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    • 4. 发明授权
    • Treatment of metal with derivative of poly-alkenylphenol
    • 用聚烯基酚衍生物处理金属
    • US4517028A
    • 1985-05-14
    • US490579
    • 1983-05-09
    • Andreas Lindert
    • Andreas Lindert
    • B05D3/10B05D7/14C09D5/08C09D5/12C09D125/00C09D125/04C23C22/78C23C22/83C23F11/173C23C1/10C09K3/00C23F5/02C23F11/00
    • C23C22/83B05D7/16C09D5/08B05D3/102
    • A metal surface is treated by contacting the surface with a solution comprising an effective amount of a soluble or dispersible treatment compound selected from the group consisting of a polymer having the following general formula, acid salts thereof, and mixtures thereof: ##STR1## where: R.sub.1 through R.sub.3 are hydrogen or an alkyl group having from 1 to about 5 carbon atoms;each Y is hydrogen, Z, CR.sub.4 R.sub.5 OR.sub.6, CH.sub.2 Cl, or an alkyl or aryl group having from 1 to 18 carbon atoms;Z is ##STR2## R.sub.4 through R.sub.10 are hydrogen, or an alkyl, aryl, hydroxy-alkyl, amino-alkyl, mercapto-alkyl or phospho-alkyl moiety, said R.sub.4 through R.sub.10 being of carbon chain lengths up to a length at which the compound is not soluble or dispersible; andn is from 2 up to a number at which the polymer is not soluble or dispersible.Preferably, the solution is an aqueous solution and "Z" moieties are present in sufficient amount that the compound is water soluble or water dispersible. Metal surfaces contacted with the solution have enhanced corrosion resistance and paint adhesion characteristics.
    • 通过使表面与包含有效量的可溶或可分散的处理化合物的溶液接触来处理金属表面,该化合物选自具有以下通式的聚合物,其酸式盐及其混合物:其中: R 1至R 3为氢或具有1至约5个碳原子的烷基; 每个Y是氢,Z,CR 4 R 5OR 6,CH 2 Cl或具有1至18个碳原子的烷基或芳基; Z是通过R 10的R 4是氢或烷基,芳基,羟基 - 烷基,氨基 - 烷基,巯基 - 烷基或磷酸 - 烷基部分,所述R4至R10的碳链长度直到 化合物不溶或可分散; 并且n为2以上,聚合物不溶于或不分散的数。 优选地,溶液是水溶液,“Z”部分以足够的量存在,使得化合物是水溶性的或水分散的。 与溶液接触的金属表面具有增强的耐腐蚀性和油漆附着特性。
    • 8. 发明授权
    • Alkaline resistant phosphate conversion coatings
    • 耐碱磷酸盐转化涂层
    • US4713121A
    • 1987-12-15
    • US5180
    • 1987-01-20
    • Ronald W. ZurillaJohn Huff
    • Ronald W. ZurillaJohn Huff
    • C23C22/12C23C2/06
    • C23C22/12
    • A method for increasing the resistance to alkaline dissolution of a phosphate conversion coating on a corrodible metal surface by an improved zinc phosphate conversion coating together with articles coated by this method are disclosed. The substrate is exposed to the phosphating solution by spraying or immersion to chemically effect a reaction with the substrate. First divalent metal cations are selected from magnesium and transition metals having a hydroxide with lower solubility in alkaline solution than zinc hydroxide. The other source of necessary metal cations is zinc and its cations are herein termed second divalent metal cations. In the preferred embodiment, the first divalent metal cations comprise about 84 to about 94 mole percent of the total first and second divalent metal cations in the bath. The deposited coating has first divalent metal cations (chemically combined with phosphate ions) present in an amount of at least 15 mole percent of the total first and second divalent metal cations in the coating.
    • 公开了一种通过改进的磷酸锌转化涂层以及通过该方法涂覆的制品来增加抗腐蚀金属表面上的磷酸盐转化涂层对碱溶解性的方法。 通过喷涂或浸渍将基板暴露于磷化溶液以化学地影响与基材的反应。 第一种二价金属阳离子选自具有比氢氧化锌在碱性溶液中溶解度低的氢氧化物的镁和过渡金属。 所需金属阳离子的另一个来源是锌,其阳离子在本文中称为第二二价金属阳离子。 在优选的实施方案中,第一二价金属阳离子包含浴中总的第一和第二二价金属阳离子的约84-约94摩尔%。 沉积的涂层具有以涂层中总的第一和第二二价金属阳离子的至少15摩尔%的量存在的第一二价金属阳离子(与磷酸根离子化学结合)。
    • 9. 发明授权
    • Metal base coating composition comprising chromium, silica and phosphate
and process for coating metal therewith
    • 包含铬,二氧化硅和磷酸盐的金属基涂料组合物以及用其涂覆金属的方法
    • US4647316A
    • 1987-03-03
    • US827668
    • 1986-02-07
    • Thomas J. Prescott
    • Thomas J. Prescott
    • C23C22/33C23C22/74C23F7/08
    • C23C22/33C23C22/74
    • Disclosed is an aqueous metal treatment composition comprising: (a) a hexavalent chromium compound; (b) a compound selected from the group consisting of silica and silicates and mixtures thereof and (c) phosphate. Preferably, the composition also comprises trivalent chromium compound and the respective weight ratios of hexavalent chromium, trivalent chromium, compound selected from the group consisting of silica and silicates and mixtures thereof, and phosphate to 1.0 total chromium by weight are from about 0.6 to 1.0; from 0.0 to about 0.4; from about 0.5 to about 5.0; and from about 0.1 to about 5.0, respectively. A metal surface can be coated with the aqueous metal treatment composition and then cured to provide a coated metal product having good corrosion resistance, paint adhesion characteristics and formability.
    • 公开了一种含水金属处理组合物,其包含:(a)六价铬化合物; (b)选自二氧化硅和硅酸盐及其混合物的化合物和(c)磷酸盐。 优选地,组合物还包含三价铬化合物,并且六价铬,三价铬,选自二氧化硅和硅酸盐的化合物及其混合物,磷酸盐与1.0重量%的铬的重量比分别为约0.6至1.0; 从0.0至约0.4; 约0.5至约5.0; 和约0.1至约5.0。 金属表面可以用含水金属处理组合物涂覆,然后固化以提供具有良好耐腐蚀性,涂料附着特性和成形性的涂覆金属产品。