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    • 3. 发明授权
    • Method for producing non-carcinogenic aromatic process oil
    • 生产非致癌芳香工艺油的方法
    • US09567532B2
    • 2017-02-14
    • US14427798
    • 2012-10-09
    • Victor Alekseevich TsebulaevNikolay Vladimirovich KhodovAndrey Fedorovich KuimovArkadiy Benyuminovich RadbilTaras Ivanovich DolinskiyOleg Anatolyevich Mazurin
    • Victor Alekseevich TsebulaevNikolay Vladimirovich KhodovAndrey Fedorovich KuimovArkadiy Benyuminovich RadbilTaras Ivanovich DolinskiyOleg Anatolyevich Mazurin
    • C10G21/12C10G21/20C10G21/22C10G29/28C10G21/16C10G21/28C10G21/02C10G29/20C10G21/00B01D11/00B01D11/04C10C3/08
    • C10G29/28C10G21/02C10G21/16C10G21/20C10G21/22C10G21/28C10G29/20
    • The present invention relates to the chemical or petroleum-processing industry and can be used in the production of petroleum plasticizers for synthetic rubber and tyres. In the method for producing non-carcinogenic aromatic process oil, containing a PCA extract of less than 3.0% according to the IP-346 method, said method comprising purifying the oil fractions of petroleum with selective solvents and separating the extract, additionally processing the extract with a polar solvent and producing a raffinate as the end product, the polar solvent used is a mixture of dimethylsulphoxide and Nmethylpyrrolidone, which is used for preliminary processing of the extract, wherein, after the preliminary processing, the mixture of extract and polar solvent is filtered, divided and the light phase is sent to the additional processing of the extract with the polar solvent, and the heavy phase is sent to a polar solvent regeneration stage. The ratio of dimethylsulphoxide to N-methylpyrrolidone in the mixture is within the range of 1:0.1-0.5. The ratio of polar solvent to extract in the additional processing stage is within the range of 1.5-2.5:1. The ratio of polar solvent to extract in the preliminary processing stage is within the range of 0.1-0.3:1. The technical result consists in increasing the efficiency of the process by preventing the formation of an intermediate layer in the extractor column, by reducing the ratio of solvent:extract, and, as a consequence, by increasing the productivity of the plant, simplifying the process of drying the solvent, and eliminating a paraffin-naphthene solvent, which substantially simplifies the regeneration of extractant from the raffinate solution.
    • 本发明涉及化学或石油加工工业,可用于生产用于合成橡胶和轮胎的石油增塑剂。 在根据IP-346方法含有小于3.0%的PCA提取物的非致癌芳香工艺油的制造方法中,所述方法包括用选择性溶剂纯化石油馏分并分离提取物,另外处理提取物 使用极性溶剂并制备萃余液作为最终产物,所用极性溶剂是二甲基亚砜和N-甲基吡咯烷酮的混合物,用于提取物的预处理,其中在预处理之后,提取物和极性溶剂的混合物为 过滤分离,将轻相送入极性溶剂对萃取液的附加处理,并将重相送入极性溶剂再生阶段。 混合物中二甲基亚砜与N-甲基吡咯烷酮的比例在1:0.1-0.5的范围内。 极性溶剂与萃取剂在附加处理阶段的比例在1.5-2.5:1的范围内。 预处理阶段极性溶剂与提取物的比例在0.1-0.3:1的范围内。 技术结果在于通过减少萃取塔中的中间层的形成来提高该方法的效率,通过降低溶剂萃取物的比例,因此通过提高装置的生产率,简化了方法 干燥溶剂,除去石蜡 - 环烷烃溶剂,这大大简化了萃余液从萃余液中的再生。