J3/04963F25J3/08F25J2200/04F25J2200/10F25J2200/50F25J2200/72F25J2210/42F25J2215/44F25J2220/42F25J2220/44F25J2235/42F25J2245/42F25J2250/20F25J2250/42F25J2270/42F25J2290/62Y10S62/92
    • For producing ultrapure nitrogen by low-temperature fractionation of air in a rectification system having at least one rectification column, compressed and purified feed air is conducted into a high pressure column, an oxygen-free pressurized nitrogen fraction is produced from the high pressure column, conducted into a low-pressure column and in the low-pressure column carbon-monoxide-free low-pressure nitrogen is produced as overhead gas. The oxygen-free pressurized nitrogen fraction (1) is either taken off in the liquid state from an upper region of the high pressure column or is provided from a liquid tank (22) containing stored oxygen-free nitrogen and the oxygen-free pressurized nitrogen fraction (1) is expanded into the bottom-heated low-pressure column (2). Ascending vapour in the lowpressure column (2) by mass transfer with and an ultrapure nitrogen reflux applied at the top of the low-pressure column (2) and is freed from carbon monoxide using ultrapure nitrogen, withdrawn as carbon-monoxide-free overhead gas (5) at the top of the low-pressure column (2). After a pressure increase the overhead (5), is partially liquefied, and the liquefied part (17, 18) is expanded into a bottom-heated He—Ne—H2 column (4) from which the ultrapure nitrogen (19) is withdrawn in the liquid state.
    • 为了在具有至少一个精馏塔的精馏系统中通过空气的低温分馏制备超纯氮,将压缩和纯化的进料空气进入高压塔,由高压塔产生无氧加压氮馏分, 进入低压塔,在低压塔中产生一氧化碳的低压氮作为塔顶气体。 无氧加压氮馏分(1)从高压塔的上部区域以液态取出,或者由含有储存无氧氮的液体罐(22)和无氧加压氮 馏分(1)膨胀到底部加热的低压塔(2)中。 在低压塔(2)的顶部通过传质和超纯氮回流在低压塔(2)中升高蒸气,并使用超纯氮从一氧化碳中除去一氧化碳,作为一氧化碳的塔顶气体 (5)在低压塔(2)的顶部。 在压力增加之后,顶部(5)部分液化,液化部分(17,18)膨胀成底部加热的He-Ne-H2柱(4),超纯氮(19)从该塔中取出 液态。
    • 10. 发明授权
    • Method and device for obtaining nitrogen by low-temperature separation
of air
    • 通过空气低温分离获得氮的方法和装置
    • US5964104A
    • 1999-10-12
    • US79236
    • 1998-05-15
    • Dietrich Rottmann
    • Dietrich Rottmann
    • F25J3/04F25J3/00
    • F25J3/04212F25J3/04309F25J3/04412F25J2200/20F25J2200/54F25J2235/42F25J2245/42F25J2250/42F25J2250/50
    • In the method and device, nitrogen is obtained by two-stage rectification of air in a double column. Double column contains a high-pressure column and a medium-pressure column that are in a heat-exchange relationship with each other. Entering air is compressed, purified, cooled in a main heat exchanger against separation products, and fed to rectification. At least one nitrogen product fraction is taken from high-pressure column. A nitrogen gas fraction from double column is heated, expanded, and brought into indirect heat exchange with an oxygen-enriched liquid from the lower region of medium-pressure column. In this way, the nitrogen gas fraction is at least partially condensed and the oxygen-enriched liquid is at least partially evaporated. The condensate formed in the indirect heat exchange is at least partially fed to medium-pressure column. The nitrogen gas fraction is heated upstream of expansion to an intermediate temperature that is between the temperatures at the cold end and the warm end of main heat exchanger.
    • 在该方法和装置中,氮气通过双塔中空气的两级精馏获得。 双柱包含彼此处于热交换关系的高压塔和中压塔。 进入空气被压缩,净化,在主热交换器中冷却分离产物,并进料进行精馏。 从高压塔取出至少一个氮气产物馏分。 来自双塔的氮气馏分被加热,膨胀,并与来自中压塔的下部区域的富氧液体进行间接热交换。 以这种方式,氮气部分至少部分冷凝,富氧液体至少部分蒸发。 在间接热交换中形成的冷凝物至少部分地供给中压塔。 将氮气馏分在膨胀的上游加热至在主热交换器的冷端和暖端之间的温度之间的中间温度。