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    • 3. 发明授权
    • Multi-step chemical and radiation process
    • 多步化学和辐射过程
    • US4140601A
    • 1979-02-20
    • US667610
    • 1976-03-16
    • Henry J. Gomberg
    • Henry J. Gomberg
    • B01J19/08B01J19/12C01B3/06G21D9/00G21H5/00B01J1/10
    • G21D9/00B01J19/081C01B3/068Y02E60/36
    • A process which utilizes radiation energy, preferably that obtained from a fusion reaction and which includes selecting starting chemical materials having at least two molecules such as calcium bromide and water which contain as a part thereof a desired product H.sub.2, a by-product O.sub.2 and which chemically form an active material HBr that may be dissociated by radiation. A two step process permits the radiolytically dissociated Br to react with residual molecules to form and recycle the starting material CaBr.sub.2. A combination of thermochemical and radiolytic reactions such as available in nuclear reactions therefore produces a greater yield of a desired end product such as hydrogen, also producing a by-product such as oxygen from a low cost expendable source material such as water, and reforms the starting material. Also the process provides for convenient separation of the desired end products.
    • 一种利用辐射能的方法,其优选是由融合反应获得的,其中包括选择具有至少两个分子的起始化学物质,例如溴化钙和水,其含有一部分所需的产物H 2,副产物O 2和 化学形成可能被辐射离解的活性物质HBr。 两步法允许放射分解的Br与残留的分子反应以形成和再循环起始材料CaBr 2。 因此,诸如可用于核反应的热化学和放射反应的组合因此产生更高的期望的最终产物如氢气的产率,还从低成本的消耗性源材料例如水产生副产物如氧气,并且将 起始材料 此外,该方法提供了方便分离所需的最终产品。
    • 6. 发明授权
    • Pyrochemical processes for the decomposition of water
    • 用于水解的热化学工艺
    • US4368169A
    • 1983-01-11
    • US568661
    • 1975-04-16
    • Ralph H. KummlerCharles B. LeffertRobert G. OzarskiRobert A. PiccirelliTheodor Teichmann
    • Ralph H. KummlerCharles B. LeffertRobert G. OzarskiRobert A. PiccirelliTheodor Teichmann
    • C01B3/06G21B1/00
    • C01B3/068Y02E60/36
    • Improved closed-loop pyrochemical processes for the decomposition of water in which at least one of the reaction steps in each process is carried out pyrochemically within the central reaction chamber of a thermonuclear reactor during and immediately after a thermonuclear reaction, and in which one of the reagents in or products of the chamber reaction is a metal having a boiling temperature which is higher than the decomposition temperature of the associated metal oxide. The product of the pyrochemical reaction which includes the metal element is in the condensed phase after completion of the reaction and may thus be easily separated from the remaining gaseous reaction products.The specific reaction processes disclosed include a two-step process in which the metal is reacted directly with water within the reaction chamber, and a three-step process in which the metal is reacted with carbon dioxide within the central chamber, the reaction products being thereafter used in later process steps for the actual decomposition of water. In either process, the initial chamber reaction yields a condensed metal oxide product which is thereafter split in a later process step, which also takes place within a central fusion reaction chamber, to yield oxygen and a condensed metal product. Tungsten (W) and Tantalum (Ta) are disclosed as exemplary metal reagents.
    • 用于水分解的改进的闭环热化学方法,其中每个方法中的至少一个反应步骤在热核反应期间和之后立即在热核反应室的中心反应室内热化学地进行,其中 室反应物中的试剂或产物是具有比相关联的金属氧化物的分解温度高的沸点温度的金属。 包含金属元素的化学反应的产物在反应完成后处于冷凝相,因此可以容易地与剩余的气态反应产物分离。 所公开的具体反应方法包括其中金属与反应室内的水直接反应的两步法,以及其中金属与中心室内的二氧化碳反应的三步法,其后的反应产物 用于后续工艺步骤中的水分的实际分解。 在任一过程中,初始室反应产生冷凝的金属氧化物产物,其随后在后续工艺步骤中分离,其也在中心熔融反应室内进行,以产生氧和冷凝的金属产物。 公开了钨(W)和钽(Ta)作为示例性金属试剂。
    • 8. 发明授权
    • Pyrochemical processes for the decomposition of water
    • 用于水解的热化学工艺
    • US4362690A
    • 1982-12-07
    • US725339
    • 1976-09-21
    • Ralph H. KummlerRichard J. Leite
    • Ralph H. KummlerRichard J. Leite
    • C01B3/06G21B1/00
    • C01B3/068Y02E60/36
    • Improved closed-loop pyrochemical processes for the decomposition of water in which at least one reaction step in each process has a high energy requirement that may be expressed in standard Gibbs free energy change terms of more than 10 to 20 kcal/mole at 298.degree. K., .DELTA.G.sup.o.sub.f298. Such high energy steps are carried out in the central reaction chamber of a thermonuclear reactor wherein the energy of intense shock waves, hereinafter called the blast waves, caused by a pellet-by-pellet intermittent thermonuclear reaction provides an automatic drive for the process step kinetics. During the radial outward propagation of the blast wave reaction materials within the chamber are heated and compressed within the blast wave and entrained behind the blast wave. The product density immediately behind the blast wave remains directly proportional to the ambient density ahead of the wave. Chemical reaction thus takes place dynamically in transit at very high temperatures and pressures in a manner that permits the chemical reaction to absorb energy, and without confinement in a vessel requiring high pressure and high temperatures chronically. In this way, the process step having a high energy change requirement is accomplished in one high-energy reaction step rather than in several low and intermediate reaction steps having an energy sum which equals the required total.
    • 改进的用于水分解的闭环热化学方法,其中每个方法中的至少一个反应步骤具有高的能量需求,其可以在298℃下以10至20kcal /摩尔的标准吉布斯自由能变化项表示 。,DELTA Gof298。 这样的高能量步骤在热核反应堆的中心反应室中进行,其中由颗粒间歇式热核反应引起的强冲击波的能量(以下称为爆炸波)提供了工艺步骤动力学的自动驱动 。 在爆炸波的径向向外传播期间,室内的反应物质被加热并在波浪中被压缩并夹带在冲击波的后面。 冲击波后面的产品密度与波前的环境密度成正比。 因此,化学反应在非常高的温度和压力下,以允许化学反应吸收能量的方式在运输过程中动态地进行,并且不需要长时间地需要高压和高温的容器中。 以这种方式,具有高能量变化要求的工艺步骤在一个高能量反应步骤中完成,而不是在具有等于所需总量的能量和的几个低和中间反应步骤中完成。