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1. 发明授权

US5412133A Radiation active silicon compounds having thioether linked functional groups 失效
标题翻译：具有硫醚连接官能团的辐射活性硅化合物
公开(公告)号：US5412133A
公开(公告)日：1995-05-02
申请号：US956924
申请日：1992-10-05
申请人： Richard P. Eckberg
发明人： Richard P. Eckberg
IPC分类号： C07F7/08 , C08G77/392 , C09D183/08 , C07F7/04
CPC分类号： C08G77/392 , C07F7/0856 , C09D183/08
摘要： Radiation active silicon compounds and a method of producing the same are disclosed which have functional groups selected from either or both of mercaptan or --CHR.sup.1 .dbd.CR.sup.1 H joined to a silicon atom through a thioether linkage. Further disclosed are radiation curable compositions containing the radiation active silicon compounds.
摘要翻译：公开了辐射活性硅化合物及其制备方法，其具有通过硫醚键连接到硅原子上的硫醇或-CHR1 = CR1H中的任一个或两者的官能团。还公开了含有辐射活性硅化合物的可辐射固化组合物。

2. 发明授权

US5091440A Acrylate- or methacrylate-functional organopolysiloxanes 失效
标题翻译：丙烯酸酯或甲基丙烯酸酯官能的有机聚硅氧烷
公开(公告)号：US5091440A
公开(公告)日：1992-02-25
申请号：US447758
申请日：1989-12-08
申请人： Roy M. Griswold
发明人： Roy M. Griswold
IPC分类号： C07F7/08 , C08F2/46 , C08F299/08 , C08G77/04 , C08G77/392 , C09D11/10 , C09D183/08
CPC分类号： C09D11/101 , C07F7/0856 , C08F299/08 , C08G77/045 , C08G77/392 , C09D183/08
摘要： Radiation polymerizable acrylate- or methacrylate-functional organo-polysiloxanes having the structural formula ##STR1## wherein R is a radical selected from the group consisting of monovalent hydrocarbon radicals having from 1 to 20 carbon atoms, substituted monovalent hydrocarbon radicals having from 1 to 20 carbon atoms, monovalent hydrocarbonoxy radicals having from 1 to 20 carbon atoms and a radical of the formula: ##STR2## in which at least one R is a radical of formula (I), R.sup.1 is hydrogen or a methyl radical, R.sup.2 is selected from the group consisting of a multivalent hydrocarbonoxy radical and a multivalent hydrocarbonoxy radical containing non-terminal atoms selected from the group consisting of oxygen, sulphur and nitrogen atoms, R.sup.3 is a divalent hydrocarbon radical or a divalent hydrocarbonoxy radical, a is a number having an average value of from 0.7 to 2.6, b is a number of from 1 to 5, and x is a number from 2 to 1000.The acrylate- or methacrylate-functional organopolysiloxanes are combined with a photosensitizer and/or a peroxide and cured by radiation and/or heat. High energy electrons may be used in lieu of a photosensitizer or peroxide to cure these compositions.
摘要翻译：具有结构式“IMAGE”的可辐射聚合的丙烯酸酯或甲基丙烯酸酯官能的有机聚硅氧烷，其中R是选自具有1至20个碳原子的一价烃基，具有1至20个碳的取代的一价烃基原子，具有1至20个碳原子的单价烃氧基和下式的基团：其中至少一个R是式（I）的基团，R 1是氢或甲基，R 2是选自含有选自氧，硫和氮原子的非末端原子的多价烃氧基和多价烃氧基，R3是二价烃基或二价烃氧基，a是具有平均值为0.7至2.6，b为1至5的数，x为2至1000的数。丙烯酸酯或甲基丙烯酸酯官能的有机聚硅氧烷洛索与光敏剂和/或过氧化物结合，并通过辐射和/或加热固化。可以使用高能电子代替光敏剂或过氧化物来固化这些组合物。

3. 再颁专利

USRE30554E Coordination complexes as catalysts 失效
标题翻译：配位络合物作为催化剂
公开(公告)号：USRE30554E
公开(公告)日：1981-03-24
申请号：US47350
申请日：1979-06-11
申请人： Kurt Weinberg , Gordon C. Johnson
发明人： Kurt Weinberg , Gordon C. Johnson
IPC分类号： C07F7/00 , C07F7/08 , C07F7/18 , C07F7/21 , C07F9/02 , C08G63/181 , C08G63/82
CPC分类号： C07F9/02 , C07F7/003 , C07F7/0856 , C07F7/18 , C07F7/182 , C07F7/21 , C08G63/181 , C08G63/82
摘要： A process for producing polyesters and copolyesters, useful for making films and fibers, by the polycondensation of dicarboxylic acids and aliphatic glycols using coordinations complexes of metal halides and silicon compounds as catalysts.

4. 发明授权

US4100172A Sulfur containing norbornanyl silicon compounds 失效
标题翻译：含硫降冰片烷基硅化合物
公开(公告)号：US4100172A
公开(公告)日：1978-07-11
申请号：US694028
申请日：1976-06-07
申请人： Jeffrey Y. P. Mui , Bernard Kanner
发明人： Jeffrey Y. P. Mui , Bernard Kanner
IPC分类号： C07F7/08 , C07F7/18
CPC分类号： C07F7/1836 , C07F7/0856
摘要： The invention relates to novel sulfur substituted norbornyl silicon compounds. Illustrated are trithianyl, dimercapto and mono-mercapto substituted norbornylsilicon compounds.
摘要翻译：本发明涉及新的硫取代的降冰片基硅化合物。示出了三噻烷基，二巯基和单巯基取代的降冰片基硅氧烷化合物。

5. 发明授权

US4093642A Surface active silicones 失效
标题翻译：表面活性硅酮
公开(公告)号：US4093642A
公开(公告)日：1978-06-06
申请号：US752879
申请日：1976-12-20
申请人： Curtis L. Schilling , Bela Prokai , Bernard Kanner
发明人： Curtis L. Schilling , Bela Prokai , Bernard Kanner
IPC分类号： C07F7/08 , C08G77/04 , C08G77/382 , C07F7/10
CPC分类号： C08G77/045 , C07F7/0856 , C08G77/382
摘要： This invention relates to ion-pair-containing siloxane compounds that are extremely effective as surface tension depressants. The compounds of the present invention contain both anionic and cationic substituents and can be formed by metathesis reactions between metallic salts of anionic silicone or organic surface-active compounds and halide salts of quaternary ammonium silicone or organic surface-active compounds. The compounds of the invention are relatively pH insensitive when compared to siloxanes bearing anionic and cationic substituents that are formed by proton transfer. Thus, the organosilicon compounds of the invention will remain stable despite changes in pH of the mixture in which they are present.
摘要翻译：本发明涉及作为表面张力抑制剂非常有效的含离子对的硅氧烷化合物。本发明的化合物含有阴离子和阳离子取代基，并且可以通过阴离子硅氧烷或有机表面活性化合物的金属盐和季铵硅氧烷或有机表面活性化合物的卤化物盐之间的复分解反应形成。当与通过质子转移形成的阴离子和阳离子取代基的硅氧烷相比时，本发明的化合物相对pH不敏感。因此，本发明的有机硅化合物将保持稳定，尽管它们存在的混合物的pH变化。

6. 发明授权

US3794672A Perfluoroalkyl silicon compounds containing sulfur 失效
标题翻译：全氟硅烷化合物含硫磺
公开(公告)号：US3794672A
公开(公告)日：1974-02-26
申请号：US3794672D
申请日：1973-07-05
申请人： DOW CORNING
发明人： KIM Y
IPC分类号： C07F7/08 , C07F7/18 , C07F7/21 , C08G77/28 , C08G77/392
CPC分类号： C07F7/0856 , C07F7/0858 , C07F7/0874 , C07F7/0889 , C07F7/182 , C07F7/21 , C08G77/28 , C08G77/392
摘要： PERFLUOROALKYL SILYL SULFIDES ARE PREPARED BY REACTING RFCH=CH2 WITH HSRSI= IN THE PRESENCE OF A FREE RADICAL GENERATOR SUCH AS ORGANIC PEROXIDES. THE PRODUCTS ARE USEFUL FOR TREATING FABRICS TO RENDER THEM OLEOPHOBIC AND WATER REPELLENT FOR EXAMPLE TRIFLUOROPROPENE IS ADDED TO MERCAPTOPROPLYTRIMETHOXYSILANE TO GIVE

CF3CH2CH2S(CH2)3CIO1.5

THIS CAN BE HYDROLYZEDTO THE SILOXANE.

CF3CH2CH4S(CH2)3SI(OCH3)3

7. 发明授权

US3715370A Xanthenyl ketone containing organosilicon materials 失效
标题翻译：含有有机硅材料的XANTHENYL KETONE
公开(公告)号：US3715370A
公开(公告)日：1973-02-06
申请号：US3715370D
申请日：1970-07-20
申请人： GEN ELECTRIC
发明人： WILKUS E , BERGER A
IPC分类号： A61K8/893 , A61K8/898 , A61K8/899 , A61Q13/00 , A61Q19/00 , C07F7/08 , C08G77/14 , C08G77/24 , C08G77/28 , C07D5/16 , C07D7/42 , C07D63/12
CPC分类号： A61K8/893 , A61K8/898 , A61K8/899 , A61Q13/00 , A61Q19/00 , C07F7/0812 , C07F7/0818 , C07F7/0852 , C07F7/0856 , C08G77/14 , C08G77/24 , C08G77/28
摘要： One class of organosilicon materials are provided having chemically combined UNITS, WHERE R'''' is a divalent hydrocarbon radical and 2 is a radical selected from aryloxyaryl, arylthioaryl, arylsulfonylaryl, and certain heteroaromatic radicals. In addition, organosilicon polymers and copolymers are provided having chemically combined UNITS, WHERE 2'' IS A RADICAL SELECTED FROM 2 RADICALS, MONOVALENT AROMATIC HYDROCARBON RADICALS AND HALOGENATED MONOVALENT AROMATIC HYDROCARBON RADICALS. The monomers and polymers can be employed as perfume oil bases, in cosmetics and as fluids in the manufacture of elastomers and resins.
摘要翻译：提供一类有机硅材料，其具有化学结合的UNITS，其中R“是二价烃基，2是选自芳氧基芳基，芳硫基芳基，芳基磺酰基芳基和某些杂芳族基团的基团。此外，提供了具有化学组合单元的有机硅聚合物和共聚物，其中2'是从2个辐射，单个芳族烃类放射性和氢化单一芳族烃类放射性物质选择的辐射。单体和聚合物可用作香料油基料，在化妆品中以及作为制备弹性体和树脂的流体。

8. 发明授权

US3707492A Silicone sulfates 失效
标题翻译：硅胶硫酸盐
公开(公告)号：US3707492A
公开(公告)日：1972-12-26
申请号：US3707492D
申请日：1970-04-06
申请人： UNION CARBIDE CORP
发明人： MOREHOUSE EDWARD L
IPC分类号： C07F7/08 , C08G77/04 , C07F7/10
CPC分类号： C07F7/0856 , C08G77/045 , C10M2201/02 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2207/04 , C10M2211/022 , C10M2211/06 , C10M2219/042 , C10M2219/044 , C10M2227/04 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , Y10S516/03 , Y10S516/05
摘要： SILOXANES CONTAINING AT LEAST 1 MOLE PERCENT OF A SULFATOORGANOXYALKYSILOXY UNIT ARE DISCLOSED. THE SILOXANES ARE USEFUL AS SURFACTANTS. A TYPICAL COMPOUND DISCLOSED IS

ME3SIO(ME-SIO)9(NH4O3SOCH2)2

C(C2H5)CH2-OC3H6SIMEO)5.6

(CH3(OC2H4)7OC3H6SIMEO)5.6SIME3

9. 发明授权

US3418352A Organosilicon compounds and process for their preparation 失效
标题翻译：有机硅化合物及其制备方法
公开(公告)号：US3418352A
公开(公告)日：1968-12-24
申请号：US38452564
申请日：1964-07-22
申请人： GOLDSCHMIDT AG TH
发明人： GERD ROSSMY
IPC分类号： C07F7/08 , C08G77/00 , C08G77/48 , C09K3/16
CPC分类号： C09K3/16 , C07F7/0856 , C07F7/0874 , C07F7/0889 , C08G77/00 , C08G77/48
摘要： The invention comprises sulphate-containing siloxanes of the formulae wherein R1 is Cl-6 alkyl radical or trialkylsilyl radical, at least 50% of R1 consisting of the latter, R is a monovalent hydrocarbon or halohydrocarbon radical, M is an alkylene radical which bridges the silicon and oxygen atoms through at least three carbon atoms, each X is a hydrogen atom, or one equivalent of a metal or NHR13, wherein R1 is a hydrogen atom or a hydrocarbon or substituted hydrocarbon radical; and x=0 to 1, y=2 to 3, z=1 to 10 and x+y=3. R is preferably an C1- 4 alkyl radical, and M is preferably (CH2)3 or (CH2)4. Specified X radicals are Na, K, Ca, Al, Zr and those derived from ammonia, hydrazine, amines, polyamines, alkanol amines, heterocyclic amines and quaternary ammonium compounds; many examples are given. Compounds of Formulae (I) and (II) are prepared by reacting an organo - silicon compound RxYySi(MOCOR)4-(x+y)with chlorosulphonic acid yielding a compound of the unit formula this is reacted with a hexa-alkyl disiloxane, R3SiOSiR3, and the R3SiY produced distilled off yielding SiRx(R3SiO)y(MO-SO2.OSiR3) which is further heated giving compounds of Formula (II). The products are subjected to hydrolysis or alcoholysis optionally followed by neutralization. A typical Example (1) describes the preparation of and the disiloxane obtained by replacing one (CH3)Si group by C2H5. Uses.-In lacquers and varnishes as spreading agents, antistatic agents, preventing glass fogging, wetting agent, in polyurethane foams, glass fibre finishing agents.

10. 发明授权

US3391109A Aryl ketone containing organosilicon materials 失效
标题翻译：含有有机硅材料的芳基酮
公开(公告)号：US3391109A
公开(公告)日：1968-07-02
申请号：US59111866
申请日：1966-11-01
申请人： GEN ELECTRIC
发明人： WILKUS EDWARD V , ABE BERGER
IPC分类号： A61K8/893 , A61Q13/00 , A61Q19/00 , C07F7/08 , C07F7/12 , C08G77/14 , C08G77/22
CPC分类号： C08G77/22 , A61K8/893 , A61Q13/00 , A61Q19/00 , C07F7/0812 , C07F7/0818 , C07F7/0836 , C07F7/0856 , C07F7/12 , C08G77/14

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