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1. 发明申请

US20140230317A1 In-Situ Upgrading Of Biomass Pyrolysis Vapor Using Water-Gas Shift And Hydroprocessing 审中-公开
标题翻译：使用水煤气转换和加氢处理原位升级生物质热解蒸气
公开(公告)号：US20140230317A1
公开(公告)日：2014-08-21
申请号：US13772738
申请日：2013-02-21
申请人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
发明人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
IPC分类号： C10L1/18
CPC分类号： C10L1/02 , C10B49/10 , C10B53/02 , C10G3/46 , C10G2300/4006 , C10G2300/4012 , C10G2300/42 , C10K1/026 , C10K3/02 , C10K3/04 , C10L1/023 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , C10L2290/02 , C10L2290/562 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： Processes for thermal conversion of biomass are provided. The processes involve upgrading the pyrolysis vapor from a pyrolysis reactor. The steps include thermally converting a biomass feedstock in a pyrolysis reactor, recovering a pyrolysis vapor from the reactor, passing the pyrolysis vapor in contact with a water-gas shift reaction catalyst and a hydrotreating catalyst, and converting the resulting upgraded pyrolysis vapor into a liquid product. The resulting biooil liquid product is more refined, and the overall processes offer economic and energy efficiency.
摘要翻译：提供了生物质热转化方法。这些方法包括从热解反应器升级热解蒸气。这些步骤包括在热解反应器中热转化生物质原料，从反应器回收热解蒸气，使热解蒸汽与水煤气变换反应催化剂和加氢处理催化剂接触，并将所得升级的热解蒸汽转化成液体产品。所得的生物油液体产品更加精炼，整个过程提供经济和能源效率。

2. 发明申请

US20140230316A1 In-Situ Upgrading of Biomass Pyrolysis Vapor 审中-公开
标题翻译：生物质热解蒸汽的原位升级
公开(公告)号：US20140230316A1
公开(公告)日：2014-08-21
申请号：US13772458
申请日：2013-02-21
申请人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
发明人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
IPC分类号： C10L1/18
CPC分类号： C10L1/1802 , C10G3/42 , C10K3/04 , C10L1/02 , C10L1/023 , C10L1/06 , Y02P30/20
摘要： Processes for thermal conversion of biomass are provided. The processes involve upgrading the pyrolysis vapor from a pyrolysis reactor. The steps include thermally converting a biomass feedstock in a pyrolysis reactor, recovering a pyrolysis vapor from the reactor, passing the pyrolysis vapor in contact with a cracking catalyst, a water-gas shift reaction catalyst, a hydrotreating catalyst, and an acid catalyst, and converting the resulting upgraded pyrolysis vapor into a liquid product. The resulting biooil liquid product is more refined, and the overall processes offer economic and energy efficiency.
摘要翻译：提供了生物质热转化方法。这些方法包括从热解反应器升级热解蒸气。所述步骤包括在热解反应器中热转化生物质原料，从反应器回收热解蒸气，使裂解蒸汽与裂化催化剂，水煤气变换反应催化剂，加氢处理催化剂和酸催化剂接触，以及将所得升级的热解蒸气转化成液体产物。所得的生物油液体产品更加精炼，整个过程提供经济和能源效率。

3. 发明申请

US20140230319A1 IN-SITU UPGRADING OF BIOMASS PYROLYSIS VAPOR USING ACID CATALYST AND ALCOHOL 审中-公开
标题翻译：使用酸性催化剂和酒精的生物质热解蒸发器的现场升级
公开(公告)号：US20140230319A1
公开(公告)日：2014-08-21
申请号：US13772700
申请日：2013-02-21
申请人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
发明人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
IPC分类号： C10L1/19
CPC分类号： C10L1/19 , C10G3/42 , C10G3/46 , C10G3/48 , C10G3/50 , C10G67/02 , C10G2400/02 , C10G2400/04 , C10L1/02 , Y02P30/20
摘要： Processes for thermal conversion of biomass are provided. The processes involve upgrading the pyrolysis vapor from a pyrolysis reactor. The steps include thermally converting a biomass feedstock in a pyrolysis reactor, recovering a pyrolysis vapor from the reactor, passing the pyrolysis vapor in contact with an acid catalyst in the presence of alcohol, and converting the resulting upgraded pyrolysis vapor into a liquid product. The resulting biooil liquid product is more refined, and the overall processes offer economic and energy efficiency.
摘要翻译：提供了生物质热转化方法。这些方法包括从热解反应器升级热解蒸气。这些步骤包括在热解反应器中热转化生物质原料，从反应器回收热解蒸气，使热解蒸汽在醇存在下与酸催化剂接触，并将所得升级的热解蒸汽转化成液体产物。所得的生物油液体产品更加精炼，整个过程提供经济和能源效率。

4. 发明申请

US20140230318A1 In-Situ Upgrading Of Biomass Pyrolysis Vapor By Cracking And Hydroprocessing 审中-公开
标题翻译：通过裂解和加氢处理原位升级生物质热解蒸气
公开(公告)号：US20140230318A1
公开(公告)日：2014-08-21
申请号：US13772749
申请日：2013-02-21
申请人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
发明人： Yunquan Liu , Armando Joseph Belardinelli , Curtis L. Krause
IPC分类号： C10L1/18
CPC分类号： C10L1/1802 , C10G3/42 , C10G3/46 , C10G3/48 , C10G3/50 , C10G67/02 , C10G2400/02 , C10G2400/04 , C10L1/06 , Y02P30/20
摘要： Processes for thermal conversion of biomass are provided. The processes involve upgrading the pyrolysis vapor from a pyrolysis reactor. The steps include thermally converting a biomass feedstock in a pyrolysis reactor, recovering a pyrolysis vapor from the reactor, passing the pyrolysis vapor in contact with a cracking catalyst, a water-gas shift reaction catalyst, and a hydrotreating catalyst, and converting the resulting upgraded pyrolysis vapor into a liquid product. The resulting biooil liquid product is more refined, and the overall processes offer economic and energy efficiency.
摘要翻译：提供了生物质热转化方法。这些方法包括从热解反应器升级热解蒸气。这些步骤包括在热解反应器中热转化生物质原料，从反应器回收热解蒸气，使裂解蒸气与裂化催化剂，水煤气变换反应催化剂和加氢处理催化剂接触，并将所得到的升级热解蒸气成液体产物。所得的生物油液体产品更加精炼，整个过程提供经济和能源效率。

5. 发明申请

US20080141675A1 Hybrid Combustor for Fuel Processing Applications 有权
标题翻译：燃料加工应用的混合燃烧器
公开(公告)号：US20080141675A1
公开(公告)日：2008-06-19
申请号：US11610983
申请日：2006-12-14
申请人： Yunquan Liu , Curtis L. Krause , Kevin H. Nguyen
发明人： Yunquan Liu , Curtis L. Krause , Kevin H. Nguyen
IPC分类号： F23Q11/00
CPC分类号： F23C13/06 , F23C2900/03002
摘要： The present invention discloses a hybrid combustor, such as an anode tailgas oxidizer (ATO), for fuel processing applications which combines both flame and catalytic type burners. The hybrid combustor of the present invention combines the advantages of both flame and catalytic type burners. The flame burner component of the hybrid combustor is used during start-up for the preheating of the catalytic burner component. As soon as the catalytic burner bed is preheated or lit off, the flame burner will be shut off. Optionally, the hybrid combustor may also include an integrated heat recovery unit located downstream of the catalytic burner for steam generation and for the preheating of the feed for a reformer, such as an autothermal reformer.
摘要翻译：本发明公开了一种混合式燃烧器，例如阳极尾气氧化器（ATO），用于结合火焰和催化型燃烧器的燃料处理应用。本发明的混合燃烧器结合了火焰和催化型燃烧器的优点。在启动期间使用混合燃烧器的火焰燃烧器部件来预热催化燃烧器部件。一旦催化燃烧器床被预热或点亮，火焰燃烧器将被关闭。可选地，混合式燃烧室还可以包括位于用于蒸汽产生的催化燃烧器下游并用于预热重整器例如自热重整器的进料的集成热回收单元。

6. 发明授权

US07578669B2 Hybrid combustor for fuel processing applications 有权
标题翻译：用于燃料处理应用的混合燃烧器
公开(公告)号：US07578669B2
公开(公告)日：2009-08-25
申请号：US11610983
申请日：2006-12-14
申请人： Yunquan Liu , Curtis L. Krause , Kevin H. Nguyen
发明人： Yunquan Liu , Curtis L. Krause , Kevin H. Nguyen
IPC分类号： C10L3/00 , F23D3/40
CPC分类号： F23C13/06 , F23C2900/03002
摘要： The present invention discloses a hybrid combustor, such as an anode tailgas oxidizer (ATO), for fuel processing applications which combines both flame and catalytic type burners. The hybrid combustor of the present invention combines the advantages of both flame and catalytic type burners. The flame burner component of the hybrid combustor is used during start-up for the preheating of the catalytic burner component. As soon as the catalytic burner bed is preheated or lit off, the flame burner will be shut off. Optionally, the hybrid combustor may also include an integrated heat recovery unit located downstream of the catalytic burner for steam generation and for the preheating of the feed for a reformer, such as an autothermal reformer.
摘要翻译：本发明公开了一种混合式燃烧器，例如阳极尾气氧化器（ATO），用于结合火焰和催化型燃烧器的燃料处理应用。本发明的混合燃烧器结合了火焰和催化型燃烧器的优点。在启动期间使用混合燃烧器的火焰燃烧器部件来预热催化燃烧器部件。一旦催化燃烧器床被预热或点亮，火焰燃烧器将被关闭。可选地，混合式燃烧室还可以包括位于用于蒸汽产生的催化燃烧器下游并用于预热重整器例如自热重整器的进料的集成热回收单元。

7. 发明授权

US08241374B2 Fluidized bed system for single step reforming for the production of hydrogen 有权
标题翻译：用于氢气生产的单步重整流化床系统
公开(公告)号：US08241374B2
公开(公告)日：2012-08-14
申请号：US11611638
申请日：2006-12-15
申请人： Farshad Bavarian , James F. Stevens , Balaji Krishnamurty , Yunquan Liu , Curtis L. Krause , Lixin You , Daniel G. Casey
发明人： Farshad Bavarian , James F. Stevens , Balaji Krishnamurty , Yunquan Liu , Curtis L. Krause , Lixin You , Daniel G. Casey
IPC分类号： B01J7/00 , C01B3/36 , B01D59/26
CPC分类号： F27B15/00 , B01J8/0055 , B01J8/1809 , B01J8/1863 , B01J2208/00292 , B01J2208/00752 , B01J2208/00761 , C01B3/44 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0425 , C01B2203/0475 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , C01B2203/1241 , C01B2203/1247 , C01B2203/1276 , C01B2203/148 , C01B2203/86 , C01F11/18 , Y02P10/122 , Y02P10/143 , Y02P30/30
摘要： The present invention discloses a fluidized bed system for the single step reforming technology for the production of hydrogen. Single step reforming combines the steam methane reforming, water gas shift, and carbon dioxide removal in a single step process of hydrogen generation. In the present invention, to address the heat transfer and the replenishment issues associated with single step reforming, the sorbent particles are fluidized. This fluidization allows the sorbent particles to be regenerated and consequently allows the optimal operating conditions for single step reforming to be maintained.
摘要翻译：本发明公开了一种用于生产氢气的单步重整技术的流化床系统。单步重整在氢气生成的一个单步过程中结合蒸汽甲烷重整，水煤气变换和二氧化碳去除。在本发明中，为了解决与单步重整相关的传热和补充问题，吸附剂颗粒被流化。这种流化允许吸附剂颗粒再生，因此允许保持单步重整的最佳操作条件。

8. 发明申请

US20100150794A1 SMALL DISTRIBUTED GASIFICATION UNITS WITH SYNGAS TRANSPORTATION VIA PIPELINE NETWORK FOR BIOMASS TREATMENT 有权
标题翻译：通过管道网络进行生物质处理的通过SYNGAS运输的小型分布式气化装置
公开(公告)号：US20100150794A1
公开(公告)日：2010-06-17
申请号：US12336928
申请日：2008-12-17
申请人： Paul F. Bryan , Yunquan Liu , Curtis L. Krause
发明人： Paul F. Bryan , Yunquan Liu , Curtis L. Krause
IPC分类号： B01J19/00
CPC分类号： C10J3/721 , C10J3/00 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/0956 , C10J2300/1618 , C10J2300/1659 , C10K1/004 , C10K1/008 , C10K3/026 , C10K3/04 , Y02E20/18 , Y02P20/145 , Y02P20/146
摘要： The present invention discloses a system for biomass treatment which addresses the need to find economical solutions to transport biomass. In the present invention, small, distributed gasifiers convert the biomass into synthesis gas (“syngas”). The syngas is then transported via a pipeline network to a central fuel production facility.
摘要翻译：本发明公开了一种用于生物质处理的系统，其满足了寻找运输生物质的经济解决方案的需要。在本发明中，小型分布式气化器将生物质转化为合成气（“合成气”）。合成气然后通过管道网络运输到中央燃料生产设施。

9. 发明申请

US20090165368A1 PROCESS AND APPARATUS FOR REFORMING GASEOUS AND LIQUID FUELS 审中-公开
标题翻译：用于改造气体和液体燃料的工艺和装置
公开(公告)号：US20090165368A1
公开(公告)日：2009-07-02
申请号：US12130376
申请日：2008-05-30
申请人： Yunquan Liu , Curtis L. Krause , Dennis P. Essl
发明人： Yunquan Liu , Curtis L. Krause , Dennis P. Essl
IPC分类号： C10L1/182
CPC分类号： C01B3/323 , C01B3/382 , C01B2203/0244 , C01B2203/0283 , C01B2203/043 , C01B2203/0811 , C01B2203/1229 , C01B2203/1241 , C01B2203/1276 , C01B2203/1288 , C01B2203/1604 , C01B2203/1609 , Y02P20/129
摘要： A process for transitioning from gaseous fuel reformation to liquid fuel reformation has been invented. The process comprises a series of control steps wherein an autothermal reforming reactor's temperature can substantially be stable and satisfactory hydrogen concentration and selectivity can be achieved for producer gas during the transition process. The temperature is controlled by, for example, adjusting the air and water feed. Formulas and algorithms for writing control programs have also been developed.
摘要翻译：已经发明了一种从气体燃料改造转变为液体燃料改造的过程。该方法包括一系列控制步骤，其中自热重整反应器的温度基本上是稳定的，并且可以在转变过程期间为生产气体实现令人满意的氢浓度和选择性。温度通过例如调节空气和水进料来控制。编写控制程序的公式和算法也已经开发出来。

10. 发明授权

US08062392B2 Small distributed gasification units with syngas transportation via pipeline network for biomass treatment 有权
标题翻译：小型分布式气化装置，通过管道网络进行合成气运输，用于生物质处理
公开(公告)号：US08062392B2
公开(公告)日：2011-11-22
申请号：US12336928
申请日：2008-12-17
申请人： Paul F. Bryan , Yunquan Liu , Curtis L. Krause
发明人： Paul F. Bryan , Yunquan Liu , Curtis L. Krause
IPC分类号： C10B1/00 , C10J3/00 , C10J3/72 , B01J19/00
CPC分类号： C10J3/721 , C10J3/00 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/0956 , C10J2300/1618 , C10J2300/1659 , C10K1/004 , C10K1/008 , C10K3/026 , C10K3/04 , Y02E20/18 , Y02P20/145 , Y02P20/146
摘要： The present invention discloses a system for biomass treatment which addresses the need to find economical solutions to transport biomass. In the present invention, small, distributed gasifiers convert the biomass into synthesis gas (“syngas”). The syngas is then transported via a pipeline network to a central fuel production facility.
摘要翻译：本发明公开了一种用于生物质处理的系统，其满足了寻找运输生物质的经济解决方案的需要。在本发明中，小型分布式气化器将生物质转化为合成气（“合成气”）。合成气然后通过管道网络运输到中央燃料生产设施。

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