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1. 发明公开

US20240352355A1 FUEL COMPOSITIONS FROM LIGHT TIGHT OILS AND HIGH SULFUR FUEL OILS 审中-公开
公开(公告)号：US20240352355A1
公开(公告)日：2024-10-24
申请号：US18759862
申请日：2024-06-29
申请人： MAWETAL LLC
发明人： Mohammed Wohaibi , Tom F. Pruitt
IPC分类号： C10G67/04 , C10C3/00 , C10G63/06 , C10G65/02 , C10J3/84 , C10L1/04 , F04D13/08 , F04D29/046 , F04D29/60
CPC分类号： C10G67/0463 , C10C3/002 , C10G63/06 , C10G65/02 , C10G67/0454 , C10J3/84 , C10L1/04 , F04D13/086 , F04D29/0462 , F04D29/606 , C10G2300/202 , C10J2300/165 , C10J2300/1675 , C10J2300/1807 , C10L2200/0407 , C10L2200/0438 , C10L2270/02 , C10L2270/026 , C10L2270/04 , C10L2270/08 , C10L2290/06 , C10L2290/10 , C10L2290/543 , C10L2290/544 , F05B2240/52
摘要： Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

2. 发明授权

US11649408B2 Fuel compositions from light tight oils and high sulfur fuel oils 有权
公开(公告)号：US11649408B2
公开(公告)日：2023-05-16
申请号：US17494588
申请日：2021-10-05
申请人： MAWETAL LLC
发明人： Mohammed Wohaibi , Tom F. Pruitt
IPC分类号： C10G67/04 , C10G63/06 , C10L1/04 , C10G65/02 , F04D13/08 , F04D29/046 , F04D29/60 , C10C3/00 , C10J3/84
CPC分类号： C10G67/0463 , C10C3/002 , C10G63/06 , C10G65/02 , C10G67/0454 , C10J3/84 , C10L1/04 , F04D13/086 , F04D29/0462 , F04D29/606 , C10G2300/202 , C10J2300/165 , C10J2300/1675 , C10J2300/1807 , C10L2200/0407 , C10L2200/0438 , C10L2270/02 , C10L2270/026 , C10L2270/04 , C10L2270/08 , C10L2290/06 , C10L2290/10 , C10L2290/543 , C10L2290/544 , F05B2240/52
摘要： Methods are provided to prepare a low sulfur fuel from hydrocarbon sources, such as light tight oil and high sulfur fuel oil, often less desired by conventional refiners, who split crude into a wide range of differing products and may prefer presence of wide ranges (C3 or C5 to C20 or higher) of hydrocarbons. These fuels can be produced by separating feeds into untreated and treated streams, and then recombining them. Such fuels can also be formulated by combinations of light, middle and heavy range constituents in a selected manner as claimed. Not only low in sulfur, the fuels of this invention are also low in nitrogen and essentially metals free. Fuel use applications include on-board large marine transport vessels but also on-shore for large land based combustion gas turbines, boilers, fired heaters and transport vehicles and trains.

3. 发明申请

US20180148651A1 INTEGRATED PROCESS FOR PRODUCING ANODE GRADE COKE 审中-公开
公开(公告)号：US20180148651A1
公开(公告)日：2018-05-31
申请号：US15877878
申请日：2018-01-23
申请人： SAUDI ARABIAN OIL COMPANY
发明人： Omer Refa KOSEOGLU
IPC分类号： C10B57/04 , C10G67/04 , C10G67/06 , C10G49/00 , C10G47/20 , C10G45/02 , C10G25/00 , C10G9/00 , C10B55/00 , C10J3/00 , C10G67/14 , C10G21/00
CPC分类号： C10B57/045 , C10B55/00 , C10G9/005 , C10G21/003 , C10G25/00 , C10G45/02 , C10G47/20 , C10G49/007 , C10G67/0463 , C10G67/049 , C10G67/06 , C10G67/14 , C10G2300/1033 , C10G2300/1055 , C10G2300/202 , C10J3/00 , Y02P20/125
摘要： The invention relates to processes for producing anode grade coke from whole crude oil. The invention is accomplished by first deasphalting a feedstock, followed by processing resulting DAO and asphalt fractions. The DAO fraction is hydrotreated or hydrocracked, resulting in removal of sulfur and hydrocarbons, which boil at temperatures over 370° C., and gasifying the asphalt portion in one embodiment. This embodiment includes subjecting hydrotreated and/or unconverted DAO fractions to delayed coking. In an alternate embodiment, rather than gasifying the asphalt portion, it is subjected to delayed coking in a separate reaction chamber. Any coke produced via delayed coking can be gasified.

4. 发明授权

US09963643B2 Process for refining a heavy hydrocarbon feed using a selective deasphalting step 有权
公开(公告)号：US09963643B2
公开(公告)日：2018-05-08
申请号：US14652813
申请日：2013-12-03
申请人： IFP Energies nouvelles
发明人： Isabelle Merdrignac , Jerome Majcher , Mathieu Digne
IPC分类号： C10G67/04 , C10G21/14 , C10G67/14 , C10G69/04 , C10G21/00 , C10G21/06
CPC分类号： C10G21/14 , C10G21/003 , C10G21/06 , C10G67/0463 , C10G67/14 , C10G69/04 , C10G2300/44
摘要： The invention concerns a process for refining a heavy hydrocarbon feed, comprising the following steps:a) a step for selective deasphalting of the heavy hydrocarbon feed by single-step liquid/liquid extraction in an extraction medium, said extraction being carried out using a mixture of at least one polar solvent and at least one apolar solvent, in order to obtain an asphalt phase and a deasphalted oil phase DAO, the proportions of said polar solvent and said apolar solvent in the solvent mixture being adjusted as a function of the properties of the feed and the desired asphalt yield, said deasphalting step being carried out under subcritical conditions for the solvent mixture; b) a step for hydrotreatment of at least a portion of the deasphalted oil phase DAO obtained from step a); c) optionally, a step for catalytic cracking of at least a portion of the effluent obtained from step b).

5. 发明申请

US20150337223A1 PROCESS FOR REFINING A HEAVY HYDROCARBON FEED USING A SELECTIVE DEASPHALTING STEP 有权
标题翻译：使用选择性去除步骤精炼重油加料的方法
公开(公告)号：US20150337223A1
公开(公告)日：2015-11-26
申请号：US14652813
申请日：2013-12-03
申请人： IFP ENERGIES NOUVELLES
发明人： Isabelle MERDRIGNAC , Jerome MAJCHER , Mathieu DIGNE
IPC分类号： C10G69/04 , C10G67/04
CPC分类号： C10G21/14 , C10G21/003 , C10G21/06 , C10G67/0463 , C10G67/14 , C10G69/04 , C10G2300/44
摘要： The invention concerns a process for refining a heavy hydrocarbon feed, comprising the following steps: a) a step for selective deasphalting of the heavy hydrocarbon feed by single-step liquid/liquid extraction in an extraction medium, said extraction being carried out using a mixture of at least one polar solvent and at least one apolar solvent, in order to obtain an asphalt phase and a deasphalted oil phase DAO, the proportions of said polar solvent and said apolar solvent in the solvent mixture being adjusted as a function of the properties of the feed and the desired asphalt yield, said deasphalting step being carried out under subcritical conditions for the solvent mixture; b) a step for hydrotreatment of at least a portion of the deasphalted oil phase DAO obtained from step a); c) optionally, a step for catalytic cracking of at least a portion of the effluent obtained from step b).
摘要翻译：本发明涉及一种用于精制重烃进料的方法，包括以下步骤：a）通过在萃取介质中单步液/液萃取来选择性脱沥青重质烃进料的步骤，所述萃取使用混合物的至少一种极性溶剂和至少一种非极性溶剂，为了获得沥青相和脱沥青油相DAO，所述极性溶剂和所述非极性溶剂在溶剂混合物中的比例作为所述进料和所需的沥青产量，所述脱沥青步骤在所述溶剂混合物的亚临界条件下进行; b）用于加氢处理从步骤a）得到的脱沥青油相DAO的至少一部分的步骤; c）任选地，用于对从步骤b）获得的至少一部分流出物进行催化裂化的步骤。

6. 发明授权

US08911613B2 Method of simultaneously manufacturing high quality naphthenic base oil and heavy base oil 有权
标题翻译：同时制造优质环烷基油和重基油的方法
公开(公告)号：US08911613B2
公开(公告)日：2014-12-16
申请号：US13695897
申请日：2010-11-02
申请人： Kyung Seok Noh , Jae Wook Ryu , Do Hyoun Kim , Gyung Rok Kim , Seung Woo Lee , Do Woan Kim , Sun Choi , Seung Hoon Oh , Byung Won Yoon , Bum Suk Chun
发明人： Kyung Seok Noh , Jae Wook Ryu , Do Hyoun Kim , Gyung Rok Kim , Seung Woo Lee , Do Woan Kim , Sun Choi , Seung Hoon Oh , Byung Won Yoon , Bum Suk Chun
IPC分类号： C10G55/06 , C10G67/04 , C10G69/04 , C10M101/02 , C10G55/08
CPC分类号： C10M101/02 , C10G55/08 , C10G65/043 , C10G67/0463 , C10G69/04 , C10G2300/107 , C10G2300/1077 , C10G2300/302 , C10G2300/4018 , C10G2400/10 , C10M2203/02 , C10M2203/1065 , C10M2203/1085 , C10N2230/02
摘要： Disclosed is a method of simultaneously manufacturing high quality naphthenic base oil and heavy base oil using a single catalyst system, by subjecting an oil fraction (slurry oil or light cycle oil) produced by fluid catalytic cracking and an oil fraction (deasphalted oil) produced by solvent deasphalting to hydrotreating, catalytic dewaxing and hydrofinishing of the single catalyst system, thereby obtaining not only products having low viscosity but also heavy base oil products (150BS) having high viscosity which was impossible to obtain using a conventional catalytic reaction process, and also thereby producing base oil products having different properties using the single catalyst system, thus generating economic benefits and exhibiting superior efficiency.
摘要翻译：本发明公开了一种使用单一催化剂体系同时制造高品质环烷基油和重质基油的方法，该方法是使通过流化催化裂化生产的油馏分（浆料油或轻质循环油）和通过流化催化裂化产生的油馏分（脱沥青油）溶剂脱沥青加氢处理，催化脱蜡和单一催化剂体系的加氢精制处理，从而不仅得到具有低粘度的产品，而且获得了使用常规催化反应方法不可能获得的具有高粘度的重基油产品（150BS）使用单一催化剂体系生产具有不同性能的基础油产品，从而产生经济效益并表现出优异的效率。

7. 发明授权

US08758600B2 Ionic liquid desulfurization process incorporated in a low pressure separator 有权
标题翻译：离子液体脱硫工艺结合在低压分离器中
公开(公告)号：US08758600B2
公开(公告)日：2014-06-24
申请号：US13071236
申请日：2011-03-24
申请人： Omer Refa Koseoglu , Adnan Al-Hajji
发明人： Omer Refa Koseoglu , Adnan Al-Hajji
IPC分类号： C10G17/00
CPC分类号： C10G45/00 , C10G21/08 , C10G21/28 , C10G67/0463 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/301 , C10G2300/44 , C10G2300/805 , C10G2400/04
摘要： Initial high sulfur levels of a hydrocarbon feedstock are reduced to desired low levels without the need for integration of substantial new equipment or hardware with existing hydroprocessing reactors. Ionic liquids are utilized as organic sulfur extraction agents and are added to and mixed with the hydrocarbon feedstock containing organosulfur compounds in, or upstream of, an existing cold separator vessel. The ionic liquid and hydrocarbon mixture is maintained in contact under conditions which promote the formation of ionic sulfur-containing derivatives that are soluble in the ionic liquid to be formed, thereby enabling extractive removal and separation of the organosulfur compounds from the feedstock.
摘要翻译：烃原料的初始高硫含量降低到所需的低水平，而不需要将大量新设备或硬件与现有的加氢处理反应器集成。离子液体用作有机硫提取剂，并且与现有冷分离器容器中或上游的含有有机硫化合物的烃原料相加并混合。离子液体和烃混合物在促进形成可溶于要形成的离子液体的离子含硫衍生物的条件下保持接触，从而能够从原料中萃取除去和分离有机硫化合物。

8. 发明申请

US20130319910A1 INTEGRATED PROCESS FOR DEASPHALTING AND DESULFURIZING WHOLE CRUDE OIL 审中-公开
标题翻译：用于去除和去除全部原油的综合方法
公开(公告)号：US20130319910A1
公开(公告)日：2013-12-05
申请号：US13904545
申请日：2013-05-29
申请人： JGC CATALYSTS AND CHEMICALS LTD. , SAUDI ARARIAN OIL COMPANY
发明人： Omer Refa KOSEOGLU , Masaru Ushio , Koji Nakano
IPC分类号： C10G67/04
CPC分类号： C10G67/0463 , C10G47/20 , C10G67/049 , C10G2300/201 , C10J3/00 , C10J2300/0946 , Y02P20/125 , Y02P20/52
摘要： The invention relates to processes for removing impurities, such as asphalt, from whole crude oil. The invention is accomplished by first deasphalting a feedstock, followed by processing resulting DAO and asphalt fractions. The DAO fraction is hydrocracked, resulting in removal of sulfur and hydrocarbons which boil at temperatures over 370° C., and gasifying the asphalt portion.
摘要翻译：本发明涉及从整个原油中除去诸如沥青的杂质的方法。本发明通过首先将原料脱沥青，然后加工得到的DAO和沥青馏分来实现。 DAO馏分被加氢裂化，导致除去在370℃以上的温度下沸腾的硫和烃，并使沥青部分气化。

9. 发明申请

US20130197284A1 INTEGRATED HYDROTREATING, SOLVENT DEASPHALTING AND STEAM PYROLYSIS PROCESS FOR DIRECT PROCESSING OF A CRUDE OIL 审中-公开
标题翻译：一体化加氢处理，溶剂脱硫和蒸汽热解法直接加工原油
公开(公告)号：US20130197284A1
公开(公告)日：2013-08-01
申请号：US13751646
申请日：2013-01-28
申请人： Abdennour BOURANE , Raheel SHAFI , Essam SAYED , Ibrahim A. ABBA , Abdul Rahman Zafer AKHRAS
发明人： Abdennour BOURANE , Raheel SHAFI , Essam SAYED , Ibrahim A. ABBA , Abdul Rahman Zafer AKHRAS
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , B01D17/0217 , B01D19/0057 , B01D53/526 , B01D2256/16 , B01D2257/7025 , C10G9/36 , C10G19/00 , C10G21/003 , C10G55/04 , C10G67/0463 , C10G2400/20 , C10G2400/30 , Y02C20/20
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a hydrotreating zone and a solvent deasphalting zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated hydrotreating, solvent deasphalting and steam pyrolysis process comprises charging the crude oil to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; charging the hydroprocessed effluent to a solvent deasphalting zone with an effective amount of solvent to produce a deasphalted and demetalized oil stream and a bottom asphalt phase; thermally cracking the deasphalted and demetalized oil stream in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream.
摘要翻译：提供了一种方法，其涉及与加氢处理区和溶剂脱沥青区一体化的蒸汽热解区，以允许直接处理原油原料以生产包括烯烃和芳族化合物的石油化学品。综合的加氢处理，溶剂脱沥青和蒸汽热解过程包括将原油装入加氢处理区，该加氢处理区在有效产生具有降低的污染物含量，降低的污染物含量，降低的矿物相关指数局和减少的矿物相关指数减少的加氢处理流出物的条件下操作美国石油学院重力; 将加氢处理的流出物用有效量的溶剂装入溶剂脱沥青区，以产生脱沥青和脱金属的油料流和底部沥青相; 在蒸汽存在下对脱沥青和脱金属精油流进行热裂解以产生混合产物流; 分离混合产物流; 净化从混合产物流中回收的氢并将其再循环到加氢处理区; 从分离的混合产物流中回收烯烃和芳族化合物; 并从分离的混合产物流中回收热解燃料油。

10. 发明申请

US20130105359A1 METHOD FOR PREPARING LUBRICATING BASE OILS BY USING VACUUM DISTILLED DEASPHALTED OIL 有权
标题翻译：通过使用真空蒸馏去除油来制备润滑基油的方法
公开(公告)号：US20130105359A1
公开(公告)日：2013-05-02
申请号：US13701528
申请日：2011-06-03
申请人： Kyung Seok Noh , Jae Wook Ryu , Do Hyoun Kim , Gyung Rok Kim , Seung Woo Lee , Do Woan Kim , Sun Choi , Seung Hoon Oh , Byung Won Yoon , Bum Suk Chun
发明人： Kyung Seok Noh , Jae Wook Ryu , Do Hyoun Kim , Gyung Rok Kim , Seung Woo Lee , Do Woan Kim , Sun Choi , Seung Hoon Oh , Byung Won Yoon , Bum Suk Chun
IPC分类号： C10G67/04 , C10G67/02
CPC分类号： C10G67/0454 , B01J27/045 , B01J27/049 , B01J27/051 , B01J29/12 , B01J29/22 , B01J29/44 , B01J29/7084 , B01J29/7415 , B01J29/7461 , B01J29/7484 , B01J29/7492 , B01J29/85 , B01J35/0006 , B01J35/0093 , C10G45/58 , C10G59/06 , C10G65/043 , C10G67/02 , C10G67/0463 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/206 , C10G2300/302 , C10G2300/4018 , C10G2400/10 , C10M101/02 , C10M177/00 , C10M2203/1006 , C10N2270/00
摘要： The present invention relates to a method for preparing lubricating base oils by using vacuum distilled deasphalted oil, and more specifically, to a method for preparing various kinds of lubricating base oils by distilling a distillate obtained from a solvent deasphalting (SDA) process under reduced pressure to obtain heavy deasphalted oil (H-DAO) and light deasphalted (Lt-DAO) and then treating the H-DAO and the Lt-DAO by catalytic reactions, respectively. According to the present invention, it is possible to obtain heavy lubricating base oil (150BS) of a high viscosity grade which can not be obtained by a known catalytic reaction and a lubricating base oil of group III by hydrogenation, in a high yield, and thus economical efficiency is excellent.
摘要翻译：本发明涉及一种使用真空蒸馏的脱沥青油制备润滑基础油的方法，更具体地说，涉及通过在减压下蒸馏由溶剂脱沥青（SDA）方法获得的馏出物制备各种润滑基础油的方法得到重质脱沥青油（H-DAO）和轻质脱沥青（Lt-DAO），然后分别通过催化反应处理H-DAO和Lt-DAO。根据本发明，可以通过氢化得到高粘度等级的重质润滑基础油（150BS），其通过已知的催化反应和润滑基础油以高收率得到，并且从而经济效益极佳。

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