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    • 2. 发明授权
    • Method of crystallizing aluminium sulphate solutions to form dust-free
granules having uniform grain size
    • 使硫酸铝溶液结晶以形成具有均匀晶粒尺寸的无尘颗粒的方法
    • US4276052A
    • 1981-06-30
    • US21205
    • 1979-03-16
    • Egon Boisen SchmidtJosef K. S. ZechnerGosta M. Frang
    • Egon Boisen SchmidtJosef K. S. ZechnerGosta M. Frang
    • B01D9/02C01F7/74
    • C01F7/746
    • A method of crystallizing a solution of aluminium sulphate to form crystal agglomerates having an essentially uniform grain size and being in the form of granules having a characteristic appearance and good storage properties. A solution having a temperature of 105.degree.-115.degree. C. and a concentration of 14.5-16.8% by weight of Al.sub.2 O.sub.3 is brought to crystallize onto a bed of crystalline aluminium sulphate in a drum, the length of which is considerably larger than the diameter, a temperature of 70.degree.-95.degree. C. being maintained in the bed. Part of the crystalline product discharged from the drum is ground and recycled to the drum in an amount of 40-200 percent by weight of added solution and air is passed through the drum to remove moisture evolved by the crystallization so as to form a final product with more than 75% by weight present in the crystalline state and containing 15.0-18.0% by weight of Al.sub.2 O.sub.3.
    • 一种使硫酸铝溶液结晶以形成具有基本均匀晶粒尺寸并且具有特征外观和良好储存性能的颗粒形式的结晶聚集体的方法。 将温度为105-115℃,浓度为14.5-16.8%(重量)的Al2O3的溶液在鼓中结晶的硫酸铝床上结晶,其长度远大于直径 在床中保持70〜-95℃的温度。 从滚筒中排出的部分结晶产物被研磨并循环到滚筒中,其量为加入的溶液的40-200重量%,空气通过滚筒以除去通过结晶放出的水分,从而形成最终产物 存在结晶状态的超过75重量%并含有15.0-18.0重量%的Al 2 O 3。
    • 7. 发明授权
    • Process for obtaining an aluminum sulfate hydrate from an impure
sulfuric acid solution of aluminum sulfate
    • 从硫酸铝的不纯硫酸溶液中获得硫酸铝水合物的方法
    • US4171205A
    • 1979-10-16
    • US973932
    • 1978-12-28
    • Jean M. LamerantJoseph CohenPierre Maurel
    • Jean M. LamerantJoseph CohenPierre Maurel
    • C01F7/74B01D9/02
    • C01F7/746
    • Process for recovering aluminum in the form of a specific acid sulfate from an initial solution containing aluminum in the form of dissolved aluminum sulfate hydrate in which the specific acid sulfate is of the formula Al.sub.2 (SO.sub.4).sub.3.0.5H.sub.2 SO.sub.4.11 to 12 H.sub.2 O and in which the initial solution is sequentially treated in a series of crystallizers, wherein successive crystallizers are maintained at a predetermined decreased generally fixed temperature such that in each crystallizer a state of supersaturation of aluminum acid sulfate exists and the parameters attendant operation of each crystallizer insure that a state of static equilibrium of precipitation of product is generally reached before the process solution/slurry is passed to a successive crystallizer, or filtered for recovery of product.
    • 从具有硫酸铝水合物形式的铝的初始溶液中回收特定酸式硫酸盐形式的铝的方法,其中特定酸式硫酸盐具有式Al 2(SO 4)3.0·5H 2 SO 4·11·12H 2 O和 其中初始溶液在一系列结晶器中连续处理,其中连续的结晶器保持在预定的降低的通常固定的温度,使得在每个结晶器中存在酸式硫酸铝的过饱和状态,并且每个结晶器的伴随操作的参数确保 通常在将工艺溶液/浆料通入连续结晶器之前通常达到产物沉淀的静态平衡状态,或过滤以回收产物。