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    • 3. 发明申请
    • Method for the production of polymer foams based on reactive polycondensation resins
    • 基于活性缩聚树脂生产聚合物泡沫的方法
    • US20070197744A1
    • 2007-08-23
    • US10593419
    • 2005-03-17
    • Volker SchadlerDaniel SchmidtAxel Weiss
    • Volker SchadlerDaniel SchmidtAxel Weiss
    • C08F2/00
    • C08J9/28C08J2201/0504C08J2361/00
    • Process for producing polymer foams derived from reactive polycondensation resins and having a maximum pore diameter of 1 μm, which comprises: 1) preparing a gelable mixture of the reactive polycondensation resin in a solvent or dispersion medium, 2) preparing an aqueous dispersion comprising polymer particles, 3) mixing the mixture from step 1) with the dispersion from step 2) to give a water-containing gel, and 4) drying the water-containing gel to give the polymer foam, with drying in step 4) being carried out at a pressure and a temperature which are below the critical pressure and below the critical temperature of the liquid phase of the gel and the gel not being brought into contact with an organic liquid to replace the water present in the gel by this liquid after step 3) and before step 4).
    • 用于生产由反应性缩聚树脂衍生的并具有最大孔径为1μm的聚合物泡沫的方法,其包括:1)在溶剂或分散介质中制备反应性缩聚树脂的可凝胶混合物,2)制备包含聚合物颗粒 ,3)将来自步骤1)的混合物与来自步骤2)的分散体混合,得到含水凝胶,4)干燥含水凝胶得到聚合物泡沫体,在步骤4)中干燥,在 压力和温度低于临界压力并且低于凝胶的液相的临界温度,并且凝胶不与有机液体接触以在步骤3之后用该液体代替凝胶中存在的水) 并在步骤4之前)。
    • 6. 发明授权
    • Method for impregnating a heated, flat, fibrous substrate with synthetic
resin
    • 用合成树脂浸渍加热的,扁平的纤维基材的方法
    • US5436031A
    • 1995-07-25
    • US167859
    • 1993-12-23
    • Helmut Payer
    • Helmut Payer
    • B29B13/02B29B15/12B29C70/50C08J5/24B05D1/18B05C1/12B05C3/152B05D1/28
    • B29B13/023B29B15/125B29C70/504C08J5/24C08J2361/00
    • A method for impregnating a flat, fibrous substrate penetrated by a low viscosity, fluid synthetic resin, the substrate web 1 being preheated by known device 2 and thereupon being made to pass over a friction roller 3 which is heated where called for and which is uniformly wetted at its surface 6 with the low viscosity, aqueous synthetic resin solution based on an aminoplastic resin, substantially a melamine resin 5 or based on a phenolformaldehyde resin 5' present in a bath, the low viscosity, aqueous synthetic resin solution being uniformly heated and at least part of it penetrating the surface of the substrate web 1, whereupon the substrate web 1 loaded with synthetic resin is fully impregnated in the bath 4. Next this substrate web soaked with synthetic resin is made to pass through a metering device 7 and a drying channel 8 wherein the solvents of the aqueous, synthetic resin solution absorbed by the substrate are extensively evaporated in a flow of hot air and thereupon this substrate is cut to size in cutting device 9 into flat pieces 10 and is stacked in stacking device 11. The composites 10 are suitable to manufacture decorative cover layers, industrial insulating materials and core-layers of decorative molded laminates.
    • PCT No.PCT / AT92 / 00080 Sec。 371日期:1993年12月23日 102(e)日期1993年12月23日PCT提交1992年6月24日PCT公布。 出版物WO93 / 00209 日本1993年1月7日。一种用于浸渍由低粘度流体合成树脂浸透的平坦的纤维基材的方法,所述基材卷材1由已知的装置2预热,然后使其通过加热的摩擦辊3 在其表面6上以基于氨基塑料树脂,基本上三聚氰胺树脂5或基于存在于浴中的酚醛树脂5'的低粘度水性合成树脂溶液均匀地润湿,低粘度的水性 合成树脂溶液被均匀加热,其至少一部分渗透到基材卷材1的表面,由此将装有合成树脂的基材卷材1完全浸渍在槽4中。接下来,使用合成树脂浸渍的该基材卷通过 通过计量装置7和干燥通道8,其中由基材吸收的水性合成树脂溶液的溶剂在热空气和t的流中被广泛蒸发 因此,将该基板在切割装置9中切割成平板10,并且堆叠在堆叠装置11中。复合材料10适于制造装饰覆盖层,工业绝缘材料和装饰成型层压体的核心层。
    • 7. 发明授权
    • Polystyrylpyridine resins having an increased toughness, and composite
materials comprising these resins
    • 具有增加的韧性的聚苯乙烯基吡啶树脂和包含这些树脂的复合材料
    • US4540770A
    • 1985-09-10
    • US643651
    • 1984-08-23
    • Sammy Chevallier
    • Sammy Chevallier
    • C08L61/00C08G16/00C08G16/02C08J5/24C08L61/34C08G12/02
    • C08J5/24C08G16/0268C08J2361/00
    • The present invention relates to polystyrylpyridine-type resins having increased toughness, and composite materials containing these resins.The resin of the invention contains a polycondensation product of at least two reactive methylated substituents, the said resin having the following general formula (I): U.sub.x V.sub.y W.sub.z in which: ##STR1## U denotes the grouping ##STR2## V denotes the grouping ##STR3## W denotes the grouping in which:R, R.sub.1 are identical or different and denote a chain segment consisting of hydrocarbon radicals and able to contain hetero atoms,A, A.sub.1 are identical or different and denote an atom or group forming a bridge between the segment R and an aromatic nucleus of the styrylpyridine chain, containing stereomobile bonds,R.sub.2 denotes hydrogen, or a methyl or ethyl radical, x, y, z denote integers that may be equal to 0, the sum y+z being at least equal to 1.Advantageously, A, A.sub.1 denotes an oxygen atom. The resins of the invention have better mechanical properties than conventional polystyrylpyridine (PSP) resins, particularly at ambient temperature, yet preserve the excellent thermostability and moisture resistance properties characteristic of PSP resins. This resin may be used as matrix in a laminate.
    • 本发明涉及韧性提高的聚苯乙烯基吡啶型树脂,以及包含这些树脂的复合材料。 本发明的树脂含有至少两个反应性甲基化取代基的缩聚产物,所述树脂具有以下通式(I):Ux Vy Wz,其中:U表示分组 V表示分组, 图像W表示其中:R,R 1相同或不同并且表示由烃基组成并能够含有杂原子的链段的分组,A,A1相同或不同,并且表示在原子或基团之间形成桥 段R和苯乙烯基吡啶链的芳香核,含有立体移动键,R2表示氢或甲基或乙基,x,y,z表示可等于0的整数,y + z之和至少等于 有利地,A,A1表示氧原子。 本发明的树脂具有比常规聚苯乙烯基吡啶(PSP)树脂更好的机械性能,特别是在环境温度下,同时保持了PSP树脂的优异的耐热性和耐湿性。 该树脂可以用作层压体中的基质。