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1. 发明申请

US20190211127A1 COATED POLYMER PARTICLES COMPRISING A WATER-SWELLABLE POLYMER CORE AND A SOL-GEL COATING 审中-公开
公开(公告)号：US20190211127A1
公开(公告)日：2019-07-11
申请号：US16093364
申请日：2017-04-05
申请人： BASF SE
发明人： Peter LEIDINGER , Piotr Antoni BAZULA , Holger MISSLITZ , Gregor HERTH , Stefan FRIEDRICH , Maik SCHLESINGER
IPC分类号： C08F220/48 , C08J7/06 , C09K8/516 , C09K8/508 , C09K8/588 , C04B24/16 , C04B20/10
CPC分类号： C08F220/48 , C04B20/1066 , C04B20/1074 , C04B24/163 , C04B2103/0049 , C04B2111/29 , C08F220/56 , C08F2800/10 , C08J3/128 , C08J7/06 , C08J2300/14 , C08J2333/20 , C08J2333/26 , C09K8/467 , C09K8/487 , C09K8/5083 , C09K8/516 , C09K8/588 , C04B24/2652 , C08F220/06 , C08F222/385 , C08F2220/585
摘要： The present invention relates to coated polymer particles comprising a water-swellable polymer core and an essentially continuous coating encapsulating the core. The coating comprises an oxide, hydroxide or oxide hydrate of silicon, aluminum, zirconium, tin or titanium. The polymer particles do not show instantaneous swelling, when contacted with water or a water-containing liquid, but show delayed water absorption after an appropriate period of time. The coated polymer particles may be used in oil fields, in mining, for construction chemical compositions or as carrier for active substances. The coated polymer particles are prepared by a suspension coating process or a fluidized bed coating process.

2. 发明授权

US08324286B2 Heat-expandable microspheres, method for producing the same, and application thereof 有权
标题翻译：热膨胀性微球，其制造方法及其应用
公开(公告)号：US08324286B2
公开(公告)日：2012-12-04
申请号：US12089600
申请日：2006-11-16
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takeyoshi Fukuda , Takayuki Aoki , Satoshi Kawanami
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takeyoshi Fukuda , Takayuki Aoki , Satoshi Kawanami
IPC分类号： C08J9/228 , C08J9/00
CPC分类号： B01J13/14 , C08F220/14 , C08F220/44 , C08F220/48 , C08F222/1006 , Y10T428/2984
摘要： Heat-expandable microspheres include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin, have a maximum expanding ratio not lower than 50 times, and are thermally expanded into hollow particulates having a repeated-compression durability not lower than 75 percent. The method of producing the heat-expandable microspheres includes the steps of dispersing an oily mixture containing a polymerizable component and the blowing agent in an aqueous dispersing medium containing a specific water-soluble compound and polymerizing the polymerizable component contained in the oily mixture.
摘要翻译：热膨胀性微球包括热塑性树脂的壳和其中包含沸点不高于热塑性树脂的软化点的发泡剂，其最大膨胀比不低于50倍，并且被热膨胀成具有重复压缩耐久性不低于75％。制造热膨胀性微球的方法包括以下步骤：将含有可聚合组分和发泡剂的油性混合物分散在含有特定水溶性化合物的水性分散介质中，并使包含在油性混合物中的可聚合组分聚合。

3. 发明申请

US20100036065A1 Maleimide-alpha-alkylstyrene-based tetrapolymer with low molten viscosity and continuous bulk process for producing it 有权
标题翻译：具有低熔融粘度的马来酰亚胺-α-烷基苯乙烯基四
聚物和用于生产它的连续的本体方法
公开(公告)号：US20100036065A1
公开(公告)日：2010-02-11
申请号：US12443358
申请日：2006-12-02
申请人： Dong Cheol Sohn , Sup Joo Lee , Byung Yoon Ahn
发明人： Dong Cheol Sohn , Sup Joo Lee , Byung Yoon Ahn
IPC分类号： C08F2/01 , C08F222/40
CPC分类号： C08F2/02 , C08F212/10 , C08F212/12 , C08F220/48 , C08F222/08 , C08F222/40 , C08F226/00
摘要： Disclosed are a maleimide-α-alkylstyrene-based, heat-resistant bulk tetrapolymer and a preparation process thereof. More specifically, disclosed are a bulk tetrapolymer, comprising 5-60 wt % of an N-substituted maleimide monomer, 10-70 wt % of an α-alkylstyrene monomer, 5-50 wt % of an unsaturated nitrile monomer and 3-50 wt % of an aromatic vinyl monomer, as well as a continuous bulk polymerization process for preparing the same. The disclosed bulk tetrapolymer has a weight-average molecular weight (Mw) of 70,000-300,000 and a glass transition temperature of 150-200° C., shows excellent high-temperature thermal stability and heat resistance and a remarkably low melt viscosity, and thus is excellent not only in processability, but also in productivity, processability, moldability and blendability, when it is blended with other resins. Also, the continuous bulk polymerization process is equipped with a devolatilizer and enables the bulk tetrapolymer to be produced at low cost and high efficiency.
摘要翻译：公开了马来酰亚胺-α-烷基苯乙烯类，耐热本体四元共聚物及其制备方法。更具体地，公开了一种本体四元共聚物，其包含5-60重量％的N-取代的马来酰亚胺单体，10-70重量％的α-烷基苯乙烯单体，5-50重量％的不饱和腈单体和3-50重量％％的芳族乙烯基单体，以及用于制备芳族乙烯基单体的连续本体聚合方法。所公开的本体四元共聚物的重均分子量（Mw）为70,000〜30000，玻璃化转变温度为150-200℃，显示出优异的高温热稳定性和耐热性，并且显示出非常低的熔融粘度，因此当其与其它树脂混合时，不仅在加工性方面优异，而且在生产率，加工性，成型性和混合性方面也是优异的。此外，连续本体聚合方法配备脱挥发物，能够以低成本和高效率制造本体四元共聚物。

4. 发明授权

US4900764A Hydrophilic materials 失效
标题翻译：亲水性材料
公开(公告)号：US4900764A
公开(公告)日：1990-02-13
申请号：US195158
申请日：1988-05-18
申请人： Donald J. Highgate , John D. Frankland
发明人： Donald J. Highgate , John D. Frankland
IPC分类号： C08F2/44 , C08F220/48 , C08F226/10 , G02B1/04 , G02C7/04
CPC分类号： G02C7/041 , C08F2/44 , C08F220/48 , C08F226/10 , G02B1/043
摘要： Hydrophilic polymers of the type suitable for use in making contact lenses and having a wide range of controllable properties including strength and gas permeability are formed from acrylonitrile or methyl methacrylate or an analogue thereof, 1-vinyl-2-pyrrolidinone and an appropriate amount of a cross-linking agent. Contact lenses (3) having an interferometric pattern thereon are also disclosed.

5. 发明授权

US4698413A Acrylic fiber suitable for preparing carbon or graphite fibers 失效
标题翻译：丙烯酸纤维适用于制备碳纤维或石墨纤维
公开(公告)号：US4698413A
公开(公告)日：1987-10-06
申请号：US793720
申请日：1985-10-31
申请人： Charles E. Lynch , William K. Wilkinson
发明人： Charles E. Lynch , William K. Wilkinson
IPC分类号： C08F220/46 , C08F220/48 , C08F28/00
CPC分类号： C08F220/46 , C08F220/48
摘要： An acrylic fiber useful in the preparation of precursor fibers for the preparation of carbon or graphite fibers contains 93.0-99.4 mol percent acrylonitrile, 0.6-4.0 mol percent of ammonium or amine having a pKb of 5 or less as neutralizing cations for sulfonic and sulfuric acid end groups derived from the initiator and activator and as neutralizing cations for sulfonic acid groups derived from one or more sulfonic acid containing comonomers and 0-3.0 mol percent of one or more comonomers selected from the group consisting of simple acrylate or methacrylate esters, simply vinyl esters, styrene, vinyl chloride and vinylidene chloride, the fiber containing no more than 0.3 mol percent of cations other than ammonium or amine.
摘要翻译：用于制备用于制备碳或石墨纤维的前体纤维的丙烯酸纤维含有93.0-99.4mol％丙烯腈，0.6-4.0mol％的pKb为5或更小的铵或胺作为磺酸和硫酸的中和阳离子衍生自引发剂和活化剂的端基以及作为用于衍生自一种或多种含磺酸共聚单体的磺酸基团的中和阳离子和0-3.0mol％选自简单丙烯酸酯或甲基丙烯酸酯的一种或多种共聚单体，简单地乙烯基酯，苯乙烯，氯乙烯和偏二氯乙烯，所述纤维含有不超过0.3mol％的除铵或胺之外的阳离子。

6. 发明授权

US09663626B2 Heat-expandable microspheres, process for producing the same, and application thereof 有权
公开(公告)号：US09663626B2
公开(公告)日：2017-05-30
申请号：US14366200
申请日：2013-01-21
申请人： MATSUMOTO YUSHI-SEIYAKU CO., LTD.
发明人： Naoya Tayagaki , Yasuyuki Nomura
IPC分类号： C08J9/20 , C08F2/44 , C09J11/00 , C08F2/20 , C08J9/00 , C08F220/48 , C08J9/228 , C09J11/08 , B01J13/18 , C08K7/22 , C08F218/08 , C08F220/18 , C08F220/56 , C08F222/38
CPC分类号： C08J9/20 , B01J13/185 , C08F2/20 , C08F2/44 , C08F218/08 , C08F220/18 , C08F220/48 , C08F220/56 , C08F222/38 , C08J9/0066 , C08J9/228 , C08J2203/22 , C08J2333/18 , C08J2333/20 , C08K7/22 , C09J11/00 , C09J11/08 , C08F220/44 , C08F2222/1013
摘要： Heat-expandable microspheres with high encapsulation efficiency of a blowing agent and good heat-expansion performance, a process for reproducibly producing the heat-expandable microspheres and application thereof are provided. The heat-expandable microspheres comprise essentially a thermoplastic resin shell and a blowing agent encapsulated therein, and contain not more than 500 ppm of silicon, not more than 350 ppm of aluminum and not more than 600 ppm of the total of the silicon and aluminum. The heat-expandable microspheres retain at least 70% of the blowing agent encapsulated therein at the temperature which is the average of their expansion-initiation temperature and maximum expansion temperature.

7. 发明授权

US09620781B2 Electrode binder for secondary battery providing excellent adhesion strength and life characteristics 有权
公开(公告)号：US09620781B2
公开(公告)日：2017-04-11
申请号：US14409582
申请日：2013-07-04
申请人： LG Chem, Ltd.
发明人： Min Ah Kang , Young-Min Kim , Eun Joo Park
IPC分类号： H01M4/13 , H01M4/58 , H01M4/62 , C08F212/10 , C08F220/46 , C08F220/48 , H01M10/052 , H01M10/0525
CPC分类号： H01M4/622 , C08F212/10 , C08F220/46 , C08F220/48 , H01M4/13 , H01M4/623 , H01M10/052 , H01M10/0525
摘要： Disclosed is a binder for a secondary battery electrode including a copolymer of a hydrophilic monomer and a hydrophobic monomer, wherein, when a concentration of the copolymer is 5% in a solution based upon NMP as a solvent, a viscosity of the solution including the copolymer is 800 cP to 10000 cP. By using the binder, stability of an electrode is fundamentally improved from an electrode preparation process and, as such, a secondary battery having excellent lifespan characteristics is provided.

8. 发明申请

US20140364521A1 HEAT-EXPANDABLE MICROSPHERES, PROCESS FOR PRODUCING THE SAME, AND APPLICATION THEREOF 有权
标题翻译：热可膨胀微球，其生产方法及其应用
公开(公告)号：US20140364521A1
公开(公告)日：2014-12-11
申请号：US14366200
申请日：2013-01-21
申请人： MATSUMOTO YUSHI-SEIYAKU CO., LTD.
发明人： Naoya Tayagaki , Yasuyuki Nomura
IPC分类号： C08J9/20 , C08F220/48 , C09J11/08 , C08J9/228
CPC分类号： C08J9/20 , B01J13/185 , C08F2/20 , C08F2/44 , C08F218/08 , C08F220/18 , C08F220/48 , C08F220/56 , C08F222/38 , C08J9/0066 , C08J9/228 , C08J2203/22 , C08J2333/18 , C08J2333/20 , C08K7/22 , C09J11/00 , C09J11/08 , C08F220/44 , C08F2222/1013
摘要： Heat-expandable microspheres with high encapsulation efficiency of a blowing agent and good heat-expansion performance, a process for reproducibly producing the heat-expandable microspheres and application thereof are provided. The heat-expandable microspheres comprise essentially a thermoplastic resin shell and a blowing agent encapsulated therein, and contain not more than 500 ppm of silicon, not more than 350 ppm of aluminum and not more than 600 ppm of the total of the silicon and aluminum. The heat-expandable microspheres retain at least 70% of the blowing agent encapsulated therein at the temperature which is the average of their expansion-initiation temperature and maximum expansion temperature.
摘要翻译：提供了发泡剂的高封装效率和良好的热膨胀性能的热膨胀性微球，可再生产热膨胀性微球的方法及其应用。热膨胀性微球体基本上包含热塑性树脂壳和包封在其中的发泡剂，并且含有不超过500ppm的硅，不超过350ppm的铝和不超过600ppm的硅和铝的总量。热膨胀性微球在其膨胀开始温度和最大膨胀温度的平均温度下保持其中包封的发泡剂的至少70％。

9. 发明授权

US08487057B2 Maleimide-alpha-alkylstyrene-based tetrapolymer with low molten viscosity and continuous bulk process for producing it 有权
标题翻译：具有低熔融粘度的马来酰亚胺-α-烷基苯乙烯基四
聚物和用于生产它的连续的本体方法
公开(公告)号：US08487057B2
公开(公告)日：2013-07-16
申请号：US13313354
申请日：2011-12-07
申请人： Dong Cheol Sohn , Sup Joo Lee
发明人： Dong Cheol Sohn , Sup Joo Lee
IPC分类号： C08F222/40
CPC分类号： C08F2/02 , C08F212/10 , C08F212/12 , C08F220/48 , C08F222/08 , C08F222/40 , C08F226/00
摘要： Disclosed are a maleimide-a-alkylstyrene-based, heat-resistant bulk tetrapolymer and a preparation process thereof. More specifically, disclosed are a bulk tetrapolymer, comprising 5-60 wt % of an N-substituted maleimide monomer, 10-70 wt % of an a-alkylstyrene monomer, 5-50 wt % of an unsaturated nitrile monomer and 3-50 wt % of an aromatic vinyl monomer, as well as a continuous bulk polymerization process for preparing the same. The disclosed bulk tetrapolymer has a weight-average molecular weight (Mw) of 70,000-300,000 and a glass transition temperature of 150-200 DEG C., shows excellent high-temperature thermal stability and heat resistance and a remarkably low melt viscosity, and thus is excellent not only in processability, but also in productivity, processability, moldability and blendability, when it is blended with other resins. Also, the continuous bulk polymerization process is equipped with a devolatilizer and enables the bulk tetrapolymer to be produced at low cost and high efficiency.
摘要翻译：公开了马来酰亚胺-α-烷基苯乙烯类，耐热本体四元共聚物及其制备方法。更具体地，公开了一种本体四元共聚物，其包含5-60重量％的N-取代的马来酰亚胺单体，10-70重量％的α-烷基苯乙烯单体，5-50重量％的不饱和腈单体和3-50重量％％的芳族乙烯基单体，以及用于制备芳族乙烯基单体的连续本体聚合方法。所公开的本体四元共聚物的重均分子量（Mw）为70,000〜30000，玻璃化转变温度为150〜200℃，显示出优异的高温热稳定性和耐热性，并且显示出非常低的熔融粘度当其与其它树脂混合时，不仅在加工性方面优异，而且在生产率，加工性，成型性和混合性方面也是优异的。此外，连续本体聚合方法配备脱挥发物，能够以低成本和高效率制造本体四元共聚物。

10. 发明申请

US20120142875A1 MALEIMIDE-ALPHA-ALKYLSTYRENE-BASED TETRAPOLYMER WITH LOW MOLTEN VISCOSITY AND CONTINUOUS BULK PROCESS FOR PRODUCING IT 有权
标题翻译：具有低粘度粘度和连续生产流程的马来酰亚胺基二苯乙烯基四氢吡喃酮
公开(公告)号：US20120142875A1
公开(公告)日：2012-06-07
申请号：US13313354
申请日：2011-12-07
申请人： Dong Cheol Sohn , Sup Joo Lee , Byung Yoon Ahn
发明人： Dong Cheol Sohn , Sup Joo Lee , Byung Yoon Ahn
IPC分类号： C08F222/40 , C08F2/01
CPC分类号： C08F2/02 , C08F212/10 , C08F212/12 , C08F220/48 , C08F222/08 , C08F222/40 , C08F226/00
摘要： Disclosed are a maleimide-a-alkylstyrene-based, heat-resistant bulk tetrapolymer and a preparation process thereof. More specifically, disclosed are a bulk tetrapolymer, comprising 5-60 wt % of an N-substituted maleimide monomer, 10-70 wt % of an a-alkylstyrene monomer, 5-50 wt % of an unsaturated nitrile monomer and 3-50 wt % of an aromatic vinyl monomer, as well as a continuous bulk polymerization process for preparing the same. The disclosed bulk tetrapolymer has a weight-average molecular weight (Mw) of 70,000-300,000 and a glass transition temperature of 150-200 DEG C., shows excellent high-temperature thermal stability and heat resistance and a remarkably low melt viscosity, and thus is excellent not only in processability, but also in productivity, processability, moldability and blendability, when it is blended with other resins. Also, the continuous bulk polymerization process is equipped with a devolatilizer and enables the bulk tetrapolymer to be produced at low cost and high efficiency.
摘要翻译：公开了马来酰亚胺-α-烷基苯乙烯类，耐热本体四元共聚物及其制备方法。更具体地，公开了一种本体四元共聚物，其包含5-60重量％的N-取代的马来酰亚胺单体，10-70重量％的α-烷基苯乙烯单体，5-50重量％的不饱和腈单体和3-50重量％％的芳族乙烯基单体，以及用于制备芳族乙烯基单体的连续本体聚合方法。所公开的本体四元共聚物的重均分子量（Mw）为70,000〜30000，玻璃化转变温度为150〜200℃，显示出优异的高温热稳定性和耐热性，并且显示出非常低的熔融粘度当其与其它树脂混合时，不仅在加工性方面优异，而且在生产率，加工性，成型性和混合性方面也是优异的。此外，连续本体聚合方法配备脱挥发物，能够以低成本和高效率制造本体四元共聚物。

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