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1. 发明授权

US08680215B2 Method for modifying surface properties with nanostructured chemicals 有权
标题翻译：用纳米结构化学品改性表面性能的方法
公开(公告)号：US08680215B2
公开(公告)日：2014-03-25
申请号：US12787145
申请日：2010-05-25
申请人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
发明人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
IPC分类号： C08G77/04
CPC分类号： C08F283/00 , B82Y30/00 , C08F283/12 , C08F289/00 , C08F291/00 , C08J3/20 , C08J3/203 , C08J3/226 , C08J5/005 , C08J2201/038 , C08J2483/00 , C08K5/549
摘要： A method of using metallized and nonmetallized nanostructured chemicals as surface and volume modification agents within polymers and on the surfaces of nano and macroscopic particulates and fillers. Because of their 0.5 nm-3.0 nm size, nanostructured chemicals can be utilized to greatly increase surface area, improve compatibility, and promote lubricity between surfaces at a length scale not previously attainable.
摘要翻译：使用金属化和非金属化的纳米结构化学物质作为表面和体积改性剂在聚合物和纳米和宏观颗粒和填料的表面上的方法。由于它们的0.5nm-3.0nm的尺寸，可以利用纳米结构化学物质来大大增加表面积，提高相容性，并提高表面之间以前所未有的长度尺度的润滑性。

2. 发明授权

US08076443B2 Preparation of polyhedral oligomeric silsesquioxane silanols and siloxides functionalized with olefinic groups 有权
标题翻译：制备用烯烃官能化的多面体低聚倍半硅氧烷硅烷醇和硅氧烷
公开(公告)号：US08076443B2
公开(公告)日：2011-12-13
申请号：US11464925
申请日：2006-08-16
申请人： Joseph J. Schwab , Yi-Zhong An , Sukhendu B. Hait , William A. Reinerth, Sr. , Hendrikus C. L. Abbenhuis
发明人： Joseph J. Schwab , Yi-Zhong An , Sukhendu B. Hait , William A. Reinerth, Sr. , Hendrikus C. L. Abbenhuis
IPC分类号： C08G77/20
CPC分类号： C08G77/04 , C08G77/16 , C08G77/20
摘要： A synthetic process for polyhedral oligomeric silsesquioxanes (POSS) and polyhedral oligomeric silicates (POS) produces silanol and siloxide molecules containing both olefinic groups and alkyl or aromatic groups. Olefin-bearing POSS silanol/siloxides are derivatized into a variety of chemical species while retaining the ability to further derivatize the silanol/siloxide.
摘要翻译：多面体低聚倍半硅氧烷（POSS）和多面体低聚硅酸盐（POS）的合成方法产生含有烯属基团和烷基或芳族基团的硅烷醇和硅氧烷分子。含烯烃的POSS硅烷醇/硅氧烷被衍生成各种化学物质，同时保持进一步衍生硅烷醇/硅氧烷的能力。

3. 发明授权

US07638195B2 Surface modification with polyhedral oligomeric silsesquioxanes silanols 有权
标题翻译：多面体低聚倍半硅氧烷硅烷醇的表面改性
公开(公告)号：US07638195B2
公开(公告)日：2009-12-29
申请号：US11342240
申请日：2006-01-27
申请人： Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , William A. Reinerth, Sr.
发明人： Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , William A. Reinerth, Sr.
IPC分类号： B32B17/02
CPC分类号： C09D5/028 , B82Y30/00 , Y10T428/2938 , Y10T428/2962 , Y10T428/2982 , Y10T428/2995 , Y10T428/31663
摘要： Nanoreinforced coatings with improved hydrophobicity, thermal stability, hardness, and durability have been developed from polyhedral oligomeric silsesquioxane (POSS) reagents and resins. The nanoscopic dimensions and hybrid (organic/inorganic) composition of POSS reagents are particularly useful for coating fillers derived from minerals, metals, glasses, and polymeric materials.
摘要翻译：已经从多面体低聚倍半硅氧烷（POSS）试剂和树脂开发出具有改进的疏水性，热稳定性，硬度和耐久性的纳米增强涂层。 POSS试剂的纳米尺寸和杂化（有机/无机）组合物特别适用于涂覆源自矿物，金属，玻璃和聚合材料的填料。

4. 发明申请

US20100305282A1 METHOD FOR MODIFYING SURFACE PROPERTIES WITH NANOSTRUCTURED CHEMICALS 有权
标题翻译：用纳米结构化学改性表面性质的方法
公开(公告)号：US20100305282A1
公开(公告)日：2010-12-02
申请号：US12787145
申请日：2010-05-25
申请人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
发明人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
IPC分类号： C08G77/38
CPC分类号： C08F283/00 , B82Y30/00 , C08F283/12 , C08F289/00 , C08F291/00 , C08J3/20 , C08J3/203 , C08J3/226 , C08J5/005 , C08J2201/038 , C08J2483/00 , C08K5/549
摘要： A method of using metallized and nonmetallized nanostructured chemicals as surface and volume modification agents within polymers and on the surfaces of nano and macroscopic particulates and fillers. Because of their 0.5 nm-3.0 nm size, nanostructured chemicals can be utilized to greatly increase surface area, improve compatibility, and promote lubricity between surfaces at a length scale not previously attainable.
摘要翻译：使用金属化和非金属化的纳米结构化学物质作为表面和体积改性剂在聚合物和纳米和宏观颗粒和填料的表面上的方法。由于它们为0.5nm-3.0纳米尺寸的，纳米结构化的化学品可被用于大大增加的表面积，提高的相容性，并且在长度尺度先前无法达到促进表面之间的润滑性。

5. 发明授权

US07612143B2 Metallized nanostructured chemicals alloyed into polymers 失效
标题翻译：金属化的纳米结构化学品合成为聚合物
公开(公告)号：US07612143B2
公开(公告)日：2009-11-03
申请号：US11466053
申请日：2006-08-21
申请人： Joseph D. Lichtenhan , Xuan Fu , Joseph J. Schwab , Paul Wheeler , Hendrikus C. L. Abbenhuis
发明人： Joseph D. Lichtenhan , Xuan Fu , Joseph J. Schwab , Paul Wheeler , Hendrikus C. L. Abbenhuis
IPC分类号： C08F8/00
CPC分类号： C08K5/549
摘要： Metallized nanostructured chemicals are incorporated at the molecular level as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments. Direct blending processes are effective because of the tailorable compatibility of the metallized nanostructured chemicals with polymers.
摘要翻译：金属化纳米结构化学品在分子水平上作为用于增强聚合物微结构的合金化剂，包括聚合物线圈，结构域，链和链段。直接共混过程是有效的，因为金属化纳米结构化学品与聚合物的可定制的相容性。

6. 发明授权

US07485692B2 Process for assembly of POSS monomers 有权
标题翻译： POSS单体装配工艺
公开(公告)号：US07485692B2
公开(公告)日：2009-02-03
申请号：US11371195
申请日：2006-03-07
申请人： Joseph J. Schwab , Yi-Zhong An
发明人： Joseph J. Schwab , Yi-Zhong An
IPC分类号： C08G77/08
CPC分类号： C07F7/21
摘要： A synthesis process for polyhedral oligomeric silsesquioxanes using phosphazene superbases to produce in high yield a low resin content, solvent free, and trace metal free monomer suitable for use in microelectronic, biological, and medical applications involving polymerization, grafting, and alloying.
摘要翻译：多面体低聚倍半硅氧烷的合成方法，其使用磷腈超级酶以高产率生产低树脂含量，无溶剂和不含痕量金属的单体，适用于涉及聚合，接枝和合金化的微电子，生物和医学应用。

7. 发明申请

US20100137464A1 POROSITY CONTROL WITH POLYHEDRAL OLIGOMERIC SILSESQUIOXANES 审中-公开
标题翻译：多孔低密度硅藻土的多孔性控制
公开(公告)号：US20100137464A1
公开(公告)日：2010-06-03
申请号：US12698931
申请日：2010-02-02
申请人： Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Jack Sammons
发明人： Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Jack Sammons
IPC分类号： C08J9/40
CPC分类号： C08J3/203 , B82Y30/00 , C08J5/005 , C08J2201/038 , C08K5/549 , Y10T428/2995 , Y10T428/31663
摘要： The use of nanostructured chemicals based on polyhedral oligomeric silsesquioxanes (POSS) and polyhedral oligomeric silicates (POS) are used to control porosity in organic and inorganic media. The precisely defined nanoscopic dimensions of this class of chemicals enables porosity to be both created (increased) or reduced (decreased) as desired. The thermal and chemical stability of the POSS/POS nanostructures and the ability of these nano-building blocks to be selectively placed or rationally assembled with both inorganic and organic material mediums allow tailoring of porosity.
摘要翻译：使用基于多面体低聚倍半硅氧烷（POSS）和多面体低聚硅酸盐（POS）的纳米结构化学品用于控制有机和无机介质中的孔隙率。这类化学品的精确定义的纳米尺寸尺寸可以根据需要产生（增加）或减少（减少）孔隙度。 POSS / POS纳米结构的热和化学稳定性以及这些纳米结构单元与无机和有机材料介质选择性地放置或合理组装的能力允许调整孔隙度。

8. 发明授权

US07723415B2 POSS nanostructured chemicals as dispersion aids and friction reducing agents 有权
标题翻译： POSS纳米结构化学品作为分散助剂和减摩剂
公开(公告)号：US07723415B2
公开(公告)日：2010-05-25
申请号：US11641543
申请日：2006-12-18
申请人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
发明人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
IPC分类号： C08K5/541
CPC分类号： C08F283/00 , B82Y30/00 , C08F283/12 , C08F289/00 , C08F291/00 , C08J3/20 , C08J3/203 , C08J3/226 , C08J5/005 , C08J2201/038 , C08J2483/00 , C08K5/549
摘要： A method of using metallized and nonmetallized nanostructured chemicals as surface and volume modification agents within polymers and on the surfaces of nano and macroscopic particulates and fillers. Because of their 0.5 nm-3.0 nm size, nanostructured chemicals can be utilized to greatly increase surface area, improve compatibility, and promote lubricity between surfaces at a length scale not previously attainable.
摘要翻译：使用金属化和非金属化的纳米结构化学物质作为表面和体积改性剂在聚合物和纳米和宏观颗粒和填料的表面上的方法。由于它们的0.5nm-3.0nm的尺寸，可以利用纳米结构化学物质来大大增加表面积，提高相容性，并提高表面之间以前所未有的长度尺度的润滑性。

9. 发明授权

US07265194B1 Polyhedral oligomeric silsesquinoxanes and polyhedral oligomeric silicates bearing surfactant functionalities 失效
标题翻译：具有表面活性剂功能的多面体低聚硅氧烷喹啉和多面体低聚硅酸盐
公开(公告)号：US07265194B1
公开(公告)日：2007-09-04
申请号：US10968370
申请日：2004-10-18
申请人： Joseph D. Lichtenhan , Joseph J. Schwab
发明人： Joseph D. Lichtenhan , Joseph J. Schwab
IPC分类号： C08G77/38
CPC分类号： C08G77/04 , C08G77/382
摘要： This invention teaches the preparation and compositions of POSS nanostructured chemicals bearing a variety of onium-type surfactants. The surfactants serve as low-cost compatibilizing groups for polyhedral oligomeric silsesquioxane and polyhedral oligomeric silicate nanostructures with man-made polymer and biological systems. Variations of the surfactants also provide reactivity for the nanostructured chemicals with man-made and biological materials. The surfactant bearing nanostructured chemicals are useful as alloying agents is for controlling the structure and bulk physical properties of materials from the nanoscopic length scale. Alternately, the surfactants can be eliminated from the nanostructures to render the formation of nanoscopically dispersed silica particles.
摘要翻译：本发明教导了具有各种鎓型表面活性剂的POSS纳米结构化学品的制备和组成。表面活性剂作为多面体低聚倍半硅氧烷和具有人造聚合物和生物体系的多面体低聚硅酸盐纳米结构的低成本相容性基团。表面活性剂的变化也为人造和生物材料的纳米结构化学品提供反应性。具有表面活性剂的纳米结构化学品可用作合金化剂用于从纳米尺度尺度控制材料的结构和体积物理性质。或者，可以从纳米结构中去除表面活性剂以形成纳米尺度分散的二氧化硅颗粒。

10. 发明授权

US09267023B2 Method for modifying surface properties with nanostructured chemicals 有权
标题翻译：用纳米结构化学品改性表面性能的方法
公开(公告)号：US09267023B2
公开(公告)日：2016-02-23
申请号：US14225182
申请日：2014-03-25
申请人： Hybrid Plastics, Inc.
发明人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
IPC分类号： C08G77/04 , C08L23/12 , C08L23/06 , C08J3/20 , C08J5/00 , C08K9/06 , B82Y30/00 , C08K5/549
CPC分类号： C08L23/12 , B82Y30/00 , C08J3/20 , C08K5/549 , C08K2201/011 , C08L23/06 , C08L2310/00 , C08L23/10 , C08L83/04 , C08K9/06
摘要： A method of using metallized and nonmetallized nanostructured chemicals as surface and volume modification agents within polymers and on the surfaces of nano and macroscopic particulates and fillers. Because of their 0.5 nm-3.0 nm size, nanostructured chemicals can be utilized to greatly increase surface area, improve compatibility, and promote lubricity between surfaces at a length scale not previously attainable.
摘要翻译：使用金属化和非金属化的纳米结构化学物质作为表面和体积改性剂在聚合物和纳米和宏观颗粒和填料的表面上的方法。由于它们的0.5nm-3.0nm的尺寸，可以利用纳米结构化学物质来大大增加表面积，提高相容性，并提高表面之间以前所未有的长度尺度的润滑性。

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