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1. 发明授权

US08486531B2 Thermally expanded microspheres and a process for producing the same 有权
标题翻译：热膨胀微球及其制备方法
公开(公告)号：US08486531B2
公开(公告)日：2013-07-16
申请号：US13355647
申请日：2012-01-23
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
IPC分类号： B32B1/00 , B32B5/16 , C08J9/22 , C08J9/00
CPC分类号： B01J13/20 , B29C44/3461 , C08J9/143 , C08J9/32 , C08J2333/18 , Y10T428/2982 , Y10T428/2984 , Y10T428/2985 , Y10T428/2991 , Y10T428/2998
摘要： The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.
摘要翻译：本发明提供具有高填充效率的热膨胀微球及其制造方法。热膨胀微球体是通过膨胀包含热塑性树脂壳和封装在其中的沸点不高于热塑性树脂的软化点的发泡剂的热膨胀性微球而制成的，平均粒径为1〜100 微米，其温度不低于其膨胀起始温度，热膨胀微球导致不高于0.70的空隙率。

2. 发明授权

US08289715B2 Plasma display device 失效
标题翻译：等离子显示装置
公开(公告)号：US08289715B2
公开(公告)日：2012-10-16
申请号：US12869334
申请日：2010-08-26
申请人： Ichiro Takahara
发明人： Ichiro Takahara
IPC分类号： H05K7/20
CPC分类号： H05K7/20972 , H05K7/2099
摘要： A plasma display device is provided with a chassis supporting a PDP on its front surface, circuit boards located within a specific region of the back surface of the chassis, a back cover including an edge portion covering the outside of the specific region of the back surface of the chassis and a projecting portion accommodating the plurality of the circuit boards, and a fan arranged inside a space defined by the projecting portion. The peripheral wall of the projecting portion is provided with a plurality of air inlets and a plurality of air outlets.
摘要翻译：等离子体显示装置设置有在其前表面上支撑PDP的底座，位于底盘的后表面的特定区域内的电路板，后盖，其包括覆盖背面的特定区域的外侧的边缘部分以及容纳所述多个电路板的突出部，以及设置在由所述突出部限定的空间内的风扇。突出部的周壁设置有多个空气入口和多个空气出口。

3. 发明申请

US20110051369A1 PLASMA DISPLAY DEVICE 失效
标题翻译：等离子体显示设备
公开(公告)号：US20110051369A1
公开(公告)日：2011-03-03
申请号：US12869334
申请日：2010-08-26
申请人： Ichiro TAKAHARA
发明人： Ichiro TAKAHARA
IPC分类号： H05K7/20
CPC分类号： H05K7/20972 , H05K7/2099
摘要： A plasma display device is provided with a chassis supporting a PDP on its front surface, circuit boards located within a specific region of the back surface of the chassis, a back cover including an edge portion covering the outside of the specific region of the back surface of the chassis and a projecting portion accommodating the plurality of the circuit boards, and a fan arranged inside a space defined by the projecting portion. The peripheral wall of the projecting portion is provided with a plurality of air inlets and a plurality of air outlets.
摘要翻译：等离子体显示装置设置有在其前表面上支撑PDP的底座，位于底盘的后表面的特定区域内的电路板，后盖，其包括覆盖背面的特定区域的外侧的边缘部分以及容纳所述多个电路板的突出部，以及设置在由所述突出部限定的空间内的风扇。突出部的周壁设置有多个空气入口和多个空气出口。

4. 发明授权

US07351752B2 Thermo-expansive microspheres, their production process and their application 失效
标题翻译：热膨胀微球，其生产工艺及其应用
公开(公告)号：US07351752B2
公开(公告)日：2008-04-01
申请号：US10954212
申请日：2004-10-01
申请人： Katsushi Miki , Toshiaki Masuda , Ichiro Takahara , Takashi Fujie , Ikuo Yosejima
发明人： Katsushi Miki , Toshiaki Masuda , Ichiro Takahara , Takashi Fujie , Ikuo Yosejima
IPC分类号： C08J9/00
CPC分类号： C08J9/32 , B01J13/14 , C08J2203/14 , C08J2203/22
摘要： The present invention provides thermo-expansive microspheres comprising thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin; and also provides the production and application processes thereof. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 μm and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.The thermo-expansive microspheres have low environmental loading and superior flame-retardant or flame-resistant performance, and have particle sizes distributing in narrow ranges. Those thermo-expansive microspheres and foamed hollow microspheres are suitable for applying to fire-proof paints, flame-retardant or flame-resistant thermo-insulating materials, flame-retardant or flame-resistant lightweight fillers, and flame-retardant or flame-resistant lightweight molded products, in addition to the conventional application field.
摘要翻译：本发明提供了包含热塑性树脂壳和封装在壳中的发泡剂的热膨胀性微球，发泡剂是具有醚键的含氟C 2-10 - 化合物，不含氯和溴原子，并且在不高于热塑性树脂的软化点的温度下气化; 并提供其生产和应用程序。热膨胀性微球体的平均粒径优选为1〜100μm，粒径分布的CV或变异系数为30％以下，发泡剂的保持率为90％以上。热膨胀微球具有低环境负荷和优异的阻燃或阻燃性能，并且粒度分布范围窄。这些热膨胀微球和发泡中空微球适用于防火涂料，阻燃或阻燃绝热材料，阻燃或阻燃轻质填料，以及阻燃或阻燃轻质模制产品，除了常规应用领域。

5. 发明授权

US06984347B2 Thermo-expansive microcapsules and their application 有权
标题翻译：热膨胀微胶囊及其应用
公开(公告)号：US06984347B2
公开(公告)日：2006-01-10
申请号：US10923811
申请日：2004-08-24
申请人： Toshiaki Masuda , Ichiro Takahara , Takashi Hujie , Yoshiaki Shirakabe , Katsushi Miki
发明人： Toshiaki Masuda , Ichiro Takahara , Takashi Hujie , Yoshiaki Shirakabe , Katsushi Miki
IPC分类号： C08J9/16 , C08J9/18 , B01J13/02 , B32B15/02
CPC分类号： B01J13/14 , Y10T428/2987
摘要： Thermo-expansive microcapsules comprising a shell of a polymer produced by polymerizing a mixture of monomers, which comprises (I) a nitrile monomer, (II) a monomer having an unsaturated double bond and carboxyl groups in a molecule, (III) a monomer having two or more of polymerizable double bonds in a molecule, and optionally, (IV) a monomer different from and copolymerizable with the monomers (I), (II) and (III) and a blowing agent encapsulated in the shell. The volume retention of the expanded microcapsules of the thermo-expansive microcapsules is 50% or more after loaded with 15 MPa.
摘要翻译：包含通过聚合单体混合物制备的聚合物的壳的热膨胀微胶囊，其包含（I）腈单体，（II）分子中具有不饱和双键的单体和羧基，（III）具有分子中的两个或更多个可聚合双键，和任选地（Ⅳ）与单体（I），（II）和（III）不同且可共聚的单体和包封在壳中的发泡剂。热膨胀微胶囊的膨胀微胶囊的体积保留率在加载15MPa后为50％以上。

6. 发明授权

US4601588A Temperature-indicating sheet 失效
标题翻译：温度指示表
公开(公告)号：US4601588A
公开(公告)日：1986-07-22
申请号：US776217
申请日：1985-09-16
申请人： Ichiro Takahara , Tomoyoshi Ono , Makoto Nakai
发明人： Ichiro Takahara , Tomoyoshi Ono , Makoto Nakai
IPC分类号： G01K11/06 , G01K11/16 , G01K11/12
CPC分类号： G01K11/06 , G01K11/16
摘要： The present invention provides a temperature-indicating sheet which, when exposed to temperatures higher than the prescribed temperature in temperature-control for the common low-temperature preserved goods, changes in color according to the exposure temperature and time. This object is attained by arranging one component which melts at the prescribed temperature and a substance which irreversibly changes in color in contact with said component through a membrane permeable to the component. The sheet of the present invention comprises a component which melts at the prescribed temperature, a substance which changes in color in contact with the component and a membrane permeable to the molten component, said component being included in microcapsules which can be broken by outer pressure at a temperature used, and in which the component and the substance are arranged at the opposite sides with respect to the membrane.
摘要翻译：本发明提供一种温度指示片，其在暴露于高于普通低温保存品的温度控制中的规定温度的温度时，根据曝光温度和时间而改变颜色。该目的通过将一种在规定温度下熔化的组分和通过可渗透组分的膜与所述组分接触而不可逆地变色的物质来实现。本发明的片材包括在规定温度下熔化的成分，与成分接触的颜色变化的物质和可熔融成分的膜，所述成分包含在微胶囊中，该微胶囊可以通过外部压力使用的温度，并且其中组分和物质相对于膜相对侧布置。

7. 发明授权

US08129020B2 Thermally expanded microspheres and a process for producing the same 有权
标题翻译：热膨胀微球及其制备方法
公开(公告)号：US08129020B2
公开(公告)日：2012-03-06
申请号：US12066057
申请日：2006-09-14
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
IPC分类号： C08J9/16 , B32B1/00
CPC分类号： B01J13/20 , B29C44/3461 , C08J9/143 , C08J9/32 , C08J2333/18 , Y10T428/2982 , Y10T428/2984 , Y10T428/2985 , Y10T428/2991 , Y10T428/2998
摘要： Heat-expanded microspheres having high packing efficiency are produced by expanding heat-expandable microspheres, which include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.
摘要翻译：具有高填充效率的热膨胀微球通过膨胀热膨胀性微球来制造，该微球包括热塑性树脂壳和封装在其中的发泡剂，其沸点不高于热塑性树脂的软化点，并且具有平均粒径 1至100微米，温度不低于其膨胀起始温度，热膨胀微球体的空隙率不高于0.70。

8. 发明授权

US07994229B2 Thermo-expansive microspheres, their production process and their application 有权
标题翻译：热膨胀微球，其生产工艺及其应用
公开(公告)号：US07994229B2
公开(公告)日：2011-08-09
申请号：US12068430
申请日：2008-02-06
申请人： Katsushi Miki , Toshiaki Masuda , Ichiro Takahara , Takashi Fujie , Ikuo Yosejima
发明人： Katsushi Miki , Toshiaki Masuda , Ichiro Takahara , Takashi Fujie , Ikuo Yosejima
IPC分类号： C08J9/32
CPC分类号： C08J9/32 , B01J13/14 , C08J2203/14 , C08J2203/22
摘要： The present invention provides a process for producing thermo-expansive microspheres comprising a thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 μm and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.
摘要翻译：本发明提供一种包含热塑性树脂壳和包封在壳中的发泡剂的热膨胀性微球的方法，发泡剂是具有醚键的含氟C2-10化合物，不含氯和溴原子并在不高于热塑性树脂的软化点的温度下气化。热膨胀性微球的平均粒径优选为1〜100μm，粒径分布的CV或变异系数为30％以下，发泡剂的保持率为90％以上。

9. 发明申请

US20090280328A1 THERMALLY EXPANDED MICROSPHERES AND A PROCESS FOR PRODUCING THE SAME 有权
标题翻译：热膨胀微晶及其制造方法
公开(公告)号：US20090280328A1
公开(公告)日：2009-11-12
申请号：US12066057
申请日：2006-09-14
申请人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
发明人： Toshiaki Masuda , Ichiro Takahara , Kenichi Kitano , Katsushi Miki , Takeshi Inohara , Takayuki Aoki
IPC分类号： B32B1/00 , C08J9/16
CPC分类号： B01J13/20 , B29C44/3461 , C08J9/143 , C08J9/32 , C08J2333/18 , Y10T428/2982 , Y10T428/2984 , Y10T428/2985 , Y10T428/2991 , Y10T428/2998
摘要： The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.
摘要翻译：本发明提供具有高填充效率的热膨胀微球及其制造方法。热膨胀微球体是通过膨胀包含热塑性树脂壳和封装在其中的沸点不高于热塑性树脂的软化点的发泡剂的热膨胀性微球而制成的，平均粒径为1〜100 微米，其温度不低于其膨胀起始温度，热膨胀微球导致不高于0.70的空隙率。

10. 发明申请

US20070154711A1 Thermally expanded microsphere, process for producing the same, thermally expandable microsphere and use thereof 有权
标题翻译：热膨胀微球，其制造方法，热膨胀性微球及其用途
公开(公告)号：US20070154711A1
公开(公告)日：2007-07-05
申请号：US10595910
申请日：2004-11-15
申请人： Toshiaki Masuda , Takashi Fujie , Ichiro Takahara , Ikuo Yosejima , Katsushi Miki
发明人： Toshiaki Masuda , Takashi Fujie , Ichiro Takahara , Ikuo Yosejima , Katsushi Miki
IPC分类号： B32B17/02 , C08K9/10
CPC分类号： C08J9/22 , B01J13/04 , B01J13/14 , C08J9/32 , C08J2203/142 , Y10T428/2985 , Y10T428/2987 , Y10T428/2991
摘要： A production process for heat-expanded microspheres comprising the step of providing a gaseous fluid containing heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 μm, feeding the gaseous fluid through a gas-introducing tube having a dispersion nozzle on its outlet and being fixed inside a hot gas flow, and emitting a jet of the gaseous fluid through the dispersion nozzle; a step wherein the gaseous fluid is collided on a collision plate fixed under the dispersion nozzle so as to disperse the heat-expandable microspheres in the hot gas flow; and a step wherein the dispersed heat-expandable microspheres are heated in the hot gas flow at a temperature not lower than their expansion initiating temperature and thus expanded. The production process results in minimum difference in the variation coefficient of particle size distribution between the microspheres before and after heat-expansion, slight ratio of raw microspheres and slightly expanded microspheres contained in resultant heat-expanded microspheres, and suppressed formation of aggregated microspheres.
摘要翻译：一种热膨胀微球的制造方法，包括以下步骤：提供包含热膨胀性微球的气态流体，其包含热塑性树脂壳和封装在其中的发泡剂，沸点不高于热塑性树脂的软化点，并具有平均粒度为1〜100μm，通过具有分散喷嘴的气体导入管在其出口处供给气体流体并固定在热气流内，并通过分散喷嘴喷射气态流体; 其中气态流体碰撞在固定在分散喷嘴下方的碰撞板上，以将热膨胀性微球分散在热气流中; 以及在热气流中以不低于其膨胀开始温度的温度加热分散的热膨胀性微球从而膨胀的步骤。生产过程导致热膨胀前后的微球之间的粒度分布的变异系数的差异最小，所得热膨胀微球中所含的微生物微球和微球的微小比例，抑制聚集的微球的形成。

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