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    • 4. 发明授权
    • Alkali metal-sulphur cells
    • 碱金属硫细胞
    • US4124739A
    • 1978-11-07
    • US808012
    • 1977-06-20
    • James L. Sudworth
    • James L. Sudworth
    • H01M10/39H01M10/42
    • H01M10/42H01M10/3909
    • An arrangement for controlling the charge and/or discharge cycles of an alkali-metal/sulphur cell or battery has detecting means for detecting predetermined high and/or low levels of alkali-metal in the anode compartment of a cell or in an alkali-metal reservoir communicating with the anode compartment whereby the end of the charge and/or discharge cycles is determined. Alternatively, similar detecting means can be associated with an alkali-metal/alkali-metal cycling device which is connected electrically in series with a group of series-connected cells of an alkali-metal/sulphur battery to determine the end of the charge and/or discharge cycles of the battery.
    • 用于控制碱金属/硫电池或电池的充电和/或放电循环的装置具有检测装置,用于检测电池阳极室或碱金属中预定的高和/或低水平的碱金属 储存器与阳极室连通,从而确定充电和/或放电循环的结束。 或者,类似的检测装置可以与碱金属/碱金属循环装置相关联,碱金属/碱金属循环装置与碱金属/硫电池的一组串联连接的电池串联电连接以确定电荷的结束和/ 或电池的放电周期。
    • 7. 发明授权
    • Alkali metal cells and batteries and the manufacture thereof
    • 碱金属电池和电池及其制造
    • US4452871A
    • 1984-06-05
    • US387093
    • 1982-06-10
    • Peter J. Bindin
    • Peter J. Bindin
    • H01M2/06H01M10/39H01M2/02
    • H01M10/3909H01M2/06
    • In a sodium sulphur cell having, within a metal housing, a ceramic electrolyte tube separating the liquid alkali metal from the cathodic reactant, a current collector extends into the region inside the electrolyte tube and is electrically insulated from the electrolyte by an insulating element. The metal housing is sealed to the insulating element in a region around the current collector which region has a maximum cross-section substantially less than the maximum cross-section of the electrolyte tube and preferably lies wholly within the outer periphery of the electrolyte tube. The small seal areas with the constructions described give improved economy and reliability. The constructon has particular advantages with cells of short length.
    • 在具有在金属壳体内的将液态碱金属与阴极反应物分离的陶瓷电解质管的钠硫电池中,集电体延伸到电解质管内部的区域中,并通过绝缘元件与电解质电绝缘。 金属壳体在集电体周围的区域中密封到绝缘元件,该区域的最大横截面积显着小于电解质管的最大横截面,并且优选完全位于电解质管的外周中。 具有所述结构的小密封区域提供了改善的经济性和可靠性。 构建体具有长度短的细胞的特殊优点。
    • 10. 发明授权
    • Sodium sulphur cells and their manufacture
    • 钠硫电池及其制造
    • US4638555A
    • 1987-01-27
    • US748933
    • 1985-06-26
    • Stuart MacLachlanChristopher O'Neill Bell
    • Stuart MacLachlanChristopher O'Neill Bell
    • H01M2/04H01M10/39H01M6/00B23K35/36
    • H01M2/0447H01M10/3909Y10T29/49108
    • An alkali metal energy conversion device, particularly a sodium sulphur cell has a cylindrical outer casing (18) containing a tubular solid electrolyte (10) of beta alumina. An outer cathode region between the electrolyte (10) and the casing (18) contains sulphur, and an inner anode region in the electrolyte tube contains sodium. An alpha alumina lid (12) closes the tube (10) and holds a current collector (15). The cathode region is sealed by an annular metal element (23) which is thermocompression bonded about its inner periphery to the lid (12) and is welded about its outer periphery to the casing (18). A second annular metal element (26) is thermocompression bonded to the lid (12) wholly inside the first annular element (23) and is welded to the current collector.The metal elements (23, 26) are bonded to the lid (12) before the lid is glazed to the electrolyte tube (10) and before the first element (23) is welded to the casing (18).
    • 碱金属能量转换装置,特别是钠硫电池具有包含β氧化铝的管状固体电解质(10)的圆柱形外壳(18)。 电解质(10)与壳体(18)之间的外部阴极区域含有硫,电解质管内的内部阳极区域含有钠。 α氧化铝盖(12)封闭管(10)并保持集电器(15)。 阴极区域由环形金属元件(23)密封,环形金属元件(23)围绕其内周热封压到盖(12),并且围绕其外周焊接到外壳(18)。 将第二环形金属元件(26)全部热封在第一环形元件(23)的内部并与盖子(12)结合在一起,并被焊接到集电器上。 在将盖子玻璃化到电解质管(10)之前并且第一元件(23)焊接到壳体(18)之前,金属元件(23,26)被接合到盖子(12)。