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1. 发明授权

US08367858B2 Terephthalic and trimellitic based acids and carboxylate derivatives thereof 失效
标题翻译：对苯二酸和偏苯三酸类的酸及其羧酸衍生物
公开(公告)号：US08367858B2
公开(公告)日：2013-02-05
申请号：US12816763
申请日：2010-06-16
申请人： John W. Frost , Adeline Miermont , Dirk Schweitzer , Vu Bui , Douglas A. Wicks
发明人： John W. Frost , Adeline Miermont , Dirk Schweitzer , Vu Bui , Douglas A. Wicks
IPC分类号： C07C67/04 , C07C63/26
CPC分类号： C07D307/89 , C07B2200/09 , C07C51/353 , C07C67/08 , C07C67/303 , C07C67/317 , C07C67/333 , C07C67/347 , C07C69/75 , C07C2601/14 , C07C2601/16 , C08G63/183 , C07C57/16 , C07C69/602 , C07C69/76 , C07C69/82 , C07C61/22
摘要： The present invention relates to novel substituted and unsubstituted terephthalic acid and carboxylate derivatives and products prepared therefrom having a significant renewable content. The invention also relates to processes for preparing substituted and unsubstituted terephthalic and carboxylate derivatives thereof wherein a portion of the starting materials utilized is derived from renewable resources. The invention also relates to novel cyclohexene based intermediates prepared in these processes and to conversion of these intermediates to substituted and unsubstituted cyclohexane-1,4-dicarboxylates and carboxylate derivatives thereof and novel forms of the resulting products having renewable content. The invention also relates to products prepared from substituted and unsubstituted terephthalic acid and carboxylate derivatives thereof derived from starting materials derived from renewable resources.
摘要翻译：本发明涉及新的取代和未取代的对苯二甲酸和羧酸酯衍生物以及由其制备的具有显着可再生含量的产物。本发明还涉及制备取代和未取代的对苯二甲酸和羧酸酯衍生物的方法，其中所用起始物质的一部分来自可再生资源。本发明还涉及在这些方法中制备的新型环己烯基中间体以及将这些中间体转化为取代和未取代的环己烷-1,4-二羧酸酯及其羧酸酯衍生物以及具有可再生含量的所得产物的新型形式。本发明还涉及由衍生自可再生资源的起始原料的取代和未取代的对苯二甲酸及其羧酸衍生物制备的产品。

2. 发明申请

US20120107886A1 Lignin Oxidation and Products Thereof 审中-公开
标题翻译：木质素氧化及其制品
公开(公告)号：US20120107886A1
公开(公告)日：2012-05-03
申请号：US13375193
申请日：2010-06-01
申请人： Kim Albizati , Cara Tracewell
发明人： Kim Albizati , Cara Tracewell
IPC分类号： C07C51/285 , C12P7/42 , C07C51/21
CPC分类号： C12P7/22 , C07C37/00 , C07C37/055 , C07C51/255 , C07C51/313 , C07C51/353 , C07C51/36 , C07C209/68 , C07C213/00 , C07C227/08 , C12P7/18 , C12P7/42 , C12P7/44 , C07C65/21 , C07C39/08 , C07C39/04 , C07C57/16 , C07C55/14 , C07C57/04 , C07C229/60 , C07C215/76 , C07C211/46 , C07C229/64 , C07C211/51
摘要： Provided herein is a method of oxidizing lignin. Further disclosed herein are aromatic and non-aromatic compounds obtained from oxidized lignin.
摘要翻译：本文提供氧化木质素的方法。本文进一步公开的是由氧化木质素获得的芳族和非芳族化合物。

3. 发明授权

US3143408A Pesticidal compound 失效
标题翻译：杀虫剂
公开(公告)号：US3143408A
公开(公告)日：1964-08-04
申请号：US25430463
申请日：1963-01-28
申请人： ROHM & HAAS
发明人： SMYTHE CARL V , KRASKIN KENNETH S
IPC分类号： C07C57/03 , C07C57/16
CPC分类号： C07C57/03 , C07C57/16

4. 发明授权

US09957218B2 Isomerization of muconic acid 有权
公开(公告)号：US09957218B2
公开(公告)日：2018-05-01
申请号：US15347985
申请日：2016-11-10
申请人： Iowa State University Research Foundation, Inc.
发明人： Jean-Philippe Tessonnier , Jack M. Carraher , Toni Pfennig , Brent Shanks
IPC分类号： C07C51/353 , C07D493/04
CPC分类号： C07C51/353 , C07B2200/09 , C07D493/04 , C07C57/16
摘要： Various embodiments disclosed relate to isomerization of muconic acid. In various embodiments, the present invention provides a method of forming trans,trans-muconic acid. The method includes heating a starting material composition to form a product composition including trans,trans-muconic acid. The starting material composition includes cis,cis-muconic acid, cis,trans-muconic acid, or a combination thereof. The starting material composition also includes an electrophilic compound, an organic solvent, or a combination thereof.

5. 发明申请

US20170001944A1 CHEMICAL PROCESS TO CONVERT MUCIC ACID TO ADIPIC ACID 审中-公开
标题翻译：化学过程将酸性转化成酸性
公开(公告)号：US20170001944A1
公开(公告)日：2017-01-05
申请号：US15102264
申请日：2014-12-04
申请人： AGENCY FOR SCIENCE TECHNOLOGY AND RESEARCH
发明人： Yugen ZHANG , Xiukai Li
IPC分类号： C07C69/44 , C07C67/08 , C07C51/377
CPC分类号： C07C69/44 , C07C51/09 , C07C51/36 , C07C51/377 , C07C67/08 , C07C67/303 , C07C69/602 , C07C55/14 , C07C57/16
摘要： The present invention provides a method of synthesizing an ester of a saturated carboxylic acid from a saturated polyhydroxycarboxylic acid by performing a deoxydehydration reaction and a hydrogen transfer reaction.
摘要翻译：本发明提供了通过进行脱氧水解反应和氢转移反应从饱和的聚羟基羧酸合成饱和羧酸的酯的方法。

6. 发明申请

US20060122425A1 Method for the production of a dicarboxylic acid from acrylic acid 审中-公开
标题翻译：从丙烯酸生产二羧酸的方法
公开(公告)号：US20060122425A1
公开(公告)日：2006-06-08
申请号：US10519523
申请日：2003-07-04
申请人： Peter Bassler , Stefan Maixner , Jens Scheidel
发明人： Peter Bassler , Stefan Maixner , Jens Scheidel
IPC分类号： C07C51/347
CPC分类号： C07C67/303 , C07C51/09 , C07C51/36 , C07C67/10 , C07C67/347 , C07C55/14 , C07C57/16 , C07C57/13 , C07C69/54 , C07C69/44 , C07C69/593
摘要： A process for the preparation of a dicarboxylic acid of the formula (I) —H—OOC-(n-C4Hx)—COO—H (I)where x is 6 or 8, starting from acrylic acid, which comprises a) reacting a dicarboxylic acid diester of the formula (II) R1—OOC-(n-C4Hx)—COO—R2 (II)where x is 6 or 8, and R1 and R2, independently of one another, are C1-, C2-, C3- or C4-alkyl, aryl or heteroaryl and may be identical to or different from one another, with acrylic acid to give a dicarboxylic acid of the formula (I) and a mixture of acrylic acid esters of the formulae C2H3—COOR1 and C2H3—COOR2, where R1 and R2 are as defined above, b) separating the dicarboxylic acid of the formula (I) obtained in step a) from the reaction mixture obtained in step a), c) dimerizing the C2H3—COOR1, C2H3—COOR2 or mixture thereof obtained in step a) to give an n-butenedicarboxylic acid diester, and d) cleaving the dicarboxylic acid diester obtained in step c) into the corresponding dicarboxylic acid of the formula (I).
摘要翻译：制备式（I）的二羧酸的方法<？in-line-formula description =“In-line Formulas”end =“lead”→H-OOC-（nC 4）＆lt;＆lt; x＆gt; x） - COO-H（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中x是6或8，从丙烯酸，其包括：a）使式（II）的二羧酸二酯与式（II）中的<？in-line-formula description =“In-line Formulas”end =“lead”→R＆ OOC-（nC 4 H x） - COO-R 2（II）<？在线公式描述=“在线式“end =”tail“？>其中x为6或8，R 1和R 2彼此独立地为C 1〜 C 1 -C 3 - ，C 3 - 或C 4 - 烷基，芳基或杂芳基，并且可以相同或不同另一个与丙烯酸反应，得到式（I）的二羧酸和式C 2 H 3 -COOR 1的丙烯酸酯的混合物＆lt; 2＆gt;和＆lt; 2＆gt;＆lt; 3＆lt; 3＆gt; 其中R 1和R 2如上所定义，b）将步骤a）中获得的式（I）的二羧酸与在步骤a）中获得的反应混合物，c）使C 2 H 3 -NOROR 1，C 2 H 2， H 3 -COOR 2或其步骤a）中获得的混合物，得到正丁二酸二酯，和d）将步骤c）中得到的二羧酸二酯切割成相应的式（I）的二羧酸。

7. 发明授权

US10017792B2 Biomass conversion to fuels and chemicals 有权
公开(公告)号：US10017792B2
公开(公告)日：2018-07-10
申请号：US14804161
申请日：2015-07-20
申请人： Alliance for Sustainable Energy, LLC
发明人： Gregg T. Beckham , Christopher W. Johnson , Derek R. Vardon , Mary Ann Franden
IPC分类号： C12P7/44 , C07C51/47 , C07C51/43 , C07C51/36 , C12N9/88
CPC分类号： C12P7/44 , C07C51/36 , C07C51/43 , C07C51/47 , C12N9/88 , C12Y113/11001 , C12Y401/01063 , C12Y402/01118 , C07C55/14 , C07C57/16
摘要： This disclosure relates to compositions and methods for converting biomass to various chemical intermediates and final products including fuels. Aspects include the depolymerization of lignin, cellulose, and hemicellulose to a wide slate of depolymerization compounds that can be subsequently metabolized by genetically modified bacterium, and converted to cis,cis-muconic acid. Other aspects include the use of monometallic catalysts for converting the cis,cis-muconic acid to commodity chemicals and fuels, for example adipic acid and/or nylon.

8. 发明申请

US20160017381A1 BIOMASS CONVERSION TO FUELS AND CHEMICALS 有权
标题翻译：生物质转化为燃料和化学品
公开(公告)号：US20160017381A1
公开(公告)日：2016-01-21
申请号：US14804161
申请日：2015-07-20
申请人： Alliance for Sustainable Energy, LLC
发明人： Gregg T. Beckham , Christopher W. Johnson , Derek R. Vardon , Mary Ann FRANDEN
IPC分类号： C12P7/44 , C12N9/88 , C07C51/36 , C07C51/47 , C07C51/43
CPC分类号： C12P7/44 , C07C51/36 , C07C51/43 , C07C51/47 , C12N9/88 , C12Y113/11001 , C12Y401/01063 , C12Y402/01118 , C07C55/14 , C07C57/16
摘要： This disclosure relates to compositions and methods for converting biomass to various chemical intermediates and final products including fuels. Aspects include the depolymerization of lignin, cellulose, and hemicellulose to a wide slate of depolymerization compounds that can be subsequently metabolized by genetically modified bacterium, and converted to cis,cis-muconic acid. Other aspects include the use of monometallic catalysts for converting the cis,cis-muconic acid to commodity chemicals and fuels, for example adipic acid and/or nylon.
摘要翻译：本公开涉及将生物质转化为各种化学中间体和包括燃料在内的最终产物的组合物和方法。方面包括将木质素，纤维素和半纤维素解聚成广泛的解聚化合物，其随后可以被遗传修饰的细菌代谢，并转化为顺式，顺式 - 粘酸。其它方面包括使用单金属催化剂将顺式，顺式 - 粘康酸转化为商品化学品和燃料，例如己二酸和/或尼龙。

9. 发明授权

US08426639B2 Preparation of trans, trans muconic acid and trans, trans muconates 有权
标题翻译：反式，反式粘康酸和反式反式粘蛋白的制备
公开(公告)号：US08426639B2
公开(公告)日：2013-04-23
申请号：US12816481
申请日：2010-06-16
申请人： John W. Frost , Adeline Miermont , Dirk Schweitzer , Vu Bui
发明人： John W. Frost , Adeline Miermont , Dirk Schweitzer , Vu Bui
IPC分类号： C07C51/00 , C07C69/66 , C07C69/52
CPC分类号： C08G63/183 , C07B2200/09 , C07C51/353 , C07C67/303 , C07C67/317 , C07C67/333 , C07C67/347 , C07C2601/14 , C07C2601/16 , C07D307/89 , C07C57/16 , C07C67/08 , C07C69/602 , C07C69/75 , C07C69/76 , C07C69/82
摘要： The present invention relates to the isomerization of cis,cis and/or cis,trans muconic acid or esters thereof to trans,trans muconic acid or esters thereof and to the esterification of such muconic acids.
摘要翻译：本发明涉及顺式，顺式和/或顺式，反式粘康酸或其酯与反式，反式粘康酸或其酯的异构化以及这种粘酸的酯化反应。

10. 发明授权

US08415496B2 Biobased polyesters 失效
标题翻译：生物基聚酯
公开(公告)号：US08415496B2
公开(公告)日：2013-04-09
申请号：US12816701
申请日：2010-06-16
申请人： John W. Frost , Adeline Miermont , Dirk Schweitzer , Vu Bui , Edward Paschke , Douglas A. Wicks
发明人： John W. Frost , Adeline Miermont , Dirk Schweitzer , Vu Bui , Edward Paschke , Douglas A. Wicks
IPC分类号： C07C69/76 , C07C63/00 , C08G63/02
CPC分类号： C07C67/347 , C07B2200/09 , C07C51/353 , C07C67/303 , C07C67/317 , C07C67/333 , C07C2601/14 , C07C2601/16 , C07D307/89 , C08G63/183 , C07C61/22 , C07C57/16 , C07C67/08 , C07C69/602 , C07C69/75 , C07C69/76 , C07C69/82
摘要： The present invention relates to polyesters prepared from benzene, cyclohexene and cyclohexane compounds having carboxylic acid groups at the 1 and 4, and optionally the 2, positions, such as terephthalic acid or dimethyl terephthalates, and alkylene glycols, such ethylene glycol or 1,4-butane diol. The invention also relates to processes for preparing such polyesters. The invention also relates to such polyesters derived from starting materials derived from renewable resources.
摘要翻译：本发明涉及由苯，环己烯和环己烷化合物制备的聚酯，所述聚合物在1和4以及任选的2位上具有羧酸基团，例如对苯二甲酸或对苯二甲酸二甲酯，以及亚烷基二醇，例如乙二醇或1,4 丁烷二醇。本发明还涉及制备这种聚酯的方法。本发明还涉及衍生自源自可再生资源的原料的这种聚酯。

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