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    • 4. 发明申请
    • Production Of High-Pressure Gaseous Nitrogen
    • 高压气态氮的生产
    • US20130000351A1
    • 2013-01-03
    • US13170572
    • 2011-06-28
    • Paul Musicus
    • Paul Musicus
    • F25J3/08
    • F25J3/04412F25J3/04309F25J2200/20F25J2200/54F25J2235/42F25J2245/42
    • An improved process for producing elevated pressure nitrogen including providing an air separation unit with at least two columns. The process includes extracting a first nitrogen stream from the MP column, warming a first portion of the first nitrogen stream in a heat exchanger, thereby producing a product nitrogen stream, and warming a second portion of the nitrogen stream in the heat exchanger, thereby producing warm nitrogen stream. Expanding the warm nitrogen stream in an expander, thereby producing a quantity of work, and a low pressure nitrogen stream and introducing the low pressure nitrogen stream into the LP column. Extracting a second nitrogen stream from the LP column, cooling the second nitrogen stream in condenser, thereby producing a liquid nitrogen stream. Introducing a first portion of the liquid nitrogen stream into the LP column, increasing the pressure of a second portion of the liquid nitrogen stream, thereby producing a pressurized liquid nitrogen stream, and introducing a first portion of the pressurized liquid nitrogen stream into the MP column, and export a second portion of the pressurized liquid nitrogen stream as product.
    • 一种用于产生高压氮气的改进方法,包括提供具有至少两个塔的空气分离单元。 该方法包括从MP柱提取第一氮气流,在热交换器中加热第一氮气流的第一部分,从而产生产物氮气流,并在热交换器中加热氮气流的第二部分,从而产生 暖氮流。 在膨胀机中膨胀温热的氮气流,从而产生一定量的工作和低压氮气流,并将低压氮气流引入LP塔。 从LP柱提取第二氮气流,冷却冷凝器中的第二氮气流,从而产生液氮流。 将液氮流的第一部分引入LP塔中,增加液氮流的第二部分的压力,从而产生加压液氮流,并将加压液氮流的第一部分引入MP柱 并且将作为产品的加压液氮流的第二部分输出。
    • 6. 发明申请
    • THERMAL INTEGRATION OF OXYGEN PLANTS
    • 氧化植物的热集成
    • US20090178408A1
    • 2009-07-16
    • US12171766
    • 2008-07-11
    • Jean-Renaud BrugerolleBao Ha
    • Jean-Renaud BrugerolleBao Ha
    • F01K13/00F23L7/00
    • F25J3/04181F01K7/40F25J3/04018F25J3/0406F25J3/04212F25J3/04303F25J3/04309F25J3/04448F25J3/04527F25J3/04533F25J3/04557F25J3/04581F25J3/04612F25J3/04618F25J2200/20F25J2200/50F25J2205/70F25J2230/06F25J2240/70F25J2245/42F25J2250/50Y02E20/344Y02P80/154
    • A process for the integration of a cryogenic air separation plant and an oxy-combustion power plant is presented. This process includes producing a pressurized nitrogen stream and a pressurized oxygen stream within said cryogenic air separation plant. This process also includes burning a fuel stream thereby generating a steam stream from a boiler feed water stream, wherein said stream is used for work expansion within said oxy-combustion power plant. This process also includes heating said pressurized nitrogen stream and said pressurized oxygen stream with a compressed air stream that is extracted from the air compressor of said cryogenic air separation plant, thereby forming a heated pressurized nitrogen stream and a heated pressurized oxygen stream. This process also includes burning a fuel stream with said heated pressurized oxygen stream to produce a flue gas stream. This process also includes heating said heated pressurized nitrogen stream to form a hot pressurized nitrogen stream. This process also includes work expanding said hot pressurized nitrogen stream to a lower pressure thereby forming a hot exhaust nitrogen stream and recovering energy. And this process also includes heating said boiler feed water stream by indirect heat exchange with said hot exhaust nitrogen stream.
    • 提出了一种低温空气分离装置和氧燃动力装置整合的方法。 该方法包括在所述低温空气分离装置内产生加压氮气流和加压氧气流。 该方法还包括燃烧燃料流,从而从锅炉给水流产生蒸汽流,其中所述流用于所述氧燃烧发电厂内的工作膨胀。 该方法还包括用从低温空气分离装置的空气压缩机中提取的压缩空气流来加热所述加压氮气流和所述加压氧气流,由此形成加热的加压氮气流和加热的加压氧气流。 该方法还包括用所述加热的加压氧气燃烧燃料流以产生烟道气流。 该方法还包括加热所述加热的加压氮气流以形成热的加压氮气流。 该方法还包括将所述热加压氮气流扩展到较低压力的工作,从而形成热排气氮气流并回收能量。 并且该方法还包括通过与所述热排气氮气流间接热交换来加热所述锅炉给水流。
    • 10. 发明申请
    • Process for the cryogenic distillation of air
    • 空气低温蒸馏的方法
    • US20060075779A1
    • 2006-04-13
    • US11246853
    • 2005-10-06
    • Paul Higginbotham
    • Paul Higginbotham
    • F25J3/00
    • F25J3/04303F25J3/04084F25J3/0409F25J3/04103F25J3/04212F25J3/0423F25J3/04236F25J3/04296F25J3/04442F25J2200/20F25J2200/50F25J2205/30F25J2235/42F25J2245/42
    • Pressurized gaseous nitrogen (“GAN”) is produced in a process in which liquid nitrogen (“LIN”) is produced in a cryogenic air separation unit (“ASU”). The pressure of at least a portion of the LIN is increased to produce pressurized LIN. A fluid having an oxygen concentration at least equal to that of air is separated in an auxiliary cryogenic distillation column to produce nitrogen-rich overhead vapor and oxygen-enriched bottoms liquid. Heat and optionally mass is transferred between at least a portion of the nitrogen-rich overhead vapor and at least a portion of the pressurized LIN to produce nitrogen-rich liquid and pressurized GAN. At least a portion of said nitrogen-rich liquid is used as reflux to the ASU after suitable pressure adjustment. Such a process allows the production of high purity GAN without the loss of oxygen recovery typically observed in conventional pumped LIN cycles.
    • 在低温空气分离装置(“ASU”)中产生液氮(“LIN”)的过程中产生加压气态氮(“GAN”)。 LIN的至少一部分的压力增加以产生加压的LIN。 在辅助低温蒸馏塔中分离具有至少等于空气的氧浓度的流体,以产生富氮塔顶蒸气和富氧底物液体。 热和任选的物质在富氮塔顶蒸气的至少一部分和加压的LIN的至少一部分之间转移以产生富氮液体和加压的GAN。 在适当的压力调节之后,将至少一部分富氮液体用作ASU的回流。 这种方法允许生产高纯度GAN,而不会在常规泵浦LIN循环中通常观察到氧气回收损失。