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1. 发明授权

US07612143B2 Metallized nanostructured chemicals alloyed into polymers 失效
标题翻译：金属化的纳米结构化学品合成为聚合物
公开(公告)号：US07612143B2
公开(公告)日：2009-11-03
申请号：US11466053
申请日：2006-08-21
申请人： Joseph D. Lichtenhan , Xuan Fu , Joseph J. Schwab , Paul Wheeler , Hendrikus C. L. Abbenhuis
发明人： Joseph D. Lichtenhan , Xuan Fu , Joseph J. Schwab , Paul Wheeler , Hendrikus C. L. Abbenhuis
IPC分类号： C08F8/00
CPC分类号： C08K5/549
摘要： Metallized nanostructured chemicals are incorporated at the molecular level as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments. Direct blending processes are effective because of the tailorable compatibility of the metallized nanostructured chemicals with polymers.
摘要翻译：金属化纳米结构化学品在分子水平上作为用于增强聚合物微结构的合金化剂，包括聚合物线圈，结构域，链和链段。直接共混过程是有效的，因为金属化纳米结构化学品与聚合物的可定制的相容性。

2. 发明授权

US07820761B2 Metallized nanostructured chemicals as cure promoters 有权
标题翻译：金属化纳米结构化学品作为固化促进剂
公开(公告)号：US07820761B2
公开(公告)日：2010-10-26
申请号：US11537306
申请日：2006-09-29
申请人： Joseph D. Lichtenhan , Joseph J. Schwab , Xuan Fu , Hendrikus C. L. Abbenhuis , Paul Wheeler
发明人： Joseph D. Lichtenhan , Joseph J. Schwab , Xuan Fu , Hendrikus C. L. Abbenhuis , Paul Wheeler
IPC分类号： C08F8/00
CPC分类号： C23C18/122 , C23C18/1212 , C23C18/1233
摘要： Metallized polyhedral oligomeric silsesquioxanes and metallized polyhedral oligomeric silicates are used as cure promoters, catalysts, and alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with polymers, polyhedral oligomeric metallosesquioxanes (POMS) can be readily and selectively incorporated into polymers by common mixing processes.
摘要翻译：金属化多面体低聚倍半硅氧烷和金属化多面体低聚硅酸盐用作固化促进剂，催化剂和合金剂，用于在分子水平上增强聚合物微结构，包括聚合物线圈，结构域，链和链段。由于它们与聚合物的可定制的相容性，多面体低聚金属倍半硅氧烷（POMS）可以通过常用的混合方法容易且有选择地并入聚合物中。

3. 发明申请

US20100125123A1 METALLIZED NANOSTRUCTURED CHEMICALS AS CURE PROMOTERS 有权
标题翻译：金属化的纳米结构化学品作为固化促进剂
公开(公告)号：US20100125123A1
公开(公告)日：2010-05-20
申请号：US11537306
申请日：2006-09-29
申请人： Joseph D. Lichtenhan , Joseph J. Schwab , Xuan Fu , H.C.L. Abbenhuis , Paul Wheeler
发明人： Joseph D. Lichtenhan , Joseph J. Schwab , Xuan Fu , H.C.L. Abbenhuis , Paul Wheeler
IPC分类号： C08G59/14 , C08G18/83 , C08F26/06
CPC分类号： C23C18/122 , C23C18/1212 , C23C18/1233
摘要： Metallized polyhedral oligomeric silsesquioxanes and metallized polyhedral oligomeric silicates are used as cure promoters, catalysts, and alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with polymers, polyhedral oligomeric metallosesquioxanes (POMS) can be readily and selectively incorporated into polymers by common mixing processes.
摘要翻译：金属化多面体低聚倍半硅氧烷和金属化多面体低聚硅酸盐用作固化促进剂，催化剂和合金剂，用于在分子水平上增强聚合物微结构，包括聚合物线圈，结构域，链和链段。由于它们与聚合物的可定制的相容性，多面体低聚金属倍半硅氧烷（POMS）可以通过常用的混合方法容易且有选择地并入聚合物中。

4. 发明申请

US20080262162A1 METALLIZED NANOSTRUCTURED CHEMICALS ALLOYED INTO POLYMERS 失效
标题翻译：金属化的纳米结构化学化合物合成聚合物
公开(公告)号：US20080262162A1
公开(公告)日：2008-10-23
申请号：US11466053
申请日：2006-08-21
申请人： Joseph D. Lichtenhan , Xuan Fu , Joseph J. Schwab , Paul Wheeler , H.C.L. Abbenhuis
发明人： Joseph D. Lichtenhan , Xuan Fu , Joseph J. Schwab , Paul Wheeler , H.C.L. Abbenhuis
IPC分类号： C08L85/00 , C08L83/06 , C08L85/04
CPC分类号： C08K5/549
摘要： Metallized nanostructured chemicals are incorporated at the molecular level as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments. Direct blending processes are effective because of the tailorable compatibility of the metallized nanostructured chemicals with polymers.
摘要翻译：金属化纳米结构化学品在分子水平上作为用于增强聚合物微结构的合金化剂，包括聚合物线圈，结构域，链和链段。直接共混过程是有效的，因为金属化纳米结构化学品与聚合物的可定制的相容性。

5. 发明授权

US07572872B2 Biomimetic materials comprising polyhedral oligomeric silsesquioxanes 失效
标题翻译：包含多面体低聚倍半硅氧烷的仿生材料
公开(公告)号：US07572872B2
公开(公告)日：2009-08-11
申请号：US11379993
申请日：2006-04-24
申请人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
发明人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
IPC分类号： C08F30/08
CPC分类号： A61L27/18 , A61L2400/12 , C08L83/04
摘要： Nanostructured chemicals such as polyhedral oligomeric silsesquioxanes, polyhedral oligomeric silicates, and polyhedral oligomeric metallasesquioxanes are attached to living and nonliving systems as biomaterials to provide a nanoscopic topology that favors biomimetic function and cellular modulation. The resulting surface is nanoscopically thin, nanoscopically dispersed, provides systematic chemistry, surface area, surface volume, surface topology, and is essentially free of impurities, and has controllable properties through selection of composition, R groups, nanostructure size and topology. Highly shape specific and chemically tailorable nanostructured molecules are sized to biological material dimensions and are compatible with all sterilization methods.
摘要翻译：纳米结构化学物质如多面体低聚倍半硅氧烷，多面体低聚硅酸盐和多面体低聚金属氧化物倍半硅氧烷作为生物材料连接到生物和非活性体系上，以提供有利于仿生功能和细胞调节的纳米视觉拓扑结构。所得表面纳米级薄，纳米级分散，提供系统化学，表面积，表面体积，表面拓扑，基本上不含杂质，通过选择组成，R基团，纳米结构尺寸和拓扑结构具有可控性。高度形状的特定和化学可裁剪的纳米结构分子的大小适合生物材料尺寸，并与所有灭菌方法兼容。

6. 发明授权

US07737228B2 Metallized polyhedral oligomeric silsesquioxanes as catalysts for polyurethanes 有权
标题翻译：金属多面体低聚倍半硅氧烷作为聚氨酯的催化剂
公开(公告)号：US07737228B2
公开(公告)日：2010-06-15
申请号：US12124887
申请日：2008-05-21
申请人： Joseph D. Lichtenhan , Joseph J. Schwab , Xuan Fu
发明人： Joseph D. Lichtenhan , Joseph J. Schwab , Xuan Fu
IPC分类号： C08F283/04
CPC分类号： C23C18/122 , C08G18/222 , C08G18/24 , C08K5/549 , C23C18/1212 , C23C18/1233
摘要： A method of using metallized polyhedral oligomeric silsesquioxanes as cure promoters and catalysts for polyurethanes.
摘要翻译：使用金属化多面体低聚倍半硅氧烷作为聚氨酯的固化促进剂和催化剂的方法。

7. 发明申请

US20090082502A1 METALLIZED POLYHEDRAL OLIGOMERIC SILSESQUIOXANES AS CATALYSTS FOR POLYURETHANES 有权
标题翻译：作为聚氨酯催化剂的金属聚合物低聚硅烷氧化物
公开(公告)号：US20090082502A1
公开(公告)日：2009-03-26
申请号：US12124887
申请日：2008-05-21
申请人： Joseph D. Lichtenhan , Joseph J. Schwab , Xuan Fu
发明人： Joseph D. Lichtenhan , Joseph J. Schwab , Xuan Fu
IPC分类号： C08K5/541 , C08G18/16
CPC分类号： C23C18/122 , C08G18/222 , C08G18/24 , C08K5/549 , C23C18/1212 , C23C18/1233
摘要： A method of using metallized polyhedral oligomeric silsesquioxanes as cure promoters and catalysts for polyurethanes.
摘要翻译：使用金属化多面体低聚倍半硅氧烷作为聚氨酯的固化促进剂和催化剂的方法。

8. 发明申请

US20090176006A1 BIOMIMETIC MATERIALS COMPRISING POLYHEDRAL OLIGOMERIC SILSESQUIOXANES 失效
标题翻译：包含聚合物低聚硅氧烷的生物材料
公开(公告)号：US20090176006A1
公开(公告)日：2009-07-09
申请号：US11379993
申请日：2006-04-24
申请人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
发明人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
IPC分类号： B05D3/00
CPC分类号： A61L27/18 , A61L2400/12 , C08L83/04
摘要： Nanostructured chemicals such as polyhedral oligomeric silsesquioxanes, polyhedral oligomeric silicates, and polyhedral oligomeric metallasesquioxanes are attached to living and nonliving systems as biomaterials to provide a nanoscopic topology that favors biomimetic function and cellular modulation. The resulting surface is nanoscopically thin, nanoscopically dispersed, provides systematic chemistry, surface area, surface volume, surface topology, and is essentially free of impurities, and has controllable properties through selection of composition, R groups, nanostructure size and topology. Highly shape specific and chemically tailorable nanostructured molecules are sized to biological material dimensions and are compatible with all sterilization methods.
摘要翻译：纳米结构化学物质如多面体低聚倍半硅氧烷，多面体低聚硅酸盐和多面体低聚金属氧化物倍半硅氧烷作为生物材料连接到生物和非活性体系上，以提供有利于仿生功能和细胞调节的纳米视觉拓扑结构。所得表面纳米级薄，纳米级分散，提供系统化学，表面积，表面体积，表面拓扑，基本上不含杂质，通过选择组成，R基团，纳米结构尺寸和拓扑结构具有可控性。高度形状的特定和化学可裁剪的纳米结构分子的大小适合生物材料尺寸，并与所有灭菌方法兼容。

9. 发明授权

US07553904B2 High use temperature nanocomposite resins 有权
标题翻译：高使用温度的纳米复合树脂
公开(公告)号：US07553904B2
公开(公告)日：2009-06-30
申请号：US11225607
申请日：2005-09-12
申请人： Joseph D. Lichtenhan , Qibo Liu , Yan-Jyh Lee , Xuan Fu , Sukhendu Hait , Joseph J. Schwab , Rusty L. Blanski , Patrick N. Ruth
发明人： Joseph D. Lichtenhan , Qibo Liu , Yan-Jyh Lee , Xuan Fu , Sukhendu Hait , Joseph J. Schwab , Rusty L. Blanski , Patrick N. Ruth
IPC分类号： C08L83/00
CPC分类号： C08K5/549 , Y10T428/31663
摘要： A method of using olefin containing nanostructured chemicals and silanol containing nanostructured chemicals as high temperature resins is described. Vinyl containing nanostructured chemicals are particularity effective in thermosets as they control the motions of polymer chains, and segments, at the molecular level. Silanol containing nanostructured chemicals are particularity effective in thermosets containing polar groups as the silanol can enhance the reactivity of these groups. Because of their tailorable compatibility with fluorinated polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending and polymerization processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are heat distortion and flammability characteristics, permeability, optical properties, texture, feel and durability. Other properties improved include time dependent mechanical and thermal properties such as creep, compression set, shrinkage, modulus, and hardness. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, and gas oxygen permeability. These improved properties may be useful in a number of applications, including composite materials, foams, cosmetics, and durable coatings.
摘要翻译：描述了使用含烯烃的纳米结构化学品和含硅烷醇的纳米结构化学品作为高温树脂的方法。含乙烯基纳米结构化学品在热固性材料中特别有效，因为它们在分子水平上控制聚合物链和链段的运动。含硅烷醇的纳米结构化学品在含极性基团的热固性材料中是特别有效的，因为硅烷醇可增强这些基团的反应性。由于它们与氟化聚合物的可定制的相容性，纳米结构化学物质可以通过直接共混和聚合过程容易且选择性地引入到聚合物中。将纳米结构化学物质掺入聚合物有利地影响了许多聚合物的物理性质。性能最有利地提高了热变形和易燃特性，渗透性，光学性能，质地，手感和耐久性。改进的其它性能包括时间依赖性机械和热性能，如蠕变，压缩永久变形，收缩率，模量和硬度。除机械性能外，还有其他物理性能得到改善，包括较低的导热系数和气体透氧性。这些改进的性质可用于许多应用，包括复合材料，泡沫，化妆品和耐用涂层。

10. 发明授权

US08076443B2 Preparation of polyhedral oligomeric silsesquioxane silanols and siloxides functionalized with olefinic groups 有权
标题翻译：制备用烯烃官能化的多面体低聚倍半硅氧烷硅烷醇和硅氧烷
公开(公告)号：US08076443B2
公开(公告)日：2011-12-13
申请号：US11464925
申请日：2006-08-16
申请人： Joseph J. Schwab , Yi-Zhong An , Sukhendu B. Hait , William A. Reinerth, Sr. , Hendrikus C. L. Abbenhuis
发明人： Joseph J. Schwab , Yi-Zhong An , Sukhendu B. Hait , William A. Reinerth, Sr. , Hendrikus C. L. Abbenhuis
IPC分类号： C08G77/20
CPC分类号： C08G77/04 , C08G77/16 , C08G77/20
摘要： A synthetic process for polyhedral oligomeric silsesquioxanes (POSS) and polyhedral oligomeric silicates (POS) produces silanol and siloxide molecules containing both olefinic groups and alkyl or aromatic groups. Olefin-bearing POSS silanol/siloxides are derivatized into a variety of chemical species while retaining the ability to further derivatize the silanol/siloxide.
摘要翻译：多面体低聚倍半硅氧烷（POSS）和多面体低聚硅酸盐（POS）的合成方法产生含有烯属基团和烷基或芳族基团的硅烷醇和硅氧烷分子。含烯烃的POSS硅烷醇/硅氧烷被衍生成各种化学物质，同时保持进一步衍生硅烷醇/硅氧烷的能力。

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