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1. 发明授权

US4400327A Preparation of siloxylated metal-containing catalysts 失效
标题翻译：含硅烷化金属的催化剂的制备
公开(公告)号：US4400327A
公开(公告)日：1983-08-23
申请号：US335612
申请日：1981-12-30
申请人： Feyyaz O, Baskent , James D. Reedy
发明人： Feyyaz O, Baskent , James D. Reedy
IPC分类号： C08G18/00 , C07F7/00 , C07F7/08 , C07F7/22 , C07F7/24 , C07F7/28 , C07F15/04 , C08G18/16 , C08G18/22 , C08G18/24 , C07F3/10 , C07F3/06
CPC分类号： C07F7/2252 , C07F7/0836 , C07F7/24 , C07F7/28 , C08G18/22 , C08G18/24
摘要： Reaction of silylamine with a metallic carboxylate produces siloxylated organometallic compounds with M--O--Si bonds. These siloxylated organometallic compounds are useful catalysts in the preparation of urethane foams and elastomers, especially when prepared in situ with the urethane foam or elastomer reactants.
摘要翻译：甲硅烷基胺与金属羧酸盐的反应产生具有M-O-Si键的硅氧烷化的有机金属化合物。这些硅氧烷化的有机金属化合物是制备聚氨酯泡沫和弹性体的有用的催化剂，特别是当用聚氨酯泡沫或弹性体反应物原位制备时。

2. 发明授权

US3312725A Toxic organotin borates 失效
标题翻译：有机锡硼酸盐
公开(公告)号：US3312725A
公开(公告)日：1967-04-04
申请号：US28182063
申请日：1963-05-20
申请人： MONSANTO CO
发明人： GUSTAV WEISSENBERGER
IPC分类号： C07F7/22
CPC分类号： C07F7/2252 , C07F7/2248

3. 发明授权

US2867641A Hydrocarbontinborates 失效
标题翻译：碳氢化合物硼酸盐
公开(公告)号：US2867641A
公开(公告)日：1959-01-06
申请号：US44116554
申请日：1954-07-02
申请人： METAL & THERMIT CORP
发明人： RAMSDEN HUGH E
IPC分类号： C07F7/22 , C08K5/57
CPC分类号： C08K5/57 , C07F7/2248 , C07F7/2252 , C08L27/06 , C08L57/08 , C08L27/04
摘要： Polyvinyl chloride and polyvinylidene chloride compositions with or without plasticizers are stabilized against heat and light by addition of a dihydrocarbon tin borate of formula (R2Sn)3-n(R1)2n(BO3)2 where R and R1 are alkyl, aryl or aralkyl groups (R1 being an alcohol or phenol residue) and n is 0, 1 or 2. Specified stabilizers include dibutyl tin borate and a compound of formula (C4H9)2Sn(C8H17)4 (BO3)2 prepared from dibutyl tin oxide, 2-ethyl hexanol and boric acid. A composition comprising polyvinyl chloride, di-2-ethylhexyl-phthalate and dibutyl tin borate is described.ALSO:The invention comprises dihydrocarbontin borates of formula wherein R-R1 are alkyl, aryl or aralkyl radicals and n is 0, 1 or 2. They may be prepared by reacting a dihydrocarbontin oxide with boric acid or a partial ester of boric acid at a temperature between 80 DEG and 140 DEG C. If desired, the oxide, boric acid and an alcohol or phenol may be reacted together. The reagents should be substantially anhydrous. An inert organic solvent (benzene, toluene, xylene) may be used as reaction medium. In an example, dibutyl tin oxide is dried by refluxing with toluene, boric acid added and the mixture heated. On distillation of the toluene dibutyl tin borate remains. The preparation of a compound (C4H9)2Sn(C8H17)4 (BO3)2 from dibutyl tin oxide, 2-ethyl hexanol and boric acid is also described.ALSO:Dihydrocarbontin borates of formula: (R2Sn)3-n (R1)2n (BO3)2 are used as rubber antioxidants and rubber accelerators. In the formula R and R1 are alkyl, aryl or aralkyl groups (R1 being the residue of an alcohol or phenol) and n is O, 1, or 2. Specified compounds include dibutyltin borate and a compound of formula (C4H9)2Sn (C8H17)4 (BO3)2 derived from dibutyltin oxide, 2-ethylhexanol and boric acid.

4. 发明授权

US5597882A Tin compound-containing compositions as one of the two components of two component systems which crosslink at room temperature to give organopolysiloxane elastomers 失效
标题翻译：含锡化合物的组合物作为双组分体系的两种组分之一，其在室温下交联以得到有机聚硅氧烷弹性体
公开(公告)号：US5597882A
公开(公告)日：1997-01-28
申请号：US240742
申请日：1994-09-06
申请人： August Schiller , Norman Dorsch , Werner Graf , Alois Strasser
发明人： August Schiller , Norman Dorsch , Werner Graf , Alois Strasser
IPC分类号： C07F7/22 , C08K5/544 , C08K5/57 , C08L83/04 , C08L83/14 , C08G77/06
CPC分类号： C08K5/57 , C07F7/2252 , C08L83/04 , C08G77/18 , C08G77/20 , C08G77/24
摘要： The compositions proposed contain, as their main constituents,(a) a diorganopolysiloxane with triorganosiloxy groups as terminal groups, the organic groups being hydrocarbon groups which may be halogenated,(b) the reaction product of a diacylated diorganotin compound with a disilaalkane containing, per molecule, at least two monovalent hydrocarbon groups which are bonded to silicon via oxygen and may optionally be substituted by an alkoxy group, or with an oligomer of such a disilaalkane,(c) an organosilicon compound containing, per molecule, at least one amino or amino group bonded to silicon via carbon,(d) optionally, a filler and(e) optionally, a disilaalkane and/or silane containing, per molecule, at least three monovalent hydrocarbon groups which are bonded to silicon via oxygen and may optionally be substituted by an alkoxy group, or an oligomer of such a disilaalkane and/or silane.
摘要翻译：所提出的组合物作为其主要成分包含（a）具有三有机甲硅烷氧基作为端基的二有机聚硅氧烷，有机基团可以被卤化的烃基，（b）二酰基二有机锡化合物与二硫代烷烃的反应产物分子，至少两个通过氧连接到硅上并可任选地被烷氧基取代的单价烃基，或与二恶烷的低聚物结合的（c）每分子含有至少一个氨基或氨基通过碳与硅键合，（d）任选的填料和（e）任选的二烷基和/或硅烷，每分子含有至少三个一价烃基，其通过氧连接到硅上，并且可以任选被取代通过烷氧基，或这种二吡烷和/或硅烷的低聚物。

5. 发明授权

US4152343A Process for preparing silicon-tin compounds 失效
标题翻译：制备硅锡化合物的方法
公开(公告)号：US4152343A
公开(公告)日：1979-05-01
申请号：US876452
申请日：1978-02-09
申请人： Ernst Wohlfarth , Wolfgang Hechtl , Paul Hittmair
发明人： Ernst Wohlfarth , Wolfgang Hechtl , Paul Hittmair
IPC分类号： C07F7/04 , C07F7/08 , C07F7/22 , C08K5/57
CPC分类号： C07F7/2252 , C07C67/54 , C07F7/045 , C07F7/0836 , C08K5/57
摘要： Silicon-tin compounds of the formulaR.sub.a Si(OSnR.sup.1 R.sup.2 OOCR.sup.3).sub.4-ain which R represents an alkyl or phenyl radical, R.sup.1, R.sup.2 and R.sup.3 are alkyl radicals and a is 0 or 1 and their use as condensation catalysts in the preparation of organopolysiloxane elastomers.

6. 发明授权

US4080190A Siloxane-tin coatings and their use for protecting materials from growth of pestiferous organisms 失效
标题翻译：硅氮涂料及其用于保护材料免受有害生物生长的用途
公开(公告)号：US4080190A
公开(公告)日：1978-03-21
申请号：US718149
申请日：1976-08-26
申请人： Gabriel H. Law , Albert Peter Gysegem
发明人： Gabriel H. Law , Albert Peter Gysegem
IPC分类号： C09D5/08 , A01N55/04 , A01N55/10 , C07F7/04 , C07F7/22 , C08G77/00 , C08G77/02 , C08G77/04 , C08G77/22 , C08G77/48 , C08G77/58 , C09D5/14 , C09D5/16 , C09D183/00 , A01N9/00
CPC分类号： C08G77/045 , A01N55/04 , C07F7/04 , C07F7/2252 , C08G77/02 , C09D5/1643 , Y10T428/31663
摘要： Compositions for protecting materials from growth of pestiferous organisms, and particularly for protecting marine surfaces from fouling organisms, are formed from precursors having the formula ##STR1## where m is from 1 to about 10, where each X is independently selected from the group consisting of alkyl and alkoxyalkyl radicals containing less than about 6 carbon atoms and Y, where Y has the formula ##STR2## where R.sub.1, R.sub.2 and R.sub.3 are independently selected from the group consisting of alkyl, cycloalkyl, and aryl radicals, where R.sub.1, R.sub.2 and R.sub.3 contain in combination up to about 18 carbon atoms. The ratio of the tin atoms to silicon atoms in the precursors is at least about 1:50.The precursors can be directly used as an additive for coatings. The precursors can also be used by subjecting them to hydrolysis and polycondensation to form an organotin substituted polysiloxane for use as an additive and a binder for coatings.
摘要翻译：用于保护材料免受生物有害生物特别是用于保护海洋表面免受污染的生物体的组合物由具有式为“IMAGE”的前体形成，其中m为1至约10，其中每个X独立地选自含有少于约6个碳原子的烷基和烷氧基烷基和Y，其中Y具有式“IMAGE”，其中R 1，R 2和R 3独立地选自烷基，环烷基和芳基，其中R 1，R 2和R 3 最多含有约18个碳原子。前体中锡原子与硅原子的比例至少约为1:50。

7. 发明授权

US4020092A Compounds bis(tributyltin)chromate and bis(triphenyltin)chromate 失效
标题翻译：化合物双（三丁基锡）铬酸盐和双（三苯基锡）铬酸盐
公开(公告)号：US4020092A
公开(公告)日：1977-04-26
申请号：US527602
申请日：1974-11-27
申请人： Thomas J. Pullukat
发明人： Thomas J. Pullukat
IPC分类号： C07F7/22 , C08F10/00
CPC分类号： C07F7/2252 , C08F10/00
摘要： A catalyst system for the polymerization of at least one 1-olefin comprising a mixture of a bis-trihydrocarbyltinchromate essentially of the formula: ##STR1## and cocatalytic amounts of an alkyl aluminum compound of the formula R.sub.a AlX.sub.b in each of which formula each R is a hydrocarbyl radical containing from 1 to about 14 carbon atoms and all R's are the same or different, X is a halogen or an alkoxy group, a is an integer of 1-3, b is an integer of 0-2 and the sum of a and b is 3. The disclosure also includes the method of polymerizing at least one such olefin which comprises contacting the olefin under polymerizing conditions with the above catalyst system.
摘要翻译：用于聚合至少一种包含基本上具有下式的双 - 三烃基铬酸锡的混合物的催化剂体系和共催化量的式RaAlXb的烷基铝化合物，其中每个R为含有1至约14个碳原子的烃基，所有R相同或不同，X为卤素或烷氧基，a为1-3的整数，b为0-2的整数，a为并且b为3.本公开还包括使至少一种这样的烯烃聚合的方法，其包括使聚合条件下的烯烃与上述催化剂体系接触。

8. 发明授权

US4360654A Reaction products of silicic acid esters and organic tin compounds 失效
标题翻译：硅酸酯和有机锡化合物的反应产物
公开(公告)号：US4360654A
公开(公告)日：1982-11-23
申请号：US295961
申请日：1981-08-25
申请人： Wolfgang Hechtl , Arnold Garhammer
发明人： Wolfgang Hechtl , Arnold Garhammer
IPC分类号： C07F7/22 , C08K5/57 , C08L83/00 , C08L83/04 , C08L83/06 , C08G77/06
CPC分类号： C07F7/2252 , C08K5/57
摘要： Hydroxyl terminated diorganopolysiloxanes may be crosslinked with a mixture containing (1) a product obtained from the reaction of (a) silicic acid esters with (b) an organic tin compound of the formulaR.sub.2 Sn(OCOR.sup.1).sub.2 (I),where R represents a butyl or an octyl radical and R.sup.1 represents a monovalent hydrocarbon radical having from 1 to 15 carbon atoms, in which at most one of the valences of the carbon atom that is bonded to the carboxyl group is saturated by a carbon atom other than that of the carboxyl group, and (2) an organic tin compound of the formulaR.sub.2 Sn(OCOR.sup.2).sub.2 (II),where R is the same as above and R.sup.2 represents a monovalent aliphatic hydrocarbon radical having from 3 to 15 carbon atoms, in which at least two of the valences of the carbon atom that is bonded to the carboxyl group are saturated by two carbon atoms other than that of the carboxyl group.
摘要翻译：羟基封端的二有机聚硅氧烷可以与含有（1）由（a）硅酸酯与（b）式R 2 Sn（OCOR 1）2（I））的有机锡化合物反应获得的产物的混合物交联，其中R表示丁基或辛基，R 1表示碳原子数为1〜15的一价烃基，其中与羧基键合的碳原子的至多一个价数被除了碳原子以外的碳原子饱和羧基，和（2）式R 2 Sn（OCOR 2）2（II）的有机锡化合物，其中R与上述相同，R 2表示具有3至15个碳原子的一价脂族烃基，其中至少与羧基键合的碳原子的两个价数被除了羧基以外的两个碳原子饱和。

9. 发明授权

US4261915A Siloxane-tin coatings 失效
标题翻译：硅氧烷锡涂层
公开(公告)号：US4261915A
公开(公告)日：1981-04-14
申请号：US122198
申请日：1980-02-19
申请人： Gabriel H. Law , Albert P. Gysegem
发明人： Gabriel H. Law , Albert P. Gysegem
IPC分类号： A01N55/00 , A01N55/04 , C07F7/22 , C08G77/02 , C09D5/16
CPC分类号： C08G77/02 , A01N55/00 , A01N55/04 , C07F7/2252 , C09D5/1643
摘要： Compositions for protecting materials from growth of pestiferous organisms, and particularly for protecting marine surfaces from fouling organisms, are formed from precursors having the formula ##STR1## where m is from 1 to about 10, where each X is independently selected from the group consisting of alkyl and alkoxyalkyl radicals containing less than about 6 carbon atoms and Y, where Y has the formula ##STR2## where R.sub.1, R.sub.2 and R.sub.3 are independently selected from the group consisting of alkyl, cycloalkyl, and aryl radicals, where R.sub.1, R.sub.2 and R.sub.3 contain in combination up to about 18 carbon atoms. The ratio of the tin atoms to silicon atoms in the precursors is at least about 1:50.The precursors can be directly used as an additive for coatings. The precursors can also be used by subjecting them to hydrolysis and polycondensation to form an organotin substituted polysiloxane for use as an additive and a binder for coatings.
摘要翻译：用于保护材料免受生物有害生物特别是用于保护海洋表面免受污染的生物体的组合物由具有式为“IMAGE”的前体形成，其中m为1至约10，其中每个X独立地选自含有少于约6个碳原子的烷基和烷氧基烷基和Y，其中Y具有式“IMAGE”，其中R 1，R 2和R 3独立地选自烷基，环烷基和芳基，其中R 1，R 2和R 3 最多含有约18个碳原子。前体中锡原子与硅原子的比例至少约为1:50。前体可以直接用作涂料的添加剂。前体也可以通过使其进行水解和缩聚反应来形成用作添加剂的有机锡取代的聚硅氧烷和用于涂料的粘合剂。

10. 发明授权

US4102860A Silicon-tin compounds as condensation catalysts in the preparation of organopolysiloxane elastomers 失效
标题翻译：硅锡化合物作为缩合催化剂制备有机聚硅氧烷弹性体
公开(公告)号：US4102860A
公开(公告)日：1978-07-25
申请号：US755532
申请日：1976-12-30
申请人： Ernst Wohlfarth , Wolfgang Hechtl , Paul Hittmair
发明人： Ernst Wohlfarth , Wolfgang Hechtl , Paul Hittmair
IPC分类号： C07F7/04 , C07F7/08 , C07F7/22 , C08K5/57 , C08G77/04
CPC分类号： C07F7/2252 , C07F7/04 , C07F7/0836 , C08K5/57
摘要： Silicon-tin compounds of the formulaR.sub.a Si(OSnR.sup.1 R.sup.2 OOCR.sup.3).sub.4-ain which R represents an alkyl or phenyl radical, R.sup.1, R.sup.2 and R.sup.3 are alkyl radicals and a is 0 or 1 and there use as condensation catalysts in the preparation of organopolysiloxane elastomers.
摘要翻译：式R a Si（OSnR 1 O 2 OCR 3）4-a IN的硅锡化合物其中R表示烷基或苯基，R 1，R 2和R 3为烷基，a为0或1，并且在制备有机聚硅氧烷弹性体时用作缩合催化剂。

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