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1. 发明授权

US09300012B2 Solid electrolyte secondary battery 有权
标题翻译：固体电解质二次电池
公开(公告)号：US09300012B2
公开(公告)日：2016-03-29
申请号：US13699661
申请日：2011-05-31
申请人： Hiroshi Ohkawa
发明人： Hiroshi Ohkawa
IPC分类号： H01M2/02 , H01M4/38 , H01M10/056 , H01M10/39 , H01M10/04 , H01M10/38 , H01M10/42
CPC分类号： H01M10/3909 , H01M10/0468 , H01M10/38 , H01M10/3954 , H01M10/4214 , H01M10/425 , H01M2300/0068
摘要： Provided is a solid electrolyte secondary battery with a greater capacity than previous solid electrolyte secondary batteries. Furthermore, the disclosed solid electrolyte secondary battery can obtain a high power output and improve battery function while ensuring a large capacity. The solid electrolyte secondary battery is provided with a cathode chamber, a cathode active material container that is provided independently and stores some cathode active material, and a channel medium that is provided between the two and through which the active material passes. The cathode active material is transferred by the channel medium and heterogeneity, when the active material is discharged, can be curbed. By providing a transfer medium, which transfers the cathode active material, the cathode active material can be forcibly transferred.
摘要翻译：提供比以前的固体电解质二次电池容量大的固体电解质二次电池。此外，所公开的固体电解质二次电池可以在确保大容量的同时获得高功率输出并且改善电池功能。固体电解质二次电池设置有阴极室，独立设置并存储一些正极活性物质的阴极活性物质容器，以及设置在两者之间并且活性物质通过的通道介质。正极活性物质通过通道介质转移，当活性物质排出时，异质性被抑制。通过提供转移阴极活性材料的转印介质，阴极活性材料可被强制转印。

2. 发明申请

US20150044545A1 LOW TEMPERATURE SULFUR AND SODIUM METAL BATTERY FOR GRID-SCALE ENERGY STORAGE APPLICATION 有权
标题翻译：低温硫磺和金属电池用于网格规模能源储存应用
公开(公告)号：US20150044545A1
公开(公告)日：2015-02-12
申请号：US14385030
申请日：2013-03-15
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
发明人： Gao Liu , Dongdong Wang
IPC分类号： H01M10/054 , H01M4/40 , H01M4/60 , H01M10/0565
CPC分类号： H01M10/054 , H01M2/1653 , H01M2/1673 , H01M4/40 , H01M4/604 , H01M4/661 , H01M10/056 , H01M10/0565 , H01M10/3918 , H01M10/3954 , H01M2300/002 , H01M2300/0082
摘要： A re-chargeable battery comprising a non-dendrite forming sodium (Na)/potassium (K) liquid metal alloy anode, a sulfur and polyacrylonitrile (PAN) conductive polymer composite cathode, a polyethyleneoxide (PEO) solid electrolyte, a solid electrolyte interface (SEI) formed on the PEO solid electrolyte; and a cell housing, wherein the anode, cathode, and electrolyte are assembled into the cell housing with the PEO solid electrolyte disposed between the cathode and anode.
摘要翻译：包含形成钠（Na）/钾（K）液态金属合金阳极，硫和聚丙烯腈（PAN）导电聚合物复合阴极，聚环氧乙烷（PEO）固体电解质，固体电解质界面 SEI）在PEO固体电解质上形成; 以及电池壳体，其中阳极，阴极和电解质被组装到电池壳体中，PEO固体电解质设置在阴极和阳极之间。

3. 发明授权

US4568620A Sodium sulphur cells and cathode current collectors for such cells 失效
标题翻译：钠硫电池和这种电池的阴极集电器
公开(公告)号：US4568620A
公开(公告)日：1986-02-04
申请号：US630630
申请日：1984-07-13
申请人： Michael L. Wright , Alec R. Tilley
发明人： Michael L. Wright , Alec R. Tilley
IPC分类号： H01M4/64 , H01M4/66 , H01M10/39
CPC分类号： H01M4/661 , H01M10/3909 , H01M4/663 , H01M4/664 , H01M10/3954 , Y10S228/903 , Y10T29/49108 , Y10T29/49115 , Y10T29/49805 , Y10T29/49886
摘要： In a sodium sulphur cell, improved protection of a cathode current collector is obtained by isostatically pressing graphite foil or flakes onto the surface of the collector, which surface is preferably roughened or coated with an intermediate conductive layer such as a nickel-chromium alloy or a conductive carbide providing a rough surface.

4. 发明授权

US4360575A Annular cathode electrode structures for sodium sulphur cells 失效
标题翻译：用于钠硫电池的环形阴极电极结构
公开(公告)号：US4360575A
公开(公告)日：1982-11-23
申请号：US245784
申请日：1981-03-20
申请人： Michael P. J. Brennan
发明人： Michael P. J. Brennan
IPC分类号： B29C37/00 , B29C53/06 , B29C53/40 , H01M4/00 , H01M4/70 , H01M10/39 , H01M4/80
CPC分类号： H01M10/3909 , B29C53/063 , B29C53/40 , B29C70/28 , H01M4/00 , H01M4/70 , B29C37/0057 , H01M10/3954 , Y10T29/49115
摘要： For a cylindrical sodium sulfur cell, a cathode electrode structure is provided with improved electronic conductivity in the radial direction, compared with other directions, by forming a block of fibre material, e.g. graphite fibres, with the fibres aligned in one direction, slicing the block to form a sheet with fibres normal to the plane of the sheet, moulding the sheet and impregnating it with cathodic reactant in a heated mould having a plurality of ribs, to form a plurality of trapezoidal segments with the fibres normal to the planes of the parallel surfaces of the trapezoids, cooling the mould so that the impregnant is solidified and then forming the trapezoids into an annular structure. Preferably the mould is such that thin webs are left joining adjacent trapezoidal sections along parallel edges of the wider of the two parallel faces so that the webs form hinges for folding the segments into the annular assembly.
摘要翻译：对于圆柱形钠硫电池，通过形成纤维材料块，例如，与其它方向相比，阴极电极结构在径向上具有改善的电子导电性。将纤维沿一个方向排列的石墨纤维，将块切片以形成垂直于片材平面的纤维的片材，模塑该片材并将其用阴极反应物浸渍在具有多个肋条的加热模具中以形成多个梯形段，纤维垂直于梯形平行表面的平面，冷却模具，使浸渍剂固化，然后将梯形成环形结构。优选地，模具使得薄的腹板沿着两个平行面的较宽的平行边缘留下连接相邻的梯形部分，使得腹板形成用于将节段折叠成环形组件的铰链。

5. 发明授权

US09252425B2 Polyacrylonitrile-sulphur composite material 有权
标题翻译：聚丙烯腈 - 硫复合材料
公开(公告)号：US09252425B2
公开(公告)日：2016-02-02
申请号：US14115248
申请日：2012-03-07
申请人： Marcus Wegner , Jens Grimminger , Martin Tenzer , Jens Fanous
发明人： Marcus Wegner , Jens Grimminger , Martin Tenzer , Jens Fanous
IPC分类号： H01M4/13 , H01M6/16 , C08C19/20 , H01M4/36 , C08F8/34 , H01M4/1399 , H01M4/04 , H01M4/137 , H01M4/60 , H01M10/39 , H01M4/38
CPC分类号： H01M4/364 , C08F8/34 , H01M4/049 , H01M4/137 , H01M4/1399 , H01M4/382 , H01M4/604 , H01M10/3954 , Y02E60/122 , C08F120/44
摘要： The invention relates to a method for preparing a polyacrylonitrile-sulfur composite material, in which, polyacrylonitrile is converted to cyclized polyacrylonitrile, and the cyclized polyacrylonitrile is reacted with sulfur to form a polyacrylonitrile-sulfur composite material. By a separation of the preparation method into two partial reactions, the reaction conditions are advantageously able to be optimized for the respective reactions and a cathode material is able to be provided for alkali-sulfur cells with improved electrochemical properties. In addition, the invention relates to a polyacrylonitrile-sulfur composite material, a cathode material, an alkali-sulfur cell or an alkali-sulfur battery as well as to an energy store.
摘要翻译：本发明涉及一种聚丙烯腈 - 硫复合材料的制备方法，其中聚丙烯腈转化为环化聚丙烯腈，环化聚丙烯腈与硫反应形成聚丙烯腈 - 硫复合材料。通过将制备方法分离成两个部分反应，反应条件有利地能够针对各个反应进行优化，并且能够提供具有改进的电化学性质的碱 - 硫电池的阴极材料。此外，本发明涉及聚丙烯腈 - 硫复合材料，阴极材料，碱硫电池或碱 - 硫电池以及能量储存器。

6. 发明授权

US4238553A Electrochemical storage cell 失效
标题翻译：电化学储存池
公开(公告)号：US4238553A
公开(公告)日：1980-12-09
申请号：US51206
申请日：1979-06-22
申请人： Gert Weddigen , Bernd Houpert , Monika Gerlach
发明人： Gert Weddigen , Bernd Houpert , Monika Gerlach
IPC分类号： H01M10/0569 , H01M10/39 , H01M10/00
CPC分类号： H01M10/0569 , H01M10/3909 , H01M10/3954
摘要： Electrochemical storage cell or battery of the alkali metal and sulfur type operable in the range from about 100.degree. C. to 200.degree. C. A solvent component is added to the cathode chamber, which solvent will at least partially dissolve sulfur and is stable under the conditions of operation.
摘要翻译：可在约100℃至200℃范围内操作的碱金属和硫型电化学储存电池或电池。向阴极室中加入溶剂组分，该溶剂将至少部分溶解硫并在操作条件

7. 发明授权

US4176447A Method for making an electrode 失效
标题翻译：电极制作方法
公开(公告)号：US4176447A
公开(公告)日：1979-12-04
申请号：US861924
申请日：1977-12-19
申请人： Michael P. J. Brennan
发明人： Michael P. J. Brennan
IPC分类号： B29C37/00 , B29C53/06 , B29C53/40 , H01M4/00 , H01M4/70 , H01M10/39 , B29C15/00 , B29C24/00
CPC分类号： H01M10/3909 , B29C53/063 , B29C53/40 , B29C70/28 , H01M4/00 , H01M4/70 , B29C37/0057 , H01M10/3954 , Y10T29/49115
摘要： In a sodium sulphur cell, a cathode electrode of annular form comprising a plurality of segments, each of trapezoidal form in cross-section is made by compressing a blanket or sheet of carbon or graphite felt or fibres in a heated mould, which is shaped to produce the segments joined by thin webs, the material being impregnated with sulphur or sodium polysulphide before or after insertion in the mould, and the material being cooled before removal from the mould. Alternatively, the segments may be formed from the blanket or sheet by using shaped rolls, the mateial being cooled, e.g., by water or air, as it leaves the rolls.
摘要翻译：在钠硫电池中，包括多个片段的环形形式的阴极电极，每个梯形形状的横截面通过在加热的模具中压缩碳或石墨毡或纤维的橡皮布或片材来制成，其被成形为生产通过薄腹板连接的节段，该材料在插入模具之前或之后被硫或多硫化钠浸渍，并且该材料在从模具中取出之前被冷却。或者，片段可以通过使用成形辊从毯子或片材形成，当材料离开辊时，材料例如由水或空气冷却。

8. 发明授权

US4118545A Sodium sulphur cells 失效
标题翻译：钠硫细胞
公开(公告)号：US4118545A
公开(公告)日：1978-10-03
申请号：US768929
申请日：1977-02-15
申请人： Ivor Wynn Jones , Graham Robinson
发明人： Ivor Wynn Jones , Graham Robinson
IPC分类号： H01M4/64 , H01M4/96 , H01M10/39 , H01M10/00
CPC分类号： H01M4/64 , H01M10/3909 , H01M4/96 , H01M10/3954
摘要： In a sodium sulphur cell having a porous matrix forming an electronic conductor in the cathodic region and extending between the surface of the solid electrolyte and a cathode current collector, this matrix is a composite comprising a first material formed of graphite or carbon of a material coated with graphite or carbon, which first material is intimately mixed with a second material, such as alumina fibres, which is more easily wetted by the polysulphides than is the first material.
摘要翻译：在具有在阴极区域形成电子导体并且在固体电解质的表面和阴极集电器之间延伸的多孔基质的钠硫电池中，该基质是包含由石墨或碳的材料形成的第一材料的复合材料与石墨或碳，第一种材料与第二种材料如氧化铝纤维密切混合，比第一种材料更容易被多硫化物润湿。

9. 发明授权

US4084042A Secondary battery or cell with polysulfide wettable electrode #1 失效
标题翻译：二次电池或带多硫化物可湿性电极的电池{190 1
公开(公告)号：US4084042A
公开(公告)日：1978-04-11
申请号：US779972
申请日：1977-03-22
申请人： Frank A. Ludwig
发明人： Frank A. Ludwig
IPC分类号： H01M4/66 , H01M10/39 , H01M10/36
CPC分类号： H01M10/3909 , H01M4/661 , H01M4/664 , H01M10/3954
摘要： An improved secondary battery or cell of the type having: (A) one or more anodic reaction zones; (B) one or more cathodic reaction zones (C) a cation-permeable barrier to mass liquid transfer interposed between and in contact with said anodic and cathodic reaction zones; and (D) an electrode which is disposed within said cathodic reaction zone. The improvement comprises employing an electrode, at least a portion of which consists essentially of a porous metal substrate which (i) is coated, at least in part, with an oxide of a metal selected from the group consisting of: (a) metals of Groups I, II and III of the Periodic Table of elements, (b) Transition Series metals, and (c) tin, lead, antimony and bismuth to a thickness which is greater than about 500 angstroms, but which results in said electrode portion having a resistivity of less than about 4 ohm-cm.sup.2, (ii) does not fill the entire volume of said cathodic reaction zone, and (iii) is, at least in part, adjacent to and contiguous with said cation-permeable barrier.
摘要翻译：一种改进的二次电池或电池，具有：（A）一个或多个阳极反应区; （B）一个或多个阴极反应区（C）介于阳极和阴极反应区之间并接触所述阳极和阴极反应区的质量液体转移的阳离子可渗透屏障; 和（D）设置在所述阴极反应区内的电极。该改进包括使用电极，其至少一部分基本上由多孔金属基底组成，（i）至少部分地用选自以下的金属的氧化物进行涂覆：（a）元素周期表I，II和III族，（b）过渡系列金属和（c）锡，铅，锑和铋的厚度大于约500埃，但是导致所述电极部分具有电阻率小于约4欧姆 - 厘米2，（ii）不填充所述阴极反应区的整个体积，和（iii）至少部分地与所述阳离子可渗透屏障相邻并邻接。

10. 发明授权

US09929432B2 Low temperature sulfur and sodium metal battery for grid-scale energy storage application 有权
公开(公告)号：US09929432B2
公开(公告)日：2018-03-27
申请号：US14385030
申请日：2013-03-15
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
发明人： Gao Liu , Dongdong Wang
IPC分类号： H01M2/00 , H01M10/054 , H01M10/056 , H01M2/16 , H01M10/0565 , H01M10/39 , H01M4/40 , H01M4/60 , H01M4/66
CPC分类号： H01M10/054 , H01M2/1653 , H01M2/1673 , H01M4/40 , H01M4/604 , H01M4/661 , H01M10/056 , H01M10/0565 , H01M10/3918 , H01M10/3954 , H01M2300/002 , H01M2300/0082
摘要： A re-chargeable battery comprising a non-dendrite forming sodium (Na)/potassium (K) liquid metal alloy anode, a sulfur and polyacrylonitrile (PAN) conductive polymer composite cathode, a polyethyleneoxide (PEO) solid electrolyte, a solid electrolyte interface (SEI) formed on the PEO solid electrolyte; and a cell housing, wherein the anode, cathode, and electrolyte are assembled into the cell housing with the PEO solid electrolyte disposed between the cathode and anode.

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