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    • 1. 发明授权
    • Thin-film electroluminescence display device
    • 薄膜电致发光显示装置
    • US5539424A
    • 1996-07-23
    • US197492
    • 1994-02-16
    • Yutaka HattoriAtsushi MizutaniNobuei ItoTadashi Hattori
    • Yutaka HattoriAtsushi MizutaniNobuei ItoTadashi Hattori
    • H05B33/12H05B33/22G09G3/30
    • H05B33/12H05B33/22
    • A thin-film EL display device of red luminescent color having high luminous intensity and high reliability is disclosed. The thin-film EL display device has a first transparent electrode, a first transparent insulating layer, a light-emitting layer of zinc sulfide (ZnS) with the addition of manganese (Mn), a red-light transmitting filter of amorphous silicon (a-Si), a second transparent insulating layer, and a second transparent electrode (second electrode), which are successively deposited one on top of another on a glass substrate. The EL display device produces red light from orange light emission from the light-emitting layer. High temperature resistance of the filter permits the insertion of the filter to a desired position during the fabrication process for the thin-film EL display device. Furthermore, since the filter characteristics of the thin-film EL display do not suffer degradation by the heat generated during the light emitting operation thereof, there is no concern for luminescent color deterioration with time.
    • 公开了一种具有高发光强度和高可靠性的红色发光颜色的薄膜EL显示装置。 薄膜EL显示装置具有第一透明电极,第一透明绝缘层,添加有锰(Mn)的硫化锌(ZnS)发光层,非晶硅的红光透射滤光片(a -Si),第二透明绝缘层和第二透明电极(第二电极),其在玻璃基板上依次彼此沉积。 EL显示装置产生来自发光层的橙色发光的红光。 过滤器的耐高温性允许在薄膜EL显示装置的制造过程中将滤光片插入所需位置。 此外,由于薄膜EL显示器的滤光器特性不会因其在发光操作期间产生的热而劣化,所以不关心发光颜色随时间劣化。
    • 2. 发明授权
    • Method and apparatus for fabricating electroluminescent device
    • 用于制造电致发光器件的方法和装置
    • US06004618A
    • 1999-12-21
    • US841334
    • 1997-04-30
    • Atsushi MizutaniMasayuki KatayamaNobuei ItoTadashi Hattori
    • Atsushi MizutaniMasayuki KatayamaNobuei ItoTadashi Hattori
    • C23C16/30C23C16/44C23C16/455H05B33/10H05B33/14B05D5/12C23C16/00
    • C23C16/45576C23C16/305H05B33/10
    • Fabrication of an electroluminescent device having a high-quality luminescent layer is disclosed. The device emits intense blue light. A first electrode layer, a first dielectric layer, the luminescent layer, a second dielectric layer, and a second electrode layer are successively formed on a glass substrate. At least the exit side of the device is made from an optically transparent material. A first gaseous source material of a group II element belonging to group II of the periodic table, a second gaseous source material of a group VIB element belonging to group VIB, and a third gaseous source material of an element forming the luminescent center of the luminescent layer are supplied into a reaction furnace through first, second, and third gas supply tubes, respectively, and caused to react with each other. Thus, the luminescent layer is formed by chemical vapor deposition. The first material acts as a base material from which the luminescent layer is formed. The first tube for the first material is laid in the center of the furnace. The third tube for the third material forming the luminescent center is laid around the first gas supply tube. The second tube is laid around the third tube.
    • 公开了具有高品质发光层的电致发光器件的制造。 该装置发出强烈的蓝光。 在玻璃基板上依次形成第一电极层,第一电介质层,发光层,第二电介质层和第二电极层。 至少装置的出口侧由光学透明材料制成。 属于元素周期表II族的第II族元素的第一气态源材料,属于VIB族的VIB族元素的第二气态源材料和形成发光体的发光中心的元素的第三气态源材料 层分别通过第一,第二和第三气体供给管供给到反应炉中,并使其彼此反应。 因此,通过化学气相沉积形成发光层。 第一材料作为形成发光层的基材。 用于第一种材料的第一管被放置在炉的中心。 形成发光中心的第三材料的第三管被放置在第一气体供应管的周围。 第二个管被放置在第三根管子周围。
    • 4. 发明授权
    • Electroluminescence element and process for fabricating same
    • 电致发光元件及其制造方法
    • US5763111A
    • 1998-06-09
    • US631158
    • 1996-04-12
    • Masayuki KatayamaAtsushi MizutaniYutaka HattoriNobuei Ito
    • Masayuki KatayamaAtsushi MizutaniYutaka HattoriNobuei Ito
    • C09K11/77H05B33/10H05B33/14H05B33/00
    • H05B33/14C09K11/776H05B33/10Y10S428/917
    • An electroluminescence element including at least an insulating substrate, a first electrode, a first insulating layer, a luminescent layer having at least one side constructed and arranged to allow light to pass out of the electroluminescence element, a second insulating layer and a second electrode in this order in a stack, with the components on the at least one side of the luminescent layer being optically transparent. The luminescent layer includes a base material formed from a II-VI compound semiconductor, at least one rare earth element, and at least one halogen element substituted for a VI group element at a lattice site of the VI group element of the II-VI compound semiconductor and located in the vicinity of the at least one rare earth element. The luminescent layer has a luminescence spectrum in which, in addition to the original emission peaks of the at least one rare earth element, some of the original emission peaks have at least one split emission peak located within a 10 nm wavelength range thereof.
    • 一种电致发光元件,其至少包括绝缘基板,第一电极,第一绝缘层,具有至少一个侧面的发光层,所述至少一个侧面构造和布置成允许光从电致发光元件中通过,第二绝缘层和第二电极 堆叠中的这种顺序与发光层的至少一侧上的组分是光学透明的。 发光层包括由II-VI化合物半导体形成的基材,至少一种稀土元素,以及在II-VI化合物的VI族元素的晶格位置取代VI族元素的至少一种卤素元素 并且位于所述至少一个稀土元素的附近。 发光层具有发光光谱,其中除了至少一种稀土元素的原始发射峰之外,一些原始发射峰具有位于其10nm波长范围内的至少一个分裂发射峰。