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1. 发明授权

US08494772B2 Method for calculating hydrogen storage inventory 有权
标题翻译：储氢库存计算方法
公开(公告)号：US08494772B2
公开(公告)日：2013-07-23
申请号：US11749838
申请日：2007-05-17
申请人： Daniel G. Casey , Brandon W. Janak , Paul D. Burger
发明人： Daniel G. Casey , Brandon W. Janak , Paul D. Burger
IPC分类号： G01F22/02 , G06Q10/08 , G06F17/40 , G06F19/00
CPC分类号： F17C13/023 , F17C2203/0639 , F17C2203/0663 , F17C2221/012 , F17C2223/0123 , F17C2223/036 , F17C2250/0408 , F17C2250/0421 , F17C2250/043 , F17C2250/0439 , F17C2250/0495 , F17C2260/026 , F17C2270/0139 , Y02E60/321
摘要： Methods for accurately and conveniently calculating the inventory of hydrogen storage in a stationary storage vessel using the external ambient temperature and the internal pressure are disclosed in the present invention. To account for the delay in the heat transfer from the ambient air to the storage vessel and then to the hydrogen gas a first order filter can be used on the external ambient temperature. Following the application of the first order filter on the external ambient temperature, an empirical equation is used to calculate the mass of hydrogen in the stationary storage vessel.
摘要翻译：在本发明中公开了使用外部环境温度和内部压力来精确和方便地计算固定储存容器中的储氢库存的方法。为了解决从环境空气到储存容器的热传递的延迟，然后考虑到氢气，可以在外部环境温度下使用一级过滤器。在第一阶滤波器应用于外部环境温度之后，使用经验方程来计算固定储存容器中的氢气质量。

2. 发明授权

US08119299B2 Coolant system for fuel processor 有权
标题翻译：燃油处理器冷却液系统
公开(公告)号：US08119299B2
公开(公告)日：2012-02-21
申请号：US10954679
申请日：2004-09-30
申请人： Hongqiao (Bruce) Sun , W. Spencer Wheat , Vesna R. Mirkovic , Daniel G. Casey
发明人： Hongqiao (Bruce) Sun , W. Spencer Wheat , Vesna R. Mirkovic , Daniel G. Casey
IPC分类号： H01M8/04
CPC分类号： B01J8/0285 , B01J8/0496 , B01J2208/00141 , B01J2208/00168 , B01J2208/0053 , B01J2219/00083 , B01J2219/00087 , C01B3/382 , C01B3/48 , C01B3/56 , C01B2203/0244 , C01B2203/0283 , C01B2203/042 , C01B2203/044 , C01B2203/047 , C01B2203/0485 , C01B2203/066 , C01B2203/0844 , C01B2203/0883 , C01B2203/146 , H01M8/0612 , H01M8/0668 , H01M2008/1095 , Y02P20/129
摘要： A coolant subsystem for use in a fuel processor and a method for its operation are disclosed. In accordance with a first aspect, the coolant subsystem is separate from the feed to the processor reactor and is capable of circulating a coolant through the processor reactor. In accordance with a second aspect, the constituent elements of the fuel processor are housed in a cabinet, and the coolant subsystem is capable of cooling both the processor reactor and the interior of the cabinet. In various alternatives, the fuel processor can be employed to reform a fuel for a fuel cell power plant and/or may be used to provide thermal control for unrelated mechanical systems.
摘要翻译：公开了一种用于燃料处理器的冷却剂子系统及其操作方法。根据第一方面，冷却剂子系统与供给到处理器反应器的进料分离，并且能够使冷却剂循环通过处理器反应器。根据第二方面，燃料处理器的组成元件容纳在机柜中，并且冷却剂子系统能够冷却处理器反应器和机柜的内部。在各种替代方案中，燃料处理器可用于改造用于燃料电池发电厂的燃料和/或可用于为不相关的机械系统提供热控制。

3. 发明授权

US07593788B2 Automated control strategy for fuel processor reactor shift catalyst regeneration 有权
标题翻译：燃料处理器反应器转换催化剂再生的自动控制策略
公开(公告)号：US07593788B2
公开(公告)日：2009-09-22
申请号：US11016676
申请日：2004-12-17
申请人： Hongqiao Sun , Daniel G. Casey , Vesna R. Mirkovic , Bhaskar Balasubramanian , W. Spencer Wheat , Curtis L. Krause
发明人： Hongqiao Sun , Daniel G. Casey , Vesna R. Mirkovic , Bhaskar Balasubramanian , W. Spencer Wheat , Curtis L. Krause
IPC分类号： G05B21/00 , C10J3/46 , G01N35/08
CPC分类号： H01M8/04992 , G05B19/0421 , G05B2219/2208 , G05B2219/2668 , H01M8/04223 , H01M8/04225 , H01M8/04228 , H01M8/04302 , H01M8/04303 , H01M8/0612 , H01M8/0662 , Y10T436/11 , Y10T436/115831 , Y10T436/12
摘要： A method and apparatus for use in regenerating a reactor shift bed catalyst are disclosed. The method comprises monitoring the saturation level of a reactor shift bed catalyst in a reformer; automatically detecting that the reactor shift bed catalyst has entered a saturated state; and automatically regenerating the reactor shift bed catalyst in response to automatically detecting the saturated state. The apparatus may be, in various aspects, a program storage method encoded with instructions that, when executed by a computing device, performs such a method; a computing apparatus programmed to perform such a method, or a control system performing such a method.
摘要翻译：公开了一种用于再生反应器换床催化剂的方法和装置。该方法包括监测重整器中反应器换档床催化剂的饱和水平; 自动检测反应器换档床催化剂已进入饱和状态; 并响应于自动检测饱和状态而自动再生反应器换档床催化剂。该装置可以是在各种方面的编码有指令的程序存储方法，所述指令在由计算装置执行时执行这种方法; 被编程为执行这种方法的计算装置，或执行这种方法的控制系统。

4. 发明申请

US20080145309A1 Fluidized Bed System for Single Step Reforming for the Production of Hydrogen 有权
标题翻译：用于氢气生产的单步重整流化床系统
公开(公告)号：US20080145309A1
公开(公告)日：2008-06-19
申请号：US11611638
申请日：2006-12-15
申请人： Farshad Bavarian , James F. Stevens , Balaji Krishnamurty , Yunquan Liu , Curtis L. Krause , Lixin You , Daniel G. Casey
发明人： Farshad Bavarian , James F. Stevens , Balaji Krishnamurty , Yunquan Liu , Curtis L. Krause , Lixin You , Daniel G. Casey
IPC分类号： F27B15/00
CPC分类号： F27B15/00 , B01J8/0055 , B01J8/1809 , B01J8/1863 , B01J2208/00292 , B01J2208/00752 , B01J2208/00761 , C01B3/44 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0425 , C01B2203/0475 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , C01B2203/1241 , C01B2203/1247 , C01B2203/1276 , C01B2203/148 , C01B2203/86 , C01F11/18 , Y02P10/122 , Y02P10/143 , Y02P30/30
摘要： The present invention discloses a fluidized bed system for the single step reforming technology for the production of hydrogen. Single step reforming combines the steam methane reforming, water gas shift, and carbon dioxide removal in a single step process of hydrogen generation. In the present invention, to address the heat transfer and the replenishment issues associated with single step reforming, the sorbent particles are fluidized. This fluidization allows the sorbent particles to be regenerated and consequently allows the optimal operating conditions for single step reforming to be maintained.
摘要翻译：本发明公开了一种用于生产氢气的单步重整技术的流化床系统。单步重整在氢气生成的一个单步过程中结合蒸汽甲烷重整，水煤气变换和二氧化碳去除。在本发明中，为了解决与单步重整相关的传热和补充问题，吸附剂颗粒被流化。这种流化允许吸附剂颗粒再生，因此允许保持单步重整的最佳操作条件。

5. 发明申请

US20080127554A1 APPARATUS AND METHOD FOR PRODUCING HYDROGEN 失效
标题翻译：用于生产氢的装置和方法
公开(公告)号：US20080127554A1
公开(公告)日：2008-06-05
申请号：US12027587
申请日：2008-02-07
申请人： Dean A. Kenefake , W. Spencer Wheat , Hongqiao Sun , Bhaskar Balasubramanian , Vesna R. Mirkovic , Daniel G. Casey
发明人： Dean A. Kenefake , W. Spencer Wheat , Hongqiao Sun , Bhaskar Balasubramanian , Vesna R. Mirkovic , Daniel G. Casey
IPC分类号： C10J1/20
CPC分类号： C01B3/38 , C01B3/501 , C01B3/56 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/0455 , C01B2203/047 , C01B2203/0485 , C01B2203/066 , C01B2203/1241 , C01B2203/16 , C01B2203/1604 , C01B2203/1628
摘要： An apparatus and method for producing a hydrogen-enriched reformate. The apparatus includes a fuel processor for converting a fuel to a reformate having fluctuations in pressure and or flow rate, means for reducing the fluctuations, a compression unit for compressing the reformate and one or more of a purification unit and a storage unit downstream of a compression unit. Means for reducing the fluctuations in the reformate can include one or more of a buffer and a conduit for providing a controlled flow of a supplemental fluid to an inlet of the compression unit. The supplemental fluid can include the compressed reformate, a hydrogen-enriched reformate, and mixtures thereof. The apparatus can include means for regulating power to the compression unit that can incrementally increase power to the compression unit particularly during start up. The purification unit can include one or more of a hydrogen selective membrane and a pressure swing adsorption unit. Methods for producing hydrogen are also disclosed.
摘要翻译：一种生产富氢重整产品的装置和方法。该装置包括用于将燃料转化为具有压力和/或流速波动的重整产品的燃料处理器，用于减少波动的装置，用于压缩重整产品的压缩单元和净化单元和存储单元下游的一个或多个压缩单元。用于减少重整产品波动的方法可以包括一个或多个缓冲器和用于向压缩单元的入口提供受控流动的补充流体的导管。补充流体可以包括压缩的重整油，富氢重整油及其混合物。该装置可以包括用于调节压缩单元的功率的装置，其可以增量地增加对压缩单元的功率，特别是在启动期间。净化单元可以包括氢选择性膜和变压吸附单元中的一种或多种。还公开了生产氢的方法。

6. 发明授权

US5227569A Skeletal isomerization of n-butylenes to isobutylene on boron-beta zeolites 失效
标题翻译：正丁烯在硼-β沸石上的异构异构化
公开(公告)号：US5227569A
公开(公告)日：1993-07-13
申请号：US747054
申请日：1991-08-19
申请人： Chi-Lin O'Young , John Hazen , Daniel G. Casey
发明人： Chi-Lin O'Young , John Hazen , Daniel G. Casey
IPC分类号： C07C5/27
CPC分类号： C07C5/2775 , Y02P20/125
摘要： Normal olefins such as n-butenes can be converted to iso olefins such as isobutylene by skeletal isomerization over catalysts of boron-beta zeolites having pore sizes of at least about 5 Angstroms and containing boron in the framework structure thereof. The boron-beta zeoliteS have sufficient acidity to catalyze the skeletal isomerization of normal olefinsto iso-olefins. The catalysts can be used to produce iso-olefins for reaction with alcohols in integrated processes to produce alkyl tertiary alkyl ethers such as MTBE.
摘要翻译：正丁烯如正丁烯可以通过骨架异构化在具有至少约5埃的孔径的硼-β沸石的催化剂上在其框架结构中含有硼而转化成异烯烃，例如异丁烯。硼-β沸石具有足够的酸度来催化正烯烃异构烯烃的骨架异构化。催化剂可用于生产异构烯烃，用于与醇在一体化方法中反应，生成烷基叔烷基醚如MTBE。

7. 发明授权

US08426071B2 Method and apparatus for separating liquid from a gas stream 失效
标题翻译：从气流中分离液体的方法和装置
公开(公告)号：US08426071B2
公开(公告)日：2013-04-23
申请号：US11752758
申请日：2007-05-23
申请人： William Spencer Wheat , David Wayne Harrison, Sr. , Daniel G. Casey , Kerry Kennedy Spilker
发明人： William Spencer Wheat , David Wayne Harrison, Sr. , Daniel G. Casey , Kerry Kennedy Spilker
IPC分类号： H01M8/06 , B01D45/12
CPC分类号： G05D9/12 , B01D45/12 , B04C5/14 , B04C11/00 , H01M8/04022 , H01M8/04164 , H01M2008/1095 , Y02P70/56
摘要： An apparatus for separating liquid from a gas stream. The apparatus includes an elongated housing having a cylindrical inner surface and a gas stream inlet that is tangential to the side wall of the housing so as to cause the entering gas stream to swirl within the housing. A gas stream outlet is located at the top of the housing and a liquid outlet at the bottom. The gas stream outlet can include an elongated tubular member that extends into the housing and has an opening that is located below the housing gas stream inlet. Liquid components of the gas stream separate from the stream under the influence of centrifugal forces that are created by the swirling flow path of the stream within the housing. A liquid outlet and liquid outlet valve are provided for maintaining a minimum level of liquid within the housing so as to maintain a liquid seal within the housing. A level indicator may optionally be provided to monitor the liquid level within the housing. A power generation apparatus having two or more of the separators for separating liquid from fuel cell and fuel processor streams. Methods for manufacturing an apparatus for removing liquid from a gas stream and methods for separating liquid from a gas stream are also provided.
摘要翻译：一种用于从气流中分离液体的装置。该装置包括具有圆柱形内表面和与壳体的侧壁相切的气流入口的细长壳体，以使进入的气流在壳体内旋转。气流出口位于壳体的顶部，底部有液体出口。气流出口可以包括延伸到壳体中并具有位于壳体气流入口下方的开口的细长管状构件。气流的液体组分在由流体在壳体内的旋流流动路径产生的离心力的影响下与流分离。提供液体出口和液体出口阀，用于将液体保持在壳体内的最低水平，以便在壳体内保持液体密封。可以可选地提供液位指示器来监测壳体内的液位。具有两个或更多个用于从燃料电池和燃料处理器流分离液体的分离器的发电装置。还提供了制造用于从气流中除去液体的装置的方法和从气流中分离液体的方法。

8. 发明授权

US07354464B2 Apparatus and method for producing hydrogen 有权
标题翻译：用于生产氢的装置和方法
公开(公告)号：US07354464B2
公开(公告)日：2008-04-08
申请号：US11015588
申请日：2004-12-17
申请人： Dean A. Kenefake , W. Spencer Wheat , Hongqiao Sun , Bhaskar Balasubramanian , Vesna R. Mirkovic , Daniel G. Casey
发明人： Dean A. Kenefake , W. Spencer Wheat , Hongqiao Sun , Bhaskar Balasubramanian , Vesna R. Mirkovic , Daniel G. Casey
IPC分类号： C10L3/00 , B01J8/04
CPC分类号： C01B3/38 , C01B3/501 , C01B3/56 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/0455 , C01B2203/047 , C01B2203/0485 , C01B2203/066 , C01B2203/1241 , C01B2203/16 , C01B2203/1604 , C01B2203/1628
摘要： An apparatus and method for producing a hydrogen-enriched reformate. The apparatus includes a fuel processor for converting a fuel to a reformate having fluctuations in pressure and or flow rate, means for reducing the fluctuations, a compression unit for compressing the reformate and one or more of a purification unit and a storage unit downstream of a compression unit. Means for reducing the fluctuations in the reformate can include one or more of a buffer and a conduit for providing a controlled flow of a supplemental fluid to an inlet of the compression unit. The supplemental fluid can include the compressed reformate, a hydrogen-enriched reformate, and mixtures thereof. The apparatus can include means for regulating power to the compression unit that can incrementally increase power to the compression unit particularly during start up. The purification unit can include one or more of a hydrogen selective membrane and a pressure swing adsorption unit. Methods for producing hydrogen are also disclosed.
摘要翻译：一种生产富氢重整产品的装置和方法。该装置包括用于将燃料转化为具有压力和/或流速波动的重整产品的燃料处理器，用于减少波动的装置，用于压缩重整产品的压缩单元和净化单元和存储单元下游的一个或多个压缩单元。用于减少重整产品波动的方法可以包括一个或多个缓冲器和用于向压缩单元的入口提供受控流动的补充流体的导管。补充流体可以包括压缩的重整油，富氢重整油及其混合物。该装置可以包括用于调节压缩单元的功率的装置，其可以增量地增加对压缩单元的功率，特别是在启动期间。净化单元可以包括氢选择性膜和变压吸附单元中的一种或多种。还公开了生产氢的方法。

9. 发明授权

US07081144B2 Autothermal reforming in a fuel processor utilizing non-pyrophoric shift catalyst 失效
标题翻译：使用非自燃变换催化剂的燃料处理器中的热重整
公开(公告)号：US07081144B2
公开(公告)日：2006-07-25
申请号：US10408001
申请日：2003-04-04
申请人： W. Spencer Wheat , Vesna R. Mirkovic , Kevin H. Nguyen , Curtis L. Krause , James F. Stevens , Daniel G. Casey
发明人： W. Spencer Wheat , Vesna R. Mirkovic , Kevin H. Nguyen , Curtis L. Krause , James F. Stevens , Daniel G. Casey
IPC分类号： C01B3/36
CPC分类号： B01J8/0453 , B01J8/025 , B01J8/0496 , B01J19/0013 , B01J19/0033 , B01J19/24 , B01J2208/00132 , B01J2208/00141 , B01J2208/00203 , B01J2208/00398 , B01J2208/00415 , B01J2208/0053 , B01J2208/00646 , B01J2208/00716 , B01J2208/00849 , B01J2219/00263 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/066 , C01B2203/0844 , C01B2203/127 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/169 , H01M8/0618 , H01M8/0668 , H01M2008/1095
摘要： A method for start-up and shut down of a fuel processor including an autothermal reformer employing a non-pyrophoric shift catalyst is disclosed. Also disclosed are a computer programmed to start-up or shut down a fuel processor including an autothermal reformer employing a non-pyrophoric shift catalyst or a program storage medium encoded with instruction that, when executed by a computer, start-up or shut down a fuel processor including an autothermal reformer employing a non-pyrophoric shift catalyst.
摘要翻译：公开了一种用于启动和关闭包括使用非自发变换催化剂的自热重整器的燃料处理器的方法。还公开了一种被编程为启动或关闭燃料处理器的计算机，该燃料处理器包括采用非自燃变换催化剂的自热重整器或编码有指令的程序存储介质，当由计算机执行时，启动或关闭燃料处理器包括采用非自燃变换催化剂的自热重整器。

10. 发明授权

US07857875B2 Autothermal reforming in a fuel processor utilizing non-pyrophoric shift catalyst 有权
标题翻译：使用非自燃变换催化剂的燃料处理器中的热重整
公开(公告)号：US07857875B2
公开(公告)日：2010-12-28
申请号：US11432068
申请日：2006-05-11
申请人： W. Spencer Wheat , Vesna R. Mirkovic , Kevin H. Nguyen , Curtis L. Krause , James F. Stevens , Daniel G. Casey
发明人： W. Spencer Wheat , Vesna R. Mirkovic , Kevin H. Nguyen , Curtis L. Krause , James F. Stevens , Daniel G. Casey
IPC分类号： C01B3/36 , C10J3/46 , C10J3/54 , H01M8/06 , H01M8/04 , F23N5/20 , F23N5/22 , F23N5/00 , F23D11/38
CPC分类号： B01J8/0453 , B01J8/025 , B01J8/0496 , B01J19/0013 , B01J19/0033 , B01J19/24 , B01J2208/00132 , B01J2208/00141 , B01J2208/00203 , B01J2208/00398 , B01J2208/00415 , B01J2208/0053 , B01J2208/00646 , B01J2208/00716 , B01J2208/00849 , B01J2219/00263 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/066 , C01B2203/0844 , C01B2203/127 , C01B2203/1604 , C01B2203/1609 , C01B2203/1619 , C01B2203/169 , H01M8/0618 , H01M8/0668 , H01M2008/1095
摘要： A method for start-up and shut down of a fuel processor including an autothermal reformer employing a non-pyrophoric shift catalyst is disclosed. Also disclosed are a computer programmed to start-up or shut down a fuel processor including an autothermal reformer employing a non-pyrophoric shift catalyst or a program storage medium encoded with instruction that, when executed by a computer, start-up or shut down a fuel processor including an autothermal reformer employing a non-pyrophoric shift catalyst.
摘要翻译：公开了一种用于启动和关闭包括使用非自发变换催化剂的自热重整器的燃料处理器的方法。还公开了一种被编程为启动或关闭燃料处理器的计算机，该燃料处理器包括采用非自燃变换催化剂的自热重整器或编码有指令的程序存储介质，当由计算机执行时，启动或关闭燃料处理器包括采用非自燃变换催化剂的自热重整器。

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