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    • 1. 发明申请
    • Process for purifying inorganic materials
    • 无机材料净化工艺
    • US20070092425A1
    • 2007-04-26
    • US10554987
    • 2003-12-19
    • Robert Lloyd
    • Robert Lloyd
    • C01B33/08
    • C01B9/08C01G23/0475C22B34/1213C22B34/1245
    • The invention relates to a process for purifying inorganic materials by treating the materials with a solution of hydrogen fluoride in aqueous hydrofluorosilicic acid. The process involves treating an inorganic material containing at least two species, to at least partially separate a first species contained in the material from a second species contained in the material, and comprises treating the material with a fluorine acid solution comprising aqueous hydrofluorosilicic acid and hydrofluoric acid (HF), such that the first species is converted to a product selected from the group consisting of a fluoride, a fluorosilicate and mixtures thereof, and such that the second species is at least partly unreacted, and separating the second species from the product.
    • 本发明涉及一种通过用氟化氢在氢氟硅酸水溶液中处理该材料来净化无机材料的方法。 该方法包括处理含有至少两种物质的无机材料,以至少部分地将包含在该材料中的第一物质与材料中所含的第二物质分离,并且包括用含氟氢氟酸和氢氟酸的氟酸溶液处理该物质 酸(HF),使得第一物质转化为选自氟化物,氟硅酸盐及其混合物的产物,并且使得第二物质至少部分未反应,并将第二物质与产物分离 。
    • 4. 发明授权
    • Process for removing thorium and recovering vanadium from titanium
chlorinator waste
    • 从钛氯化物废物中去除钍和回收钒的方法
    • US5494648A
    • 1996-02-27
    • US188863
    • 1994-01-31
    • Richard S. OlsenJohn T. Banks
    • Richard S. OlsenJohn T. Banks
    • C01F15/00C01G49/00C22B34/12C22B34/22C22B60/02
    • C01F15/00C01G49/0018C22B34/1213C22B34/22C22B60/02C01P2006/80
    • A process for removal of thorium from titanium chlorinator waste comprising: (a) leaching an anhydrous titanium chlorinator waste in water or dilute hydrochloric acid solution and filtering to separate insoluble minerals and coke fractions from soluble metal chlorides; (b) beneficiating the insoluble fractions from step (a) on shaking tables to recover recyclable or otherwise useful TiO.sub.2 minerals and coke; and (c) treating filtrate from step (a) with reagents to precipitate and remove thorium by filtration along with acid metals of Ti, Zr, Nb, and Ta by the addition of the filtrate (a), a base and a precipitant to a boiling slurry of reaction products (d); treating filtrate from step (c) with reagents to precipitate and recover an iron vanadate product by the addition of the filtrate (c), a base and an oxidizing agent to a boiling slurry of reaction products; and (e) treating filtrate from step (d) to remove any remaining cations except Na by addition of Na.sub.2 CO.sub.3 and boiling.
    • 一种从钛氯化物废料中除去钍的方法,包括:(a)将无水氯化钛废物浸入水或稀盐酸溶液中并过滤以从可溶性金属氯化物中分离出不溶性矿物和焦炭馏分; (b)从摇台上挑选步骤(a)中的不溶级分,以回收可回收或以其他方式使用的二氧化钛矿物和焦炭; 和(c)用试剂处理来自步骤(a)的滤液,通过加入滤液(a),碱和沉淀剂将其与Ti,Zr,Nb和Ta的酸性金属一起过滤沉淀并除去钍 沸腾的反应产物浆液(d); 用试剂处理来自步骤(c)的滤液,通过向反应产物的沸腾浆液中加入滤液(c),碱和氧化剂来沉淀并回收钒酸铁产物; 和(e)处理来自步骤(d)的滤液,通过加入Na 2 CO 3并煮沸除去Na外的任何剩余的阳离子。