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    • 5. 发明授权
    • Mixed phases of sphene structure
    • SPHENE结构混合相
    • US3753754A
    • 1973-08-21
    • US3753754D
    • 1971-07-27
    • BAYER AG
    • HUND F
    • C01B33/20C09C1/00C09C1/04C09C1/22C09C1/28C09C1/34C09C1/36C09C1/40C09C
    • C09C1/405C01B33/20C01P2002/72C01P2002/77C01P2006/32C09C1/00C09C1/0009C09C1/04C09C1/046C09C1/22C09C1/28C09C1/34C09C1/36C09C1/40
    • Synthetic mixed phases of sphene structure corresponding to the general formula MMeZX5 or MMeZX4Y and comprising as host components pure or isotype mixed phases in which M calcium and/or barium, Me titanium and/or tin, Z silicon, X oxygen and Y fluorine and/or hydroxyl, comprising at least about 0.1 percent by weight of at least one guest component in place of the aforementioned host components without any change in the sphene structure or in the electroneutrality, the guest component for Z being a di-valent to pentavalent cation with an ionic radius of less than about 0.6 A. and/or a zinc cation, for Me being a monoto hexavalent cation with a radius of from about 0.45 A. to about 1.0 A. and for M being a mono-to tetra-valent cation with a radius of greater than about 0.9 A., the stoichiometric quantities for (Me+M):Z:(X+Y) being about 2:1:5.
    • 对应于通式MMeZX5或MMeZX4Y并且包含作为主体组分的纯化或同种型混合相的合成混合相,其中M =钙和/或钡,Me =钛和/或锡,Z =硅,X =氧和 Y =氟和/或羟基,包含至少约0.1重量%的至少一种客体组分代替上述主体组分而没有任何改变的sphene结构或电中性,Z的客体组分是二 - 离子半径小于约0.6A的五价阳离子和/或锌阳离子,对于Me,其半径为约0.45A至约1.0A的单价至六价阳离子,并且对于M为 (Me + M):Z:(X + Y)的化学计量量为约2:1:5的一价至四价阳离子。
    • 7. 发明授权
    • CaZn.sub.2 (PO.sub.4).sub.2 .2H.sub.2 O anticorrosion pigment
    • CaZn {hd 2 {b(PO {HD 4 {B){HD 2 {B.2H {HD 2 {B O防腐颜料
    • US4153465A
    • 1979-05-08
    • US855482
    • 1977-11-28
    • Franz HundPeter Kresse
    • Franz HundPeter Kresse
    • C09C1/00C01B25/45C09C1/04C09D5/08
    • C01B25/45C09C1/046C09D5/084C01P2002/30C01P2006/12
    • An anticorrosion pigment suited for paints and lacquers and consisting of CaZn.sub.2 (PO.sub.4).sub.2 . 2H.sub.2 O crystallizing in the Scholzite lattice and having a specific surface according to BET of from 0.1 to 50 m.sup.2 /g is produced by a process wherein(a) (i) a salt solution containing calcium and zinc cations in a ratio of about 1:2 is normally, inversely or simultaneously precipitated in air at temperatures of up to about 100.degree. C. with an equivalent or substantially equivalent quantity of a solution containing an alkali metal or ammonium phosphate ion; or (ii) compounds of calcium and zinc, which can be decomposed with relatively strong acids or neutralized with acids, in a ratio of about 1:2, have phosphoric acid or ammonium phosphate added to them in approximately the quantity which is required for decomposition or neutralization, or in a slight excess of that quantity, at temperatures of up to about 100.degree. C.; and(b) the suspension obtained in accordance with (a) (i) or (ii) is heated in air to a temperature of up to about 100.degree. C. or in an autoclave to a temperature of up to about 175.degree. C. over a period of up to about 10 hours, e.g. about 1 to 8 hours, the pigment suspension obtained is washed, filtered off and dried.
    • 一种适用于油漆和漆的防腐颜料,由CaZn2(PO4)2组成。 通过其中(A)(I)含有约1:2比例的钙和锌溶液的盐溶液的方法制备了在Scholzite晶格中结晶并具有0.1至50m 2 / g的BET比表面积的2H 2 O 2 在相当于或基本上相当量的含有碱金属或磷酸铵离子的溶液的情况下,正常地,相反地或同时地在空气中降解高达约100℃的温度。 或(ii)钙和锌的化合物,其可用相对较强的酸分解或用酸中和,以约1:2的比例分解,其中添加了大约为分解所需量的磷酸或磷酸铵 或中和,或略高于该量,在高达约100℃的温度下