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    • 2. 发明申请
    • Method of manufacturing a semiconductor device and substrate processing apparatus
    • 半导体器件和衬底处理设备的制造方法
    • US20100297846A1
    • 2010-11-25
    • US12801082
    • 2010-05-20
    • Yukinao KagaTatsuyuki SaitoMasanori Sakai
    • Yukinao KagaTatsuyuki SaitoMasanori Sakai
    • H01L21/285C23C16/06C23C16/34
    • H01L21/28562C23C16/34C23C16/45527C23C16/45544H01L21/76841
    • A method of manufacturing a semiconductor device includes the steps of: forming a first metal film on the substrate placed in a processing chamber by alternately supplying at least one type of a metal compound that is an inorganic raw material and a reactant gas that has reactivity to the metal compound to the processing chamber more than once; forming a second metal film on the substrate by simultaneously supplying at least one type of a metal compound that is an inorganic raw material and a reactant gas that has reactivity to the metal compound to the processing chamber once so that the metal compound and the reactant gas are mixed with each other; and modifying at least one of the first metal film and the second metal film is modified using at least one of the reactant gas and an inert gas after at least one of the alternate supply process and the simultaneous supply process. It thus becomes possible to provide a dense, low-resistive metal film having a smooth film surface with a better quality in comparison with a titanium nitride film formed by the CVD method at a higher deposition rate, that is, at a higher productivity, in comparison with a titanium nitride film formed by the ALD method at a low temperature.
    • 一种制造半导体器件的方法包括以下步骤:通过交替地供给至少一种作为无机原料的金属化合物和具有反应性的反应物气体,在放置在处理室中的基板上形成第一金属膜 金属化合物对处理室不止一次; 通过同时将至少一种作为无机原料的金属化合物和与金属化合物具有反应性的反应物气体同时供给到处理室,从而在基板上形成第二金属膜,使得金属化合物和反应气体 相互混合; 并且在交替供给处理和同时供给处理中的至少一个之后,使用至少一种反应气体和惰性气体来修饰第一金属膜和第二金属膜中的至少一个。 因此,与通过CVD法形成的氮化钛膜以更高的生产率,即更高的生产率相比,可以提供具有光滑膜表面的致密的低电阻金属膜,具有更好的质量 与在低温下通过ALD法形成的氮化钛膜进行比较。
    • 5. 发明授权
    • Method of manufacturing semiconductor device, cleaning method, and substrate processing apparatus
    • 半导体装置的制造方法,清洗方法以及基板处理装置
    • US09238257B2
    • 2016-01-19
    • US12862180
    • 2010-08-24
    • Masanori SakaiYukinao KagaTakashi YokogawaTatsuyuki Saito
    • Masanori SakaiYukinao KagaTakashi YokogawaTatsuyuki Saito
    • H01L21/00B08B7/00H01L21/67C23C16/44H01L21/285
    • B08B7/00C23C16/4404C23C16/4405H01L21/28562H01L21/67028
    • It is possible to efficiently remove deposited materials such as a conductive film or insulting film adhered to parts such as the inner wall of a processing chamber and a substrate supporting tool disposed in the processing chamber. There is provided a method of manufacturing a semiconductor device. The method comprises: loading a substrate into a processing chamber; forming a conductive film or an insulating film on the substrate by supplying a plurality of source gases into the processing chamber; unloading the substrate from the processing chamber; and modifying a conductive film or an insulating film adhered to the processing chamber by supplying a modifying gas into the processing chamber. After performing a cycle of the loading, the forming, the unloading, and the modifying processes a plurality of times, the modified conductive film or the modified insulating film adhered to the processing chamber is removed from the processing chamber by supplying a cleaning gas into the processing chamber.
    • 可以有效地除去附着在处理室的内壁和设置在处理室中的基板支撑工具等部分的导电膜或绝缘膜等沉积材料。 提供了制造半导体器件的方法。 该方法包括:将基板装载到处理室中; 通过将多个源气体供应到所述处理室中,在所述基板上形成导电膜或绝缘膜; 从处理室卸载基板; 以及通过向所述处理室供应修饰气体来修饰粘附到所述处理室的导电膜或绝缘膜。 在进行加载循环之后,多次进行成形,卸载和修改处理,通过将清洁气体供给到处理室中而将附着到处理室的改性导电膜或改性绝缘膜从处理室中除去 处理室。
    • 6. 发明授权
    • Substrate processing apparatus and method of manufacturing semiconductor device
    • 基板处理装置及半导体装置的制造方法
    • US08808455B2
    • 2014-08-19
    • US13014419
    • 2011-01-26
    • Tatsuyuki SaitoMasanori SakaiYukinao KagaTakashi Yokogawa
    • Tatsuyuki SaitoMasanori SakaiYukinao KagaTakashi Yokogawa
    • C23C16/455C23C16/52C23C16/00H01L21/00H01L21/02C23C16/30H01L23/482H01L21/3205
    • C23C16/455C23C16/301C23C16/303C23C16/45578C23C16/52H01L21/00H01L21/02186H01L21/3205H01L23/482H01L2924/0002H01L2924/00
    • Provided are a substrate processing apparatus and a method of manufacturing a semiconductor device which are able to form a conductive film, which is dense, includes a low concentration of source-derived impurities and has low resistivity, at a higher film-forming rate. The substrate processing apparatus includes a processing chamber configured to stack and accommodate a plurality of substrates; a first processing gas supply system configured to supply a first processing gas into the processing chamber; a second processing gas supply system configured to supply a second processing gas into the processing chamber; and a control unit configured to control the first processing gas supply system and the second processing gas supply system. Here, at least one of the first processing gas supply system and the second processing gas supply system includes two nozzles which are vertically arranged in a stacking direction of the substrates and have different shapes, and the control unit is configured to supply at least one of the first processing gas and the second processing gas into the processing chamber through the two nozzles having different shapes when films are formed on the substrates by supplying the first processing gas and the second processing gas into the processing chamber at pulses having different film-forming rates.
    • 本发明提供一种能够形成导电膜的基板处理装置和半导体装置的制造方法,所述半导体装置在较高的成膜速率下能够形成致密的导电膜,其包含低浓度源源杂质并具有低电阻率。 基板处理装置包括:处理室,被配置为堆叠并容纳多个基板; 第一处理气体供应系统,被配置为将第一处理气体供应到所述处理室中; 第二处理气体供应系统,被配置为将第二处理气体供应到所述处理室中; 以及控制单元,被配置为控制第一处理气体供应系统和第二处理气体供应系统。 这里,第一处理气体供给系统和第二处理气体供给系统中的至少一个包括沿基板的堆叠方向垂直配置的两个喷嘴,并且具有不同的形状,并且控制单元被配置为提供至少一个 当通过在具有不同成膜速率的脉冲下将第一处理气体和第二处理气体供应到处理室中时,通过具有不同形状的两个喷嘴将第一处理气体和第二处理气体输送到处理室中, 。