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    • 10. 发明申请
    • Process for the Production of Acetic Acid
    • 醋酸生产工艺
    • US20100228051A1
    • 2010-09-09
    • US12225244
    • 2007-03-16
    • Lesley Ann KeyAndrew David Poole
    • Lesley Ann KeyAndrew David Poole
    • C07C51/12
    • B01J19/128B01J19/002B01J2219/00051B01J2219/00162B01J2219/00175B01J2219/00186B01J2219/00195B01J2219/00213B01J2219/00229B01J2219/00252C07C51/12C07C53/08
    • A process for the production of acetic acid which process comprises carbonylating methanol and/or a reactive derivative thereof in a liquid reaction composition in which there exists in equilibrium, at least a first soluble catalytic species and a second soluble catalytic species, wherein the first catalytic species is the least catalytically active or promotionally active of the species existing in the equilibrium, comprises determining (i) the concentration of the first catalytic species and/or (ii) the ratio of the concentration of the first catalytic species to the concentration of the second catalytic species in equilibrium therewith, present in the liquid reaction composition and/or a present in a liquid fraction in a separation step and maintaining (i) and/or (ii) below a pre-determined value, preferably by adjusting the concentration of at least the first catalytic species present in the liquid reaction composition and/or liquid fraction.
    • 一种生产乙酸的方法,该方法包括在平衡存在的液体反应组合物中羰基化甲醇和/或其活性衍生物,至少第一可溶性催化物质和第二可溶性催化物质,其中第一催化剂 物种是存在于平衡中的物质的催化活性或促进活性最低的物质,包括确定(i)第一催化物质的浓度和/或(ii)第一催化物质的浓度与第一催化物质的浓度之比 存在于液体反应组合物中的第二催化物质和/或在分离步骤中存在于液体馏分中,并且将(i)和/或(ii)维持在预定值以下,优选通过调节浓度 至少第一催化物质存在于液体反应组合物和/或液体馏分中。