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    • 6. 发明申请
    • Maleimide-alpha-alkylstyrene-based tetrapolymer with low molten viscosity and continuous bulk process for producing it
    • 具有低熔融粘度的马来酰亚胺-α-烷基苯乙烯基四
      聚物和用于生产它的连续的本体方法
    • US20100036065A1
    • 2010-02-11
    • US12443358
    • 2006-12-02
    • Dong Cheol SohnSup Joo LeeByung Yoon Ahn
    • Dong Cheol SohnSup Joo LeeByung Yoon Ahn
    • C08F2/01C08F222/40
    • C08F2/02C08F212/10C08F212/12C08F220/48C08F222/08C08F222/40C08F226/00
    • Disclosed are a maleimide-α-alkylstyrene-based, heat-resistant bulk tetrapolymer and a preparation process thereof. More specifically, disclosed are a bulk tetrapolymer, comprising 5-60 wt % of an N-substituted maleimide monomer, 10-70 wt % of an α-alkylstyrene monomer, 5-50 wt % of an unsaturated nitrile monomer and 3-50 wt % of an aromatic vinyl monomer, as well as a continuous bulk polymerization process for preparing the same. The disclosed bulk tetrapolymer has a weight-average molecular weight (Mw) of 70,000-300,000 and a glass transition temperature of 150-200° C., shows excellent high-temperature thermal stability and heat resistance and a remarkably low melt viscosity, and thus is excellent not only in processability, but also in productivity, processability, moldability and blendability, when it is blended with other resins. Also, the continuous bulk polymerization process is equipped with a devolatilizer and enables the bulk tetrapolymer to be produced at low cost and high efficiency.
    • 公开了马来酰亚胺-α-烷基苯乙烯类,耐热本体四元共聚物及其制备方法。 更具体地,公开了一种本体四元共聚物,其包含5-60重量%的N-取代的马来酰亚胺单体,10-70重量%的α-烷基苯乙烯单体,5-50重量%的不饱和腈单体和3-50重量% %的芳族乙烯基单体,以及用于制备芳族乙烯基单体的连续本体聚合方法。 所公开的本体四元共聚物的重均分子量(Mw)为70,000〜30000,玻璃化转变温度为150-200℃,显示出优异的高温热稳定性和耐热性,并且显示出非常低的熔融粘度,因此 当其与其它树脂混合时,不仅在加工性方面优异,而且在生产率,加工性,成型性和混合性方面也是优异的。 此外,连续本体聚合方法配备脱挥发物,能够以低成本和高效率制造本体四元共聚物。
    • 8. 发明授权
    • Acrylic fiber suitable for preparing carbon or graphite fibers
    • 丙烯酸纤维适用于制备碳纤维或石墨纤维
    • US4698413A
    • 1987-10-06
    • US793720
    • 1985-10-31
    • Charles E. LynchWilliam K. Wilkinson
    • Charles E. LynchWilliam K. Wilkinson
    • C08F220/46C08F220/48C08F28/00
    • C08F220/46C08F220/48
    • An acrylic fiber useful in the preparation of precursor fibers for the preparation of carbon or graphite fibers contains 93.0-99.4 mol percent acrylonitrile, 0.6-4.0 mol percent of ammonium or amine having a pKb of 5 or less as neutralizing cations for sulfonic and sulfuric acid end groups derived from the initiator and activator and as neutralizing cations for sulfonic acid groups derived from one or more sulfonic acid containing comonomers and 0-3.0 mol percent of one or more comonomers selected from the group consisting of simple acrylate or methacrylate esters, simply vinyl esters, styrene, vinyl chloride and vinylidene chloride, the fiber containing no more than 0.3 mol percent of cations other than ammonium or amine.
    • 用于制备用于制备碳或石墨纤维的前体纤维的丙烯酸纤维含有93.0-99.4mol%丙烯腈,0.6-4.0mol%的pKb为5或更小的铵或胺作为磺酸和硫酸的中和阳离子 衍生自引发剂和活化剂的端基以及作为用于衍生自一种或多种含磺酸共聚单体的磺酸基团的中和阳离子和0-3.0mol%选自简单丙烯酸酯或甲基丙烯酸酯的一种或多种共聚单体,简单地乙烯基 酯,苯乙烯,氯乙烯和偏二氯乙烯,所述纤维含有不超过0.3mol%的除铵或胺之外的阳离子。