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1. 发明授权

US5686505A Process and apparatus for surface treatment of unvulcanized rubber sheet 失效
标题翻译：未硫化橡胶片表面处理工艺及装置
公开(公告)号：US5686505A
公开(公告)日：1997-11-11
申请号：US569010
申请日：1995-12-07
申请人： Yukihiro Kusano , Mahito Fuji , Masato Yoshikawa , Kazuo Naito , Fumihiro Matsuyama , Yoshio Nohara , Setsuo Akiyama
发明人： Yukihiro Kusano , Mahito Fuji , Masato Yoshikawa , Kazuo Naito , Fumihiro Matsuyama , Yoshio Nohara , Setsuo Akiyama
IPC分类号： B29C35/08 , C08J3/24 , C08J3/28
CPC分类号： C08J3/243 , B29C2035/0822 , B29L2030/002 , C08J2321/00
摘要： Only an outer surface of an unvulcanized rubber sheet is preliminarily crosslinked by irradiating an infrared ray or a far infrared ray to the unvulcanized rubber sheet prior to subsequent final vulcanization, whereby the occurrence of rubber spew and rubber flash is considerably suppressed at the vulcanization step.
摘要翻译：未硫化橡胶片的外表面通过在随后的最终硫化之前将红外线或远红外线照射到未硫化橡胶片而预先交联，从而在硫化步骤中显着地抑制橡胶喷射和橡胶闪光的发生。

2. 发明授权

US5316739A Method and apparatus for surface treatment 失效
标题翻译：表面处理方法和装置
公开(公告)号：US5316739A
公开(公告)日：1994-05-31
申请号：US932382
申请日：1992-08-19
申请人： Masato Yoshikawa , Yukihiro Kusano , Setsuo Akiyama , Kazuo Naito , Satiko Okazaki , Masuhiro Kogoma
发明人： Masato Yoshikawa , Yukihiro Kusano , Setsuo Akiyama , Kazuo Naito , Satiko Okazaki , Masuhiro Kogoma
IPC分类号： B29C59/14 , H01J37/32 , B01J19/08 , H05H1/24
CPC分类号： H05H1/24 , B29C59/14 , H01J37/32082 , H01J37/32761 , B29C2059/145 , B29K2021/00 , H01J2237/336 , H05H2245/123
摘要： Disclosed herein is a method for surface treatment which comprises subjecting an object for surface treatment to an atmospheric pressure plasma while rolling or floating said object in an insulating vessel fed with a prescribed gas and provided on the outside thereof or on both the outside and inside thereof with electrodes for voltage application and grounding, said atmospheric pressure plasma occurring upon application of a voltage to said electrodes. This method permits simple, certain, and uniform surface treatment of any objects in the form of lump or sphere. The surface treatment by the atmospheric pressure plasma does not need the apparatus to be evacuated. Therefore, it can be carried out in a simple apparatus without causing the object for surface treatment to release volatile matters.Disclosed also herein is a method for the surface treatment of vulcanized rubber with an atmospheric pressure plasma in the presence of an oxygen-containing gas and halogen containing gases. This method is simple and permits the surface treatment of vulcanized rubber in a clean environment. The surface treatment by this method provides the vulcanized rubber with a surface having better adhesion properties than the surface treatment with a low-pressure glow plasma. Moreover, the surface treatment is limited only to a very thin surface layer, with the vulcanized rubber itself remaining intact.
摘要翻译：本发明公开了一种表面处理方法，其特征在于，在进行了规定气体的绝缘容器的滚动或浮动的同时将其进行表面处理的物体进行表面处理，并且设置在其外侧或其外部和内部具有用于施加电压和接地的电极，所述大气压等离子体在对所述电极施加电压时发生。这种方法允许以块状或球形的形式对任何物体进行简单，确定和均匀的表面处理。通过大气压等离子体的表面处理不需要抽真空的装置。因此，可以在简单的装置中进行，而不会导致表面处理物体释放挥发性物质。本文还公开了在含氧气体和含卤素气体的存在下用大气压等离子体表面处理硫化橡胶的方法。该方法简单，可在干净的环境中对硫化橡胶进行表面处理。通过该方法进行的表面处理为硫化橡胶提供了具有比用低压辉光等离子体进行的表面处理更好的粘合性能的表面。此外，表面处理仅限于非常薄的表面层，硫化橡胶本身保持完整。

3. 发明授权

US5466424A Corona discharge surface treating method 失效
标题翻译：电晕放电表面处理方法
公开(公告)号：US5466424A
公开(公告)日：1995-11-14
申请号：US174436
申请日：1993-12-28
申请人： Yukihiro Kusano , Tomoko Inagaki , Masato Yoshikawa , Setsuo Akiyama , Kazuo Naitoh
发明人： Yukihiro Kusano , Tomoko Inagaki , Masato Yoshikawa , Setsuo Akiyama , Kazuo Naitoh
IPC分类号： A63B37/00 , A63B37/14 , B01J19/08 , B05D3/14 , B29C59/12 , C08J7/00 , C08J7/12 , B05D3/06
CPC分类号： C08J7/123 , B05D3/144 , B29C59/12 , A63B37/0003 , A63B37/14 , B29K2021/00 , B29K2105/24
摘要： A surface treating method is described, which method comprising applying, between electrodes, a potential sufficient to cause corona discharge to occur in the presence of a gas which comprises molecules containing at least one atom selected from the group consisting of halogen atom, oxygen atom and nitrogen atom. The resultant corona discharge is applied to an object to be treated for the surface treatment of the object, said object being outside said electrodes. The excellent adhesive surface can be obtained when said object is separated from said electrodes at a distance in the range of 10 mm to 5 m.
摘要翻译：描述了一种表面处理方法，该方法包括在电极之间施加足以在气体存在下发生电晕放电的电势，所述气体包含含有至少一个选自卤原子，氧原子和氮原子。所得到的电晕放电被施加到被处理物体进行物体的表面处理，所述物体在所述电极之外。当所述物体与所述电极分离在10mm至5μm范围内的距离时，可以获得优异的粘合表面。

4. 发明授权

US5403419A Method for making rubbery composite materials by plating a plastic substrate with cobalt 失效
标题翻译：通过用钴电镀塑料基材来制备橡胶复合材料的方法
公开(公告)号：US5403419A
公开(公告)日：1995-04-04
申请号：US38074
申请日：1993-03-29
申请人： Masato Yoshikawa , Yukio Fukuura , Setsuo Akiyama , Makoto Nakamura , Kazuo Naito , Toshio Honda
发明人： Masato Yoshikawa , Yukio Fukuura , Setsuo Akiyama , Makoto Nakamura , Kazuo Naito , Toshio Honda
IPC分类号： B32B15/06 , C04B41/52 , C04B41/89 , C08J5/12 , C23C28/00 , C25D5/54 , B60C9/00
CPC分类号： C04B41/009 , B32B15/06 , C04B41/52 , C04B41/89 , C08J5/12 , C23C28/00 , C08J2321/00 , Y10S156/91 , Y10T428/12937 , Y10T428/31707
摘要： A rubbery composite material comprising a substrate and a rubber composition bonded thereto is prepared by metallizing a substrate with a thin film of zinc, copper, cobalt or an alloy thereof by dry plating such as vacuum deposition, ion plating, DC magnetron sputtering, bipolar sputtering, and RF sputtering processes, and pressing a vulcanizable rubber composition to the metallized substrate under heat and pressure to effect vulcanization bonding.
摘要翻译：通过例如真空沉积，离子镀，直流磁控溅射，双极溅射等干式电镀，通过用锌，铜，钴或其合金的薄膜对基板进行金属化来制备包含基材和与其结合的橡胶组合物的橡胶状复合材料和RF溅射工艺，并且在加热和加压下将可硫化橡胶组合物压制到金属化基底上以实现硫化粘合。

5. 发明授权

US4872932A Method for making rubbery composite materials by plating a metal substrate with a cobalt alloy 失效
标题翻译：通过用钴合金电镀金属基材来制备橡胶复合材料的方法
公开(公告)号：US4872932A
公开(公告)日：1989-10-10
申请号：US182083
申请日：1988-04-15
申请人： Masato Yoshikawa , Yukio Fukuura , Setsuo Akiyama , Makoto Nakamura , Kazuo Naito , Toshio Honda
发明人： Masato Yoshikawa , Yukio Fukuura , Setsuo Akiyama , Makoto Nakamura , Kazuo Naito , Toshio Honda
IPC分类号： B32B15/06 , C04B41/52 , C04B41/89 , C08J5/12 , C23C28/00
CPC分类号： C04B41/009 , B32B15/06 , C04B41/52 , C04B41/89 , C08J5/12 , C23C28/00 , C08J2321/00 , Y10S156/91 , Y10T428/12937 , Y10T428/31707
摘要： A rubbery composite material comprising a substrate and a rubber composition bonded thereto is prepared by metallizing a substrate with a thin film of zinc, copper, cobalt or an alloy thereof by dry plating such as vacuum deposition, iron plating, DC magnetron sputtering, bipolar sputtering, and RF sputtering processes, and pressing a vulcanizable rubber composition to the metallized substrate under heat and pressure to effect vulcanization bonding.
摘要翻译：通过例如真空沉积，铁电镀，DC磁控溅射，双极溅射等干法电镀，通过用锌，铜，钴或其合金的薄膜对基板进行金属化来制备包含基材和与其结合的橡胶组合物的橡胶状复合材料和RF溅射工艺，并且在加热和加压下将可硫化橡胶组合物压制到金属化基底上以实现硫化粘合。

6. 发明授权

US4657285A Tubular rubber products 失效
标题翻译：管状橡胶制品
公开(公告)号：US4657285A
公开(公告)日：1987-04-14
申请号：US669845
申请日：1984-11-09
申请人： Setsuo Akiyama , Yukio Fukuura , Masato Yoshikawa , Takeyuki Matsuda , Hisanobu Monobe , Shigeki Ohkubo , Shiro Yoshida
发明人： Setsuo Akiyama , Yukio Fukuura , Masato Yoshikawa , Takeyuki Matsuda , Hisanobu Monobe , Shigeki Ohkubo , Shiro Yoshida
IPC分类号： B29C71/00 , B29D23/00 , B29K21/00 , F16L11/04 , F16L33/207 , F16L33/00
CPC分类号： F16L33/2076 , F16L11/04
摘要： A process for producing a tubular rubber product such as a rubber hose and a rubber coupling in which a polyamide resin and/or polyester resin layer is formed to the main body of a tubular rubber product. The resin layer is formed either by coating an organic solvent-soluble nylon to the surface of the main body of the tubular rubber product applied with the surface treatment of a halogenoid compound, or by polyamide resin or by polyester resin film having a softening point in the vulcanization temperature region and treated with an adhesive mainly comprising a resorcine-formaldehyde resin and a rubber latex or treated with an adhesive rubber mainly comprising a resorcine, a formaldehyde-forming substance and a vinylpyridine-butadiene-styrene copolymer rubber and then bonding under vulcanization onto the main body of the non-vulcanized tubular rubber product.
摘要翻译：一种用于制造管状橡胶制品的方法，例如橡胶软管和橡胶联接器，其中聚酰胺树脂和/或聚酯树脂层形成在管状橡胶制品的主体上。树脂层通过将有机溶剂可溶性尼龙涂覆在应用了含卤素化合物的表面处理的管状橡胶制品的主体的表面上，或者通过聚酰胺树脂或具有软化点的聚酯树脂膜硫化温度区域，并用主要包含甲醛 - 甲醛树脂和橡胶胶乳的粘合剂处理，或者用主要包含间苯二酚，甲醛形成物质和乙烯基吡啶 - 丁二烯 - 苯乙烯共聚物橡胶的粘合橡胶处理，然后在硫化下粘合到非硫化管状橡胶制品的主体上。

7. 发明授权

US4985510A Crystalline N-methoxymethylated nylon and nylon composition 失效
标题翻译：结晶N-甲氧基甲基化尼龙和尼龙组合物
公开(公告)号：US4985510A
公开(公告)日：1991-01-15
申请号：US225821
申请日：1988-07-29
申请人： Setsuo Akiyama , Hisanobu Monobe , Kazuo Naito , Toshio Honda , Kazuo Tanaka
发明人： Setsuo Akiyama , Hisanobu Monobe , Kazuo Naito , Toshio Honda , Kazuo Tanaka
IPC分类号： C08G69/48 , C08J7/04
CPC分类号： C08J7/047 , C08G69/48 , C08J2321/00 , C08J2477/00 , Y10T428/31725 , Y10T428/31739 , Y10T428/3175
摘要： Crystalline N-methoxymethylated nylon is useful to form a coating on a rubber substrate. It is prepared by adding acid to N-methoxymethylated nylon and heat treating the mixture for crystallization.
摘要翻译：结晶N-甲氧基甲基化尼龙可用于在橡胶基材上形成涂层。通过向N-甲氧基甲基化尼龙中加入酸并将混合物热处理结晶来制备。

8. 发明授权

US5707701A Resin/rubber laminate 失效
标题翻译：树脂/橡胶层压板
公开(公告)号：US5707701A
公开(公告)日：1998-01-13
申请号：US518296
申请日：1995-08-23
申请人： Shinji Saitoh , Setsuo Akiyama , Kazuo Naito
发明人： Shinji Saitoh , Setsuo Akiyama , Kazuo Naito
IPC分类号： B32B25/08 , C08K5/5419 , F16L11/04 , B29D23/00
CPC分类号： F16L11/04 , B32B25/08 , C08K5/5419 , Y10T428/1393 , Y10T428/31743 , Y10T428/31746 , Y10T428/3175 , Y10T428/31757
摘要： A rubber composition comprising a rubber component and a di- or trialkoxysilane compound is joined to a surface-modified resin to form a resin/rubber laminate. The laminate typically forms a refrigerant carrying hose wherein the resin defines an inside surface.
摘要翻译：将包含橡胶组分和二 - 或三烷氧基硅烷化合物的橡胶组合物接合到表面改性树脂上以形成树脂/橡胶层压体。层压板通常形成制冷剂承载软管，其中树脂限定内表面。

9. 发明授权

US4317862A Sandwich glass 失效
标题翻译：三明治玻璃
公开(公告)号：US4317862A
公开(公告)日：1982-03-02
申请号：US108093
申请日：1979-12-28
申请人： Toshio Honda , Itsuo Tanuma , Masao Ogawa , Hikaru Ishikawa , Yukio Fukuura , Setsuo Akiyama , Shozo Ojima , Kazuo Naito
发明人： Toshio Honda , Itsuo Tanuma , Masao Ogawa , Hikaru Ishikawa , Yukio Fukuura , Setsuo Akiyama , Shozo Ojima , Kazuo Naito
IPC分类号： B32B17/10 , C03C27/12 , B32B27/30
CPC分类号： B32B17/10688 , B32B17/1055 , B32B17/10706 , Y10T428/31645 , Y10T428/31649 , Y10T428/31855 , Y10T428/31931 , Y10T428/31935
摘要： A sandwich glass having an intermediate layer formed of a photosensitive resin consisting mainly of an acryloyloxy group- or methacryloyloxy group-containing high polymer and at least one of acrylic acid, methacrylic acid and acryloyloxy group- or methacryloyloxy group-containing compound is excellent in the adhesion between the intermediate layer and the glass plates and has high impact absorbing ability, light resistance and heat resistance.
摘要翻译：具有由主要由含丙烯酰氧基或含甲基丙烯酰氧基的高分子组成的感光性树脂和丙烯酸，甲基丙烯酸和含丙烯酰氧基或含甲基丙烯酰氧基的化合物中的至少一种形成的中间层的夹心玻璃具有优异的中间层和玻璃板之间的粘合性，并且具有高冲击吸收能力，耐光性和耐热性。

10. 发明授权

US5780132A Composite rubber article and method of making 失效
标题翻译：复合橡胶制品及其制造方法
公开(公告)号：US5780132A
公开(公告)日：1998-07-14
申请号：US736783
申请日：1996-10-25
申请人： Shinji Saitoh , Masato Yoshikawa , Setsuo Akiyama , Shingo Kato
发明人： Shinji Saitoh , Masato Yoshikawa , Setsuo Akiyama , Shingo Kato
IPC分类号： B32B1/08 , B32B7/04 , B32B9/04 , B32B15/06 , B32B25/04 , C08J5/12 , C08K5/54 , F16L3/13 , F16L11/04 , B29D22/00
CPC分类号： C08J5/124 , B32B7/04 , C08K5/54 , F16L11/04 , F16L3/13 , C08J2323/22 , C08J2323/28 , Y10S138/07 , Y10T428/1386 , Y10T428/139 , Y10T428/1393 , Y10T428/31663 , Y10T428/31743 , Y10T428/3175
摘要： A composite rubber article is obtained by joining a rubber composition based on a brominated p-methylstyrene/isobutylene copolymer to a different material such as a plastic, inorganic and metallic material through a di-, tri- or tetra-alkoxysilane compound. The copolymer is firmly joined to the different material. The invention is applicable to the manufacture of composite rubber articles such as tires, high-pressure hoses, and pneumatic springs.
摘要翻译：通过二 - ，三 - 或四 - 烷氧基硅烷化合物将基于溴化对甲基苯乙烯/异丁烯共聚物的橡胶组合物与塑料，无机和金属材料等不同材料接合而获得复合橡胶制品。共聚物牢固地连接到不同的材料上。本发明适用于复合橡胶制品如轮胎，高压软管和气动弹簧的制造。

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