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1. 发明授权

US3985794A Process for the production of vinyl acetate from ethylene 失效
标题翻译：从乙烯生产乙酸乙烯酯的方法
公开(公告)号：US3985794A
公开(公告)日：1976-10-12
申请号：US862914
申请日：1969-10-01
申请人： Benedetto Calcagno , Claudio Divo , Marcello Ghirga
发明人： Benedetto Calcagno , Claudio Divo , Marcello Ghirga
IPC分类号： B01J27/06 , B01J31/40 , C07C67/055 , C07C69/15 , C07C67/05
CPC分类号： B01J27/06 , B01J31/30 , B01J31/403 , B01J31/4038 , B01J31/4076 , C07C67/055 , B01J2231/70 , B01J31/04 , Y02P20/584
摘要： Palladium and copper ethylene-oxidation catalysts, used in production of vinyl acetate, are regenerated by a process including electrolytic deposition of the metals and subsequent reconversion to halides.
摘要翻译：用于生产乙酸乙烯酯的钯和铜乙烯氧化催化剂通过包括电解沉积金属并随后再转化成卤化物的方法再生。

2. 发明授权

US4196096A Process for regeneration of rhodium hydroformylation catalysts 失效
标题翻译：铑加氢甲酰化催化剂再生方法
公开(公告)号：US4196096A
公开(公告)日：1980-04-01
申请号：US11604
申请日：1979-02-12
申请人： John L. Dawes , Thomas J. Devon
发明人： John L. Dawes , Thomas J. Devon
IPC分类号： B01J31/40 , B01J38/68 , B01J38/70 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00 , B01J27/28
CPC分类号： B01J31/18 , B01J31/20 , B01J31/2404 , B01J31/4046 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J31/4076 , Y02P20/584
摘要： Rhodium hydroformylation catalysts are regenerated by a novel process which includes the steps of removing the catalyst to be regenerated from the hydroformylation reaction, adjusting the aldehyde contents of the catalyst containing stream so as to have at least one mole of aldehyde present per mole of rhodium and ligand present in the catalyst, treating the aldehyde containing catalyst stream with oxygen or oxygen containing gas at a temperature less than the boiling point of the aldehyde, removing any solid material formed during the oxidation and adjusting the ligand to rhodium ratio as required for use in the hydroformylation reaction.
摘要翻译：铑加氢甲酰化催化剂通过新方法再生，其包括以下步骤：从加氢甲酰化反应中除去待再生的催化剂，调节含催化剂流的醛含量，使其每摩尔铑具有至少1摩尔的醛，配体存在于催化剂中，在低于醛的沸点的温度下用含氧或含氧气体处理含醛的催化剂流，除去氧化期间形成的任何固体物质，并根据需要调整配体与铑的比例加氢甲酰化反应。

3. 发明授权

US5302257A Electrocatalytic asymmetric dihydroxylation of olefinic compounds 失效
标题翻译：烯烃化合物的电催化不对称二羟基化
公开(公告)号：US5302257A
公开(公告)日：1994-04-12
申请号：US839601
申请日：1992-02-21
申请人： Yun Gao , Charles M. Zepp
发明人： Yun Gao , Charles M. Zepp
IPC分类号： B01J31/16 , B01J31/18 , B01J31/40 , B01J37/34 , C07C29/03 , C07C29/48 , C07C31/20 , C07C31/42 , C07C33/18 , C07C33/20 , C07C33/26 , C07C33/30 , C07C45/51 , C07C49/497 , C07C49/82 , C07C67/31 , C07C69/732 , C25B3/02
CPC分类号： B01J31/183 , B01J31/16 , B01J31/4038 , B01J31/4061 , B01J31/4076 , B01J37/348 , C07C29/48 , B01J2531/825 , C07B2200/07 , C07C2102/10 , Y02P20/584
摘要： A process is disclosed in which optically active glycols are produced through an electrolytic asymmetric dihydroxylation (ADH) reaction involving olefins as substrates. The ADH reaction is mediated by a catalytically active amount of osmium tetroxide or osmium-containing precursor in a protic medium in the presence of chiral ligand. Any lower valent osmium species produced in the course of the ADH reaction is regenerated electrolytically either directly in the absence of a secondary oxidant or indirectly in the presence of a secondary oxidant that itself undergoes electrolytic regeneration.
摘要翻译：公开了一种方法，其中通过涉及烯烃作为底物的电解不对称二羟基化（ADH）反应制备光学活性二醇。在手性配体的存在下，质子介质中的ADH反应由催化活性量的四氧化锇或含锇前体介导。在ADH反应过程中产生的任何较低价锇物质都可以直接在不存在二次氧化剂的情况下电解再生，或间接地在本身进行电解再生的二次氧化剂存在下再生。

4. 发明申请

US20100087308A1 METHODS FOR CONVERSION OF METHANE TO USEFUL HYDROCARBONS, CATALYSTS FOR USE THEREIN, AND REGENERATION OF THE CATALYSTS 审中-公开
标题翻译：用于甲烷转化为有用的烃类的方法，其使用的催化剂和催化剂的再生
公开(公告)号：US20100087308A1
公开(公告)日：2010-04-08
申请号：US12442223
申请日：2007-09-14
申请人： Joe D. Sauer , Tyson J. Hall , George Wyndham Cook , Joseph E. Coury
发明人： Joe D. Sauer , Tyson J. Hall , George Wyndham Cook , Joseph E. Coury
IPC分类号： B01J38/00
CPC分类号： B01J31/4015 , B01J27/32 , B01J31/121 , B01J31/143 , B01J31/4076 , B01J2231/46 , B01J2531/0216
摘要： Methods are provided for regenerating catalyst compositions useful in processes for converting methane to useful hydrocarbons. The methods comprise applying voltage across the catalyst compositions.
摘要翻译：提供了用于再生用于将甲烷转化为有用的烃的方法中的催化剂组合物的方法。所述方法包括在催化剂组合物上施加电压。

5. 发明授权

US5419817A Electrocatalytic asymmetric dihydroxylation of olefinic compounds 失效
标题翻译：烯烃化合物的电催化不对称二羟基化
公开(公告)号：US5419817A
公开(公告)日：1995-05-30
申请号：US182919
申请日：1994-01-18
申请人： Yun Gao , Charles M. Zepp
发明人： Yun Gao , Charles M. Zepp
IPC分类号： B01J31/16 , B01J31/18 , B01J31/40 , B01J37/34 , C07C29/03 , C07C29/48 , C07C31/20 , C07C31/42 , C07C33/18 , C07C33/20 , C07C33/26 , C07C33/30 , C07C45/51 , C07C49/497 , C07C49/82 , C07C67/31 , C07C69/732 , C25B3/02
CPC分类号： B01J31/183 , B01J31/16 , B01J31/4038 , B01J31/4061 , B01J31/4076 , B01J37/348 , C07C29/48 , B01J2531/825 , C07B2200/07 , C07C2102/10 , Y02P20/584
摘要： A process is disclosed in which optically active glycols are produced through an electrolytic asymmetric dihydroxylation (ADH) reaction involving olefins as substrates. The ADH reaction is mediated by a catalytically active amount of osmium tetroxide or osmium-containing precursor in a protic medium in the presence of chiral ligand. Any lower valent osmium species produced in the course of the ADH reaction is regenerated electrolytically either directly in the absence of a secondary oxidant or indirectly in the presence of a secondary oxidant that itself undergoes electrolytic regeneration.
摘要翻译：公开了一种方法，其中通过涉及烯烃作为底物的电解不对称二羟基化（ADH）反应制备光学活性二醇。在手性配体的存在下，质子介质中的ADH反应由催化活性量的四氧化锇或含锇前体介导。在ADH反应过程中产生的任何较低价锇物质都可以直接在不存在二次氧化剂的情况下电解再生，或间接地在本身进行电解再生的二次氧化剂存在下再生。

6. 发明授权

US5232559A Separation of molybdenum 失效
标题翻译：分离钼
公开(公告)号：US5232559A
公开(公告)日：1993-08-03
申请号：US793902
申请日：1991-11-18
申请人： William A. Smith , David L. Miller , Robert A. Meyer
发明人： William A. Smith , David L. Miller , Robert A. Meyer
IPC分类号： B01J31/40 , B01J37/34 , B01J38/48 , B01J38/68 , C25C1/22
CPC分类号： B01J31/0201 , B01J31/0202 , B01J31/0239 , B01J31/34 , B01J31/4015 , B01J31/4076 , B01J37/348 , B01J38/48 , B01J38/68 , C25C1/22 , B01J2231/72
摘要： An organic solution of a soluble molybdenum compound is ammonated with ammonia, ammonium hydroxide and/or an ammonium salt in order to significantly reduce the electrical resistance of the solution and a direct electric current is passed therethrough in order to collect a significant amount of the molybdenum in solid form at the negative electrode. Preferably, an epoxidation reaction product formed by the molybdenum catalyzed reaction of propylene with tertiary butyl hydroperoxide to provide propylene oxide and tertiary butyl alcohol is separated by distillation into a propylene fraction, a propylene oxide fraction, a tertiary butyl alcohol fraction and a heavy liquid distillation fraction containing substantially all of the dissolved molybdenum catalyst, the heavy liquid distillation fraction is saturated with ammonia to precipitate the molybdenum therefrom, the precipitated molybdenum is removed from the ammonated heavy distillation fraction and a direct electric current is passed through the remaining liquid portion of the ammonated fraction in an electrolytic cell in order to collect a significant portion of the remaining molybdenum residually dissolved therein at the cathode.
摘要翻译：可溶性钼化合物的有机溶液用氨，氢氧化铵和/或铵盐氨化，以显着降低溶液的电阻，并且直流电流通过其中以收集显着量的钼在固体形式的负极。优选地，通过丙烯与叔丁基过氧化氢的钼催化反应形成环氧丙烷和叔丁醇形成的环氧化反应产物通过蒸馏分离成丙烯馏分，环氧丙烷馏分，叔丁醇馏分和重液体蒸馏馏分含有基本上所有的溶解的钼催化剂，重液体蒸馏馏分用氨饱和，从中沉淀出钼，从氨化的重馏分中除去沉淀的钼，直流电流通过在电解池中的氨化部分，以便在阴极收集残留的钼的很大部分。

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