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    • 1. 发明授权
    • Alkaline resistant phosphate conversion coatings
    • 耐碱磷酸盐转化涂层
    • US4713121A
    • 1987-12-15
    • US5180
    • 1987-01-20
    • Ronald W. ZurillaJohn Huff
    • Ronald W. ZurillaJohn Huff
    • C23C22/12C23C2/06
    • C23C22/12
    • A method for increasing the resistance to alkaline dissolution of a phosphate conversion coating on a corrodible metal surface by an improved zinc phosphate conversion coating together with articles coated by this method are disclosed. The substrate is exposed to the phosphating solution by spraying or immersion to chemically effect a reaction with the substrate. First divalent metal cations are selected from magnesium and transition metals having a hydroxide with lower solubility in alkaline solution than zinc hydroxide. The other source of necessary metal cations is zinc and its cations are herein termed second divalent metal cations. In the preferred embodiment, the first divalent metal cations comprise about 84 to about 94 mole percent of the total first and second divalent metal cations in the bath. The deposited coating has first divalent metal cations (chemically combined with phosphate ions) present in an amount of at least 15 mole percent of the total first and second divalent metal cations in the coating.
    • 公开了一种通过改进的磷酸锌转化涂层以及通过该方法涂覆的制品来增加抗腐蚀金属表面上的磷酸盐转化涂层对碱溶解性的方法。 通过喷涂或浸渍将基板暴露于磷化溶液以化学地影响与基材的反应。 第一种二价金属阳离子选自具有比氢氧化锌在碱性溶液中溶解度低的氢氧化物的镁和过渡金属。 所需金属阳离子的另一个来源是锌,其阳离子在本文中称为第二二价金属阳离子。 在优选的实施方案中,第一二价金属阳离子包含浴中总的第一和第二二价金属阳离子的约84-约94摩尔%。 沉积的涂层具有以涂层中总的第一和第二二价金属阳离子的至少15摩尔%的量存在的第一二价金属阳离子(与磷酸根离子化学结合)。
    • 2. 发明授权
    • Alkaline resistant phosphate conversion coatings
    • 耐碱磷酸盐转化涂层
    • US4722753A
    • 1988-02-02
    • US5185
    • 1987-01-20
    • Ronald W. ZurillaJohn Huff
    • Ronald W. ZurillaJohn Huff
    • C23C22/12
    • C23C22/12
    • A method for increasing the resistance to alkaline dissolution of a phosphate conversion coating on a corrodible metal surface by an improved zinc phosphate conversion coating together with articles coated by this method are disclosed. The substrate is exposed to the phosphating solution by spraying or immersion to chemically effect a reaction with the substrate. First divalent metal cations are selected from magnesium and transition metals having a hydroxide with lower solubility in alkaline solution than zinc hydroxide. The other source of necessary metal cations is zinc and its cations are herein termed second divalent metal cations. In the preferred embodiment, the first divalent metal cations comprise aobut 84 to about 94 mole percent of the total first and second divalent metal cations in the bath. The deposited coating has first divalent metal cations (chemically combined with phosphate ions) present in an amount of at least 15 mole percent of the total first and second divalent metal cations in the coating.
    • 公开了一种通过改进的磷酸锌转化涂层以及通过该方法涂覆的制品来增加抗腐蚀金属表面上的磷酸盐转化涂层对碱溶解性的方法。 通过喷涂或浸渍将基板暴露于磷化溶液以化学地影响与基材的反应。 第一种二价金属阳离子选自具有比氢氧化锌在碱性溶液中溶解度低的氢氧化物的镁和过渡金属。 所需金属阳离子的另一个来源是锌,其阳离子在本文中称为第二二价金属阳离子。 在优选的实施方案中,第一二价金属阳离子包含浴中的总第一和第二二价金属阳离子的约84-约94摩尔%。 沉积的涂层具有以涂层中总的第一和第二二价金属阳离子的至少15摩尔%的量存在的第一二价金属阳离子(与磷酸根离子化学结合)。