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    • 5. 发明授权
    • Separation of nickel and cobalt and manganese in solution
    • 在溶液中分离镍和钴和锰
    • US3984520A
    • 1976-10-05
    • US445918
    • 1974-02-26
    • Paul H. CardwellJames A. Olander
    • Paul H. CardwellJames A. Olander
    • C22B3/30C22B3/32C22B3/36C22B47/00C01G3/04C01G45/06C01G51/08C01G53/08
    • C22B3/0037C22B3/0017C22B3/0027C22B47/0081Y02P10/234Y10S423/04
    • This invention provides a process for separating the halide of cobalt, and optionally nickel, from a pregnant aqueous solution, the aqueous solution also containing a manganese halide. The process comprises initially extracting the cobalt halide and a portion of any manganese halide which is present into an organic extract. The nickel halide is then separately extracted from the solution. The manganese halide is preliminarily preferentially stripped from the organic extract containing cobalt and manganese utilizing an aqueous solution comprising halide ions. The cobalt halide in the extract can then be stripped into an aqueous solution together with the remaining manganese to form a strip solution. The manganese is then preferentially extracted from the strip solution, leaving a manganese-free, substantially pure cobalt solution. Any nickel can be selectively extracted from the manganese remaining in the pregnant solution.
    • 本发明提供了一种从怀孕水溶液中分离钴和任选的镍的卤化物的方法,该水溶液也含有卤化锰。 该方法包括首先提取卤化钴和存在于有机提取物中的部分任何卤化锰。 然后从溶液中分别提取卤化镍。 使用包含卤离子的水溶液,预先从含有钴和锰的有机提取物中剥离卤化锰。 然后将提取物中的卤化钴与剩余的锰一起汽提成水溶液形成条状溶液。 然后优先从带状溶液中提取锰,留下无锰的,基本上纯的钴溶液。 任何镍可以从残留在怀孕溶液中的锰中选择性提取。